Facile preparation of highly reactive electrogenerated zinc
Highly reactive electrogenerated zinc metal (EGZn/Naph) was readily prepared by electrolysis of a DMF solution containing naphthalene and a supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a zinc anode. The reactivity of this EGZn/Nagh was elucidated by an efficien...
| Main Authors: | , , , |
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| Format: | Conference or Workshop Item |
| Language: | English |
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2004
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| Online Access: | http://eprints.utm.my/5233/1/AishahAbdulJalil2004_FacilePreparationOfHighlyReactiveElectrogeneratedZinc.pdf |
| _version_ | 1796853874859966464 |
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| author | Abdul Jalil, Aishah Kurono, Nobuhita Takasugi, Shingo Tokuda, Masao |
| author_facet | Abdul Jalil, Aishah Kurono, Nobuhita Takasugi, Shingo Tokuda, Masao |
| author_sort | Abdul Jalil, Aishah |
| collection | ePrints |
| description | Highly reactive electrogenerated zinc metal (EGZn/Naph) was readily prepared by electrolysis of a DMF solution containing naphthalene and a supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a zinc anode. The reactivity of this EGZn/Nagh was elucidated by an efficient transformation of ethyl 2-bromobutanoate as a model substrate into the corresponding organozinc compound, which can not be achieved by the use of usual zinc metal. It was found that the electrolysis at -10 C at a constant current of 60 mA/cm2 under nitrogen atmosphere was the optimum conditions in preparing this EGZn/Naph. |
| first_indexed | 2024-03-05T18:06:03Z |
| format | Conference or Workshop Item |
| id | utm.eprints-5233 |
| institution | Universiti Teknologi Malaysia - ePrints |
| language | English |
| last_indexed | 2024-03-05T18:06:03Z |
| publishDate | 2004 |
| record_format | dspace |
| spelling | utm.eprints-52332017-09-10T06:39:10Z http://eprints.utm.my/5233/ Facile preparation of highly reactive electrogenerated zinc Abdul Jalil, Aishah Kurono, Nobuhita Takasugi, Shingo Tokuda, Masao T Technology (General) Highly reactive electrogenerated zinc metal (EGZn/Naph) was readily prepared by electrolysis of a DMF solution containing naphthalene and a supporting electrolyte in a one-compartment cell fitted with a platinum cathode and a zinc anode. The reactivity of this EGZn/Nagh was elucidated by an efficient transformation of ethyl 2-bromobutanoate as a model substrate into the corresponding organozinc compound, which can not be achieved by the use of usual zinc metal. It was found that the electrolysis at -10 C at a constant current of 60 mA/cm2 under nitrogen atmosphere was the optimum conditions in preparing this EGZn/Naph. 2004 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/5233/1/AishahAbdulJalil2004_FacilePreparationOfHighlyReactiveElectrogeneratedZinc.pdf Abdul Jalil, Aishah and Kurono, Nobuhita and Takasugi, Shingo and Tokuda, Masao (2004) Facile preparation of highly reactive electrogenerated zinc. In: Annual Fundamental Science Seminar 2004 (AFSS 2004), 14-15 June 2004, Ibnu Sina Institute for Fundamental Science Studies,UTM. (Submitted) |
| spellingShingle | T Technology (General) Abdul Jalil, Aishah Kurono, Nobuhita Takasugi, Shingo Tokuda, Masao Facile preparation of highly reactive electrogenerated zinc |
| title | Facile preparation of highly reactive electrogenerated zinc |
| title_full | Facile preparation of highly reactive electrogenerated zinc |
| title_fullStr | Facile preparation of highly reactive electrogenerated zinc |
| title_full_unstemmed | Facile preparation of highly reactive electrogenerated zinc |
| title_short | Facile preparation of highly reactive electrogenerated zinc |
| title_sort | facile preparation of highly reactive electrogenerated zinc |
| topic | T Technology (General) |
| url | http://eprints.utm.my/5233/1/AishahAbdulJalil2004_FacilePreparationOfHighlyReactiveElectrogeneratedZinc.pdf |
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