Surface modification and performance enhancement of nano-hybrid f-MWCNT/PVP90/PES hemodialysis membranes

The use of nanoparticles for surface modification and performance enhancement of membranes is another latest trend in membrane technology. In this work acid functionalized multi wall carbon nanotubes (f-MWCNT) was initially mixed with polyvinylpyrrolidone (PVP) in dimethylformamide (DMF) to form nan...

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Main Authors: Irfan, Muhammad, Idris, Ani, Mohd. Yusof, Noordin, Mohd. Khairuddin, Nur Farahah, Akhmal, Hasrul
Format: Article
Published: Elsevier 2014
Subjects:
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author Irfan, Muhammad
Idris, Ani
Mohd. Yusof, Noordin
Mohd. Khairuddin, Nur Farahah
Akhmal, Hasrul
author_facet Irfan, Muhammad
Idris, Ani
Mohd. Yusof, Noordin
Mohd. Khairuddin, Nur Farahah
Akhmal, Hasrul
author_sort Irfan, Muhammad
collection ePrints
description The use of nanoparticles for surface modification and performance enhancement of membranes is another latest trend in membrane technology. In this work acid functionalized multi wall carbon nanotubes (f-MWCNT) was initially mixed with polyvinylpyrrolidone (PVP) in dimethylformamide (DMF) to form nano-composites (NCs) and then blended with polyethersulfone (PES). The PES/PVP-f-MWCNT nano-hybrid hemodialysis membrane was formed via the phase inversion process. The membranes were characterized and their performances were then evaluated in terms of pure water permeation rates (PWP), urea, creatinine and lysozyme rejection. The results revealed that, compared to the pristine PES membrane, the PES nano-hybrid hemodialysis membranes were more hydrophilic; possess high PWP rate up to 72.20 L.m(-2).h(-1), exhibited 58.82% reduced protein absorption, and better uremic waste clearance of 56.30%, 55.08% and 27.90% of urea, creatinine and lysozyme respectively. Thus the addition of NCs in the membranes indeed modified the surface and enhanced the performance of the PES membranes.
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spelling utm.eprints-627342017-06-05T03:07:23Z http://eprints.utm.my/62734/ Surface modification and performance enhancement of nano-hybrid f-MWCNT/PVP90/PES hemodialysis membranes Irfan, Muhammad Idris, Ani Mohd. Yusof, Noordin Mohd. Khairuddin, Nur Farahah Akhmal, Hasrul TP Chemical technology The use of nanoparticles for surface modification and performance enhancement of membranes is another latest trend in membrane technology. In this work acid functionalized multi wall carbon nanotubes (f-MWCNT) was initially mixed with polyvinylpyrrolidone (PVP) in dimethylformamide (DMF) to form nano-composites (NCs) and then blended with polyethersulfone (PES). The PES/PVP-f-MWCNT nano-hybrid hemodialysis membrane was formed via the phase inversion process. The membranes were characterized and their performances were then evaluated in terms of pure water permeation rates (PWP), urea, creatinine and lysozyme rejection. The results revealed that, compared to the pristine PES membrane, the PES nano-hybrid hemodialysis membranes were more hydrophilic; possess high PWP rate up to 72.20 L.m(-2).h(-1), exhibited 58.82% reduced protein absorption, and better uremic waste clearance of 56.30%, 55.08% and 27.90% of urea, creatinine and lysozyme respectively. Thus the addition of NCs in the membranes indeed modified the surface and enhanced the performance of the PES membranes. Elsevier 2014 Article PeerReviewed Irfan, Muhammad and Idris, Ani and Mohd. Yusof, Noordin and Mohd. Khairuddin, Nur Farahah and Akhmal, Hasrul (2014) Surface modification and performance enhancement of nano-hybrid f-MWCNT/PVP90/PES hemodialysis membranes. Journal of Membrane Science, 467 . pp. 73-84. ISSN 1873-3123 http://dx.doi.org/10.1016/j.memsci.2014.05.001 DOI:10.1016/j.memsci.2014.05.001
spellingShingle TP Chemical technology
Irfan, Muhammad
Idris, Ani
Mohd. Yusof, Noordin
Mohd. Khairuddin, Nur Farahah
Akhmal, Hasrul
Surface modification and performance enhancement of nano-hybrid f-MWCNT/PVP90/PES hemodialysis membranes
title Surface modification and performance enhancement of nano-hybrid f-MWCNT/PVP90/PES hemodialysis membranes
title_full Surface modification and performance enhancement of nano-hybrid f-MWCNT/PVP90/PES hemodialysis membranes
title_fullStr Surface modification and performance enhancement of nano-hybrid f-MWCNT/PVP90/PES hemodialysis membranes
title_full_unstemmed Surface modification and performance enhancement of nano-hybrid f-MWCNT/PVP90/PES hemodialysis membranes
title_short Surface modification and performance enhancement of nano-hybrid f-MWCNT/PVP90/PES hemodialysis membranes
title_sort surface modification and performance enhancement of nano hybrid f mwcnt pvp90 pes hemodialysis membranes
topic TP Chemical technology
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