Enhanced photocatalytic performance of copper-modified titanium dioxide prepared by uv reduction method
In the present study, commercial Hombikat N100 TiO2 that consists of 100% of anatase phase was modified with copper (Cu) as a co-catalyst via two different preparation methods, which were photocatalytic UV reduction and impregnation methods. The Cu loading was fixed to be 0.1 wt%. The X-ray diffract...
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2015
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author | Roslan, Nur Azmina Lintang, Hendrik Oktendy Leny Yuliati, Leny Yuliati |
author_facet | Roslan, Nur Azmina Lintang, Hendrik Oktendy Leny Yuliati, Leny Yuliati |
author_sort | Roslan, Nur Azmina |
collection | ePrints |
description | In the present study, commercial Hombikat N100 TiO2 that consists of 100% of anatase phase was modified with copper (Cu) as a co-catalyst via two different preparation methods, which were photocatalytic UV reduction and impregnation methods. The Cu loading was fixed to be 0.1 wt%. The X-ray diffraction (XRD) patterns showed that Cu/TiO2 sample prepared via different preparation methods gave different crystallinity and/or crystallite size. The Cu/TiO2 sample prepared by photocatalytic UV reduction method has lower crystallinity and/or crystallite size than the sample prepared by impregnation method. The performance of the TiO2 and Cu/TiO2 samples was evaluated for degradation of 2,4-dichlorophenoxyacetic acid (2,4-D). After 1 hour reaction, the TiO2 showed percentage removal of 31%, while the Cu/TiO2 sample prepared by photocatalytic UV reduction and impregnation methods gave 39 and 28%, respectively. It was proposed that the higher activity on the Cu/TiO2 sample prepared by photocatalytic UV reduction method was caused by the more successful suppression of electron-hole recombination, as supported by the emission spectra. |
first_indexed | 2024-03-05T19:52:08Z |
format | Conference or Workshop Item |
id | utm.eprints-61767 |
institution | Universiti Teknologi Malaysia - ePrints |
last_indexed | 2024-03-05T19:52:08Z |
publishDate | 2015 |
record_format | dspace |
spelling | utm.eprints-617672017-08-09T04:31:51Z http://eprints.utm.my/61767/ Enhanced photocatalytic performance of copper-modified titanium dioxide prepared by uv reduction method Roslan, Nur Azmina Lintang, Hendrik Oktendy Leny Yuliati, Leny Yuliati QD Chemistry In the present study, commercial Hombikat N100 TiO2 that consists of 100% of anatase phase was modified with copper (Cu) as a co-catalyst via two different preparation methods, which were photocatalytic UV reduction and impregnation methods. The Cu loading was fixed to be 0.1 wt%. The X-ray diffraction (XRD) patterns showed that Cu/TiO2 sample prepared via different preparation methods gave different crystallinity and/or crystallite size. The Cu/TiO2 sample prepared by photocatalytic UV reduction method has lower crystallinity and/or crystallite size than the sample prepared by impregnation method. The performance of the TiO2 and Cu/TiO2 samples was evaluated for degradation of 2,4-dichlorophenoxyacetic acid (2,4-D). After 1 hour reaction, the TiO2 showed percentage removal of 31%, while the Cu/TiO2 sample prepared by photocatalytic UV reduction and impregnation methods gave 39 and 28%, respectively. It was proposed that the higher activity on the Cu/TiO2 sample prepared by photocatalytic UV reduction method was caused by the more successful suppression of electron-hole recombination, as supported by the emission spectra. 2015 Conference or Workshop Item PeerReviewed Roslan, Nur Azmina and Lintang, Hendrik Oktendy and Leny Yuliati, Leny Yuliati (2015) Enhanced photocatalytic performance of copper-modified titanium dioxide prepared by uv reduction method. In: Advanced Research Materials, 26-28 Sept, 2015, Indonesia. https://www.scientific.net/AMR.1112.180 |
spellingShingle | QD Chemistry Roslan, Nur Azmina Lintang, Hendrik Oktendy Leny Yuliati, Leny Yuliati Enhanced photocatalytic performance of copper-modified titanium dioxide prepared by uv reduction method |
title | Enhanced photocatalytic performance of copper-modified titanium dioxide prepared by uv reduction method |
title_full | Enhanced photocatalytic performance of copper-modified titanium dioxide prepared by uv reduction method |
title_fullStr | Enhanced photocatalytic performance of copper-modified titanium dioxide prepared by uv reduction method |
title_full_unstemmed | Enhanced photocatalytic performance of copper-modified titanium dioxide prepared by uv reduction method |
title_short | Enhanced photocatalytic performance of copper-modified titanium dioxide prepared by uv reduction method |
title_sort | enhanced photocatalytic performance of copper modified titanium dioxide prepared by uv reduction method |
topic | QD Chemistry |
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