Mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films

This study was carried out to develop renewable and degradable plastics film with good mechanical properties. The mechanical properties between compatibilized montmorillonite (MMT)/chitosan filled tapioca starch (TPS), uncompatibilized MMT/TPS, and chitosan/TPS nanocomposite films were investigated....

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Main Authors: Abdul Ghani, Siti Waqina, Abu Bakar, Aznizam, Samsudin, Sani Amril
Format: Conference or Workshop Item
Published: 2013
Subjects:
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author Abdul Ghani, Siti Waqina
Abu Bakar, Aznizam
Samsudin, Sani Amril
author_facet Abdul Ghani, Siti Waqina
Abu Bakar, Aznizam
Samsudin, Sani Amril
author_sort Abdul Ghani, Siti Waqina
collection ePrints
description This study was carried out to develop renewable and degradable plastics film with good mechanical properties. The mechanical properties between compatibilized montmorillonite (MMT)/chitosan filled tapioca starch (TPS), uncompatibilized MMT/TPS, and chitosan/TPS nanocomposite films were investigated. Experimental works were started with the extraction of local chitosan from chitin derived from prawn shells which involving deprotenization, demineralization and deacetylation treatments. Degree of deacetylation of chitosan was determined using infrared spectroscopy method. Chitosan was acted as compatibilizer between MMT and starch in order to improve the dispersion of MMT in nanocomposite systems. Nanocomposite films were prepared using a solution casting method with addition of glycerol as the plasticizer. The starch solution was cast onto PTFE mold with cavity thickness of 0.5mm. Characterizations of the nanocomposite films were done using Fourier Transform Infrared Analysis (FTIR). Tensile properties of nanocomposites were investigated. The compatibilized nanocomposite films, chitosan/MMT/TPS give significant effects to tensile properties. Chitosan has played its role as the compatibilizer and also as flexibility improvers to nanocomposite films because elongation at break improved after addition of chitosan.
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spelling utm.eprints-511612017-09-03T11:30:25Z http://eprints.utm.my/51161/ Mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films Abdul Ghani, Siti Waqina Abu Bakar, Aznizam Samsudin, Sani Amril TP Chemical technology This study was carried out to develop renewable and degradable plastics film with good mechanical properties. The mechanical properties between compatibilized montmorillonite (MMT)/chitosan filled tapioca starch (TPS), uncompatibilized MMT/TPS, and chitosan/TPS nanocomposite films were investigated. Experimental works were started with the extraction of local chitosan from chitin derived from prawn shells which involving deprotenization, demineralization and deacetylation treatments. Degree of deacetylation of chitosan was determined using infrared spectroscopy method. Chitosan was acted as compatibilizer between MMT and starch in order to improve the dispersion of MMT in nanocomposite systems. Nanocomposite films were prepared using a solution casting method with addition of glycerol as the plasticizer. The starch solution was cast onto PTFE mold with cavity thickness of 0.5mm. Characterizations of the nanocomposite films were done using Fourier Transform Infrared Analysis (FTIR). Tensile properties of nanocomposites were investigated. The compatibilized nanocomposite films, chitosan/MMT/TPS give significant effects to tensile properties. Chitosan has played its role as the compatibilizer and also as flexibility improvers to nanocomposite films because elongation at break improved after addition of chitosan. 2013-04 Conference or Workshop Item PeerReviewed Abdul Ghani, Siti Waqina and Abu Bakar, Aznizam and Samsudin, Sani Amril (2013) Mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films. In: Advanced Materials Research (Volume 686). https://www.scientific.net/AMR.686.145
spellingShingle TP Chemical technology
Abdul Ghani, Siti Waqina
Abu Bakar, Aznizam
Samsudin, Sani Amril
Mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films
title Mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films
title_full Mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films
title_fullStr Mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films
title_full_unstemmed Mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films
title_short Mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films
title_sort mechanical properties of chitosan modified montmorillonite filled tapioca starch nanocomposite films
topic TP Chemical technology
work_keys_str_mv AT abdulghanisitiwaqina mechanicalpropertiesofchitosanmodifiedmontmorillonitefilledtapiocastarchnanocompositefilms
AT abubakaraznizam mechanicalpropertiesofchitosanmodifiedmontmorillonitefilledtapiocastarchnanocompositefilms
AT samsudinsaniamril mechanicalpropertiesofchitosanmodifiedmontmorillonitefilledtapiocastarchnanocompositefilms