Rapid adsorption of copper(ii) and lead(ii) by rice straw/fe3o4 nanocomposite: optimization, equilibrium isotherms, and adsorption kinetics study

Rice straw/magnetic nanocomposites (RS/Fe3O4-NCs) were prepared via co-precipitation method for removal of Pb(II) and Cu(II) from aqueous solutions. Response surface methodology (RSM) was utilized to find the optimum conditions for removal of ions. The effects of three independent variables includin...

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Main Authors: Khandanlou, Roshanak, Ahmad, Mansor, Masoumi, Hamid Reza Fard, Shameli, Kamyar, Basri, Mahiran, Kalantari, Katayoon
Format: Article
Published: Public Library Science 2015
Subjects:
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author Khandanlou, Roshanak
Ahmad, Mansor
Masoumi, Hamid Reza Fard
Shameli, Kamyar
Basri, Mahiran
Kalantari, Katayoon
author_facet Khandanlou, Roshanak
Ahmad, Mansor
Masoumi, Hamid Reza Fard
Shameli, Kamyar
Basri, Mahiran
Kalantari, Katayoon
author_sort Khandanlou, Roshanak
collection ePrints
description Rice straw/magnetic nanocomposites (RS/Fe3O4-NCs) were prepared via co-precipitation method for removal of Pb(II) and Cu(II) from aqueous solutions. Response surface methodology (RSM) was utilized to find the optimum conditions for removal of ions. The effects of three independent variables including initial ion concentration, removal time, and adsorbent dosage were investigated on the maximum adsorption of Pb (II) and Cu (II). The optimum conditions for the adsorption of Pb(II) and Cu(II) were obtained (100 and 60 mg/L) of initial ion concentration, (41.96 and 59.35 s) of removal time and 0.13 g of adsorbent for both ions, respectively. The maximum removal efficiencies of Pb(II) and Cu(II) were obtained 96.25% and 75.54%, respectively. In the equilibrium isotherm study, the adsorption data fitted well with the Langmuir isotherm model. The adsorption kinetics was best depicted by the pseudo-second order model. Desorption experiments showed adsorbent can be reused successfully for three adsorption-desorption cycles.
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spelling utm.eprints-551792016-09-04T01:04:18Z http://eprints.utm.my/55179/ Rapid adsorption of copper(ii) and lead(ii) by rice straw/fe3o4 nanocomposite: optimization, equilibrium isotherms, and adsorption kinetics study Khandanlou, Roshanak Ahmad, Mansor Masoumi, Hamid Reza Fard Shameli, Kamyar Basri, Mahiran Kalantari, Katayoon T Technology (General) Rice straw/magnetic nanocomposites (RS/Fe3O4-NCs) were prepared via co-precipitation method for removal of Pb(II) and Cu(II) from aqueous solutions. Response surface methodology (RSM) was utilized to find the optimum conditions for removal of ions. The effects of three independent variables including initial ion concentration, removal time, and adsorbent dosage were investigated on the maximum adsorption of Pb (II) and Cu (II). The optimum conditions for the adsorption of Pb(II) and Cu(II) were obtained (100 and 60 mg/L) of initial ion concentration, (41.96 and 59.35 s) of removal time and 0.13 g of adsorbent for both ions, respectively. The maximum removal efficiencies of Pb(II) and Cu(II) were obtained 96.25% and 75.54%, respectively. In the equilibrium isotherm study, the adsorption data fitted well with the Langmuir isotherm model. The adsorption kinetics was best depicted by the pseudo-second order model. Desorption experiments showed adsorbent can be reused successfully for three adsorption-desorption cycles. Public Library Science 2015-03-27 Article PeerReviewed Khandanlou, Roshanak and Ahmad, Mansor and Masoumi, Hamid Reza Fard and Shameli, Kamyar and Basri, Mahiran and Kalantari, Katayoon (2015) Rapid adsorption of copper(ii) and lead(ii) by rice straw/fe3o4 nanocomposite: optimization, equilibrium isotherms, and adsorption kinetics study. Plos One, 10 (3). ISSN 1932-6203 http://dx.doi.org/10.1371/journal.pone.0120264 DOI:10.1371/journal.pone.0120264
spellingShingle T Technology (General)
Khandanlou, Roshanak
Ahmad, Mansor
Masoumi, Hamid Reza Fard
Shameli, Kamyar
Basri, Mahiran
Kalantari, Katayoon
Rapid adsorption of copper(ii) and lead(ii) by rice straw/fe3o4 nanocomposite: optimization, equilibrium isotherms, and adsorption kinetics study
title Rapid adsorption of copper(ii) and lead(ii) by rice straw/fe3o4 nanocomposite: optimization, equilibrium isotherms, and adsorption kinetics study
title_full Rapid adsorption of copper(ii) and lead(ii) by rice straw/fe3o4 nanocomposite: optimization, equilibrium isotherms, and adsorption kinetics study
title_fullStr Rapid adsorption of copper(ii) and lead(ii) by rice straw/fe3o4 nanocomposite: optimization, equilibrium isotherms, and adsorption kinetics study
title_full_unstemmed Rapid adsorption of copper(ii) and lead(ii) by rice straw/fe3o4 nanocomposite: optimization, equilibrium isotherms, and adsorption kinetics study
title_short Rapid adsorption of copper(ii) and lead(ii) by rice straw/fe3o4 nanocomposite: optimization, equilibrium isotherms, and adsorption kinetics study
title_sort rapid adsorption of copper ii and lead ii by rice straw fe3o4 nanocomposite optimization equilibrium isotherms and adsorption kinetics study
topic T Technology (General)
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AT ahmadmansor rapidadsorptionofcopperiiandleadiibyricestrawfe3o4nanocompositeoptimizationequilibriumisothermsandadsorptionkineticsstudy
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