The prediction of vapour liquid equilibrium behaviour of propane butane mixture
This paper is a contribution to the development of mathematical model for the prediction of vapour liquid equilibrium behaviour of propane butane mixture at non-ideal state. The proposed model is based on the generalized virial equation of state and Gamma/Phi formulation. Mathematical modeling, Math...
| Main Authors: | , |
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| Format: | Conference or Workshop Item |
| Language: | English |
| Published: |
2005
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| Online Access: | http://eprints.utm.my/5262/1/ZainalZakaria2005_ThePredictionOfVapourLiquidEquilibrium.pdf |
| _version_ | 1825909703985594368 |
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| author | Zakaria, Zainal Tee, S. Y. |
| author_facet | Zakaria, Zainal Tee, S. Y. |
| author_sort | Zakaria, Zainal |
| collection | ePrints |
| description | This paper is a contribution to the development of mathematical model for the prediction of vapour liquid equilibrium behaviour of propane butane mixture at non-ideal state. The proposed model is based on the generalized virial equation of state and Gamma/Phi formulation. Mathematical modeling, Mathcad is used to numerically solve for fugacity, fugacity coefficient, activity coefficient and vapour-phase composition of propane butane mixture by taking into consideration the effects of temperature and pressure. A temperature range of 263.15K to 313.15K chosen in this modeling is of practicability for propane butane mixture in cylindrical storage. The prediction of vapour liquid equilibrium behaviour for propane butane mixture is illustrated in PxY diagram at different system temperatures. It is clearly shown that solution fugacity coefficient decreases steadily as system temperature and pressure increase. It is also shown that the solution fugacity increases with system temperature and pressure. Activity coefficient of butane in mixture becomes larger as system temperature and pressure increase. Meanwhile, there is insignificant decrease in activity coefficient of propane with temperature and pressure. As system temperature and pressure go higher, vapour-phase composition of propane decreases while for butane, its concentration in vapour phase becomes richer. |
| first_indexed | 2024-03-05T18:06:07Z |
| format | Conference or Workshop Item |
| id | utm.eprints-5262 |
| institution | Universiti Teknologi Malaysia - ePrints |
| language | English |
| last_indexed | 2024-03-05T18:06:07Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | utm.eprints-52622010-06-01T15:28:15Z http://eprints.utm.my/5262/ The prediction of vapour liquid equilibrium behaviour of propane butane mixture Zakaria, Zainal Tee, S. Y. T Technology (General) This paper is a contribution to the development of mathematical model for the prediction of vapour liquid equilibrium behaviour of propane butane mixture at non-ideal state. The proposed model is based on the generalized virial equation of state and Gamma/Phi formulation. Mathematical modeling, Mathcad is used to numerically solve for fugacity, fugacity coefficient, activity coefficient and vapour-phase composition of propane butane mixture by taking into consideration the effects of temperature and pressure. A temperature range of 263.15K to 313.15K chosen in this modeling is of practicability for propane butane mixture in cylindrical storage. The prediction of vapour liquid equilibrium behaviour for propane butane mixture is illustrated in PxY diagram at different system temperatures. It is clearly shown that solution fugacity coefficient decreases steadily as system temperature and pressure increase. It is also shown that the solution fugacity increases with system temperature and pressure. Activity coefficient of butane in mixture becomes larger as system temperature and pressure increase. Meanwhile, there is insignificant decrease in activity coefficient of propane with temperature and pressure. As system temperature and pressure go higher, vapour-phase composition of propane decreases while for butane, its concentration in vapour phase becomes richer. 2005 Conference or Workshop Item PeerReviewed application/pdf en http://eprints.utm.my/5262/1/ZainalZakaria2005_ThePredictionOfVapourLiquidEquilibrium.pdf Zakaria, Zainal and Tee, S. Y. (2005) The prediction of vapour liquid equilibrium behaviour of propane butane mixture. In: Malaysian Science and Technology Congress (MSTC 2005), 18-20 April 2005, CitiTel Hotel Mid Valley, Kuala Lumpur. |
| spellingShingle | T Technology (General) Zakaria, Zainal Tee, S. Y. The prediction of vapour liquid equilibrium behaviour of propane butane mixture |
| title | The prediction of vapour liquid equilibrium behaviour of
propane butane mixture
|
| title_full | The prediction of vapour liquid equilibrium behaviour of
propane butane mixture
|
| title_fullStr | The prediction of vapour liquid equilibrium behaviour of
propane butane mixture
|
| title_full_unstemmed | The prediction of vapour liquid equilibrium behaviour of
propane butane mixture
|
| title_short | The prediction of vapour liquid equilibrium behaviour of
propane butane mixture
|
| title_sort | prediction of vapour liquid equilibrium behaviour of propane butane mixture |
| topic | T Technology (General) |
| url | http://eprints.utm.my/5262/1/ZainalZakaria2005_ThePredictionOfVapourLiquidEquilibrium.pdf |
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