Enhanced luminescence from erbium doped phosphate glass containing ZnO nanoparticles

Enhancing the up-conversion luminescence and nonlinear optical properties by incorporating various metallic nanoparticles (NPs) into rare earth (RE) doped glass oxides is the key issue towards the fabrication of photonic devices. Series of erbium doped phosphate glasses containing ZnO NPs with compo...

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Main Authors: Arifin, Ramli, Zulkifeli, N. A., Sahar, Md. Rahim, Ghoshal, Sibkrishna
Format: Article
Published: Trans Tech Publications, Switzerland 2014
Subjects:
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author Arifin, Ramli
Zulkifeli, N. A.
Sahar, Md. Rahim
Ghoshal, Sibkrishna
author_facet Arifin, Ramli
Zulkifeli, N. A.
Sahar, Md. Rahim
Ghoshal, Sibkrishna
author_sort Arifin, Ramli
collection ePrints
description Enhancing the up-conversion luminescence and nonlinear optical properties by incorporating various metallic nanoparticles (NPs) into rare earth (RE) doped glass oxides is the key issue towards the fabrication of photonic devices. Series of erbium doped phosphate glasses containing ZnO NPs with composition (78.5-x)P2O5 10Li2O 10ZnO 1.5Er2O3 (x)ZnO, where 0 x 1.2 are prepared by melt quenching technique and their spectroscopic characterization are made. The amorphous nature of the glass is confirmed by XRD spectra. The influence of NPs on the luminescence characteristics using 357 nm excitations is studied and the mechanisms involved in the enhancement on emission intensity are examined. The emission spectra exhibit eight peaks in which the peak intensity of the violet and blue band (413 and 458 nm) shows gradual increment with increasing concentration of ZnO NPs added to the host matrix. The enhancement in the emission peak intensity for the transition is attributed to the effects of quantum confinement and local field of ZnO NPs. The effect of NPs within the glass matrix in influencing the optical properties are analysed and discussed. Our observation may contribute towards the development of nanophotonics.
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spelling utm.eprints-526932018-06-29T23:05:10Z http://eprints.utm.my/52693/ Enhanced luminescence from erbium doped phosphate glass containing ZnO nanoparticles Arifin, Ramli Zulkifeli, N. A. Sahar, Md. Rahim Ghoshal, Sibkrishna Q Science Enhancing the up-conversion luminescence and nonlinear optical properties by incorporating various metallic nanoparticles (NPs) into rare earth (RE) doped glass oxides is the key issue towards the fabrication of photonic devices. Series of erbium doped phosphate glasses containing ZnO NPs with composition (78.5-x)P2O5 10Li2O 10ZnO 1.5Er2O3 (x)ZnO, where 0 x 1.2 are prepared by melt quenching technique and their spectroscopic characterization are made. The amorphous nature of the glass is confirmed by XRD spectra. The influence of NPs on the luminescence characteristics using 357 nm excitations is studied and the mechanisms involved in the enhancement on emission intensity are examined. The emission spectra exhibit eight peaks in which the peak intensity of the violet and blue band (413 and 458 nm) shows gradual increment with increasing concentration of ZnO NPs added to the host matrix. The enhancement in the emission peak intensity for the transition is attributed to the effects of quantum confinement and local field of ZnO NPs. The effect of NPs within the glass matrix in influencing the optical properties are analysed and discussed. Our observation may contribute towards the development of nanophotonics. Trans Tech Publications, Switzerland 2014 Article PeerReviewed Arifin, Ramli and Zulkifeli, N. A. and Sahar, Md. Rahim and Ghoshal, Sibkrishna (2014) Enhanced luminescence from erbium doped phosphate glass containing ZnO nanoparticles. Advanced Materials Research, 895 . pp. 241-244. ISSN 1022-6680 https://dx.doi.org/10.4028/www.scientific.net/AMR.895.241 DOI:10.4028/www.scientific.net/AMR.895.24
spellingShingle Q Science
Arifin, Ramli
Zulkifeli, N. A.
Sahar, Md. Rahim
Ghoshal, Sibkrishna
Enhanced luminescence from erbium doped phosphate glass containing ZnO nanoparticles
title Enhanced luminescence from erbium doped phosphate glass containing ZnO nanoparticles
title_full Enhanced luminescence from erbium doped phosphate glass containing ZnO nanoparticles
title_fullStr Enhanced luminescence from erbium doped phosphate glass containing ZnO nanoparticles
title_full_unstemmed Enhanced luminescence from erbium doped phosphate glass containing ZnO nanoparticles
title_short Enhanced luminescence from erbium doped phosphate glass containing ZnO nanoparticles
title_sort enhanced luminescence from erbium doped phosphate glass containing zno nanoparticles
topic Q Science
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AT zulkifelina enhancedluminescencefromerbiumdopedphosphateglasscontainingznonanoparticles
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