Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications
Herein we report the first example of benzene-1,3,5-tricarboxamide bearing hydrophobic aminododecane side chains (1) which spontaneously forms supramolecular network by a hydrogen bonding interaction. The compound 1 was synthesized by Schotten-Baumann reaction of 1,3,5-benzenetricarbonyl trichloride...
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| Format: | Article |
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Trans Tech Publication
2014
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| author | Matmin, Juan Yuliati, Leny Shamsuddin, Mustaffa Lintang, Hendrik Oktendy |
| author_facet | Matmin, Juan Yuliati, Leny Shamsuddin, Mustaffa Lintang, Hendrik Oktendy |
| author_sort | Matmin, Juan |
| collection | ePrints |
| description | Herein we report the first example of benzene-1,3,5-tricarboxamide bearing hydrophobic aminododecane side chains (1) which spontaneously forms supramolecular network by a hydrogen bonding interaction. The compound 1 was synthesized by Schotten-Baumann reaction of 1,3,5-benzenetricarbonyl trichloride and 1-aminododecane in the presence of N,N-diisopropylethylamine. Nuclear Magnetic Resonance (NMR), Mass Spectrometry (MS), and Fourier Transform Infrared (FTIR) spectroscopies have proved the successful synthesis of 1 in 93% as white powder solid. The supramolecular organization was successfully utilized for sensing of nitrate anions by deformation of the hydrogen bonding to form inactive nitroso groups. |
| first_indexed | 2024-03-05T19:54:37Z |
| format | Article |
| id | utm.eprints-62732 |
| institution | Universiti Teknologi Malaysia - ePrints |
| last_indexed | 2024-03-05T19:54:37Z |
| publishDate | 2014 |
| publisher | Trans Tech Publication |
| record_format | dspace |
| spelling | utm.eprints-627322017-06-05T03:05:59Z http://eprints.utm.my/62732/ Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications Matmin, Juan Yuliati, Leny Shamsuddin, Mustaffa Lintang, Hendrik Oktendy Q Science Herein we report the first example of benzene-1,3,5-tricarboxamide bearing hydrophobic aminododecane side chains (1) which spontaneously forms supramolecular network by a hydrogen bonding interaction. The compound 1 was synthesized by Schotten-Baumann reaction of 1,3,5-benzenetricarbonyl trichloride and 1-aminododecane in the presence of N,N-diisopropylethylamine. Nuclear Magnetic Resonance (NMR), Mass Spectrometry (MS), and Fourier Transform Infrared (FTIR) spectroscopies have proved the successful synthesis of 1 in 93% as white powder solid. The supramolecular organization was successfully utilized for sensing of nitrate anions by deformation of the hydrogen bonding to form inactive nitroso groups. Trans Tech Publication 2014 Article PeerReviewed Matmin, Juan and Yuliati, Leny and Shamsuddin, Mustaffa and Lintang, Hendrik Oktendy (2014) Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications. Advanced Materials Research, 925 . pp. 228-232. ISSN 1022-6680 http://dx.doi.org/10.4028/www.scientific.net/AMR.925.228 DOI:10.4028/www.scientific.net/AMR.925.228 |
| spellingShingle | Q Science Matmin, Juan Yuliati, Leny Shamsuddin, Mustaffa Lintang, Hendrik Oktendy Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications |
| title | Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications |
| title_full | Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications |
| title_fullStr | Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications |
| title_full_unstemmed | Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications |
| title_short | Supramolecular hydrogen bonding interactions of novel 1,3,5-benzenetricarbonyl trisubstituted alkyl for anion sensor applications |
| title_sort | supramolecular hydrogen bonding interactions of novel 1 3 5 benzenetricarbonyl trisubstituted alkyl for anion sensor applications |
| topic | Q Science |
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