Synthesis, optimization, characterization, and potential agricultural application of polymer hydrogel composites based on cotton microfiber

The optimum content of cotton microfiber, initiator, cross-linker, and sodium hydroxide were determined using the central composite design method. Polymer hydrogels (PHGs) were characterized using Fourier-transform infrared (FT-IR), scanning electron microscopy, and thermal gravimetric analysis. A c...

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Main Authors: Laftah, Waham Ashaier, Hashim, Shahrir
Format: Article
Published: Walter De Gruyter 2014
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author Laftah, Waham Ashaier
Hashim, Shahrir
author_facet Laftah, Waham Ashaier
Hashim, Shahrir
author_sort Laftah, Waham Ashaier
collection ePrints
description The optimum content of cotton microfiber, initiator, cross-linker, and sodium hydroxide were determined using the central composite design method. Polymer hydrogels (PHGs) were characterized using Fourier-transform infrared (FT-IR), scanning electron microscopy, and thermal gravimetric analysis. A comparison between plain PHG and the polymer hydrogel composite (PHGC) in terms of biodegradation, swelling rate, and re-swelling capacity was carried out. The effect of PHGC on the sandy soil holding capacity, urea leaching loss rate (ULLR), and okra plant growth were evaluated. The highest water absorption capacity was obtained at 1.30 mass %, 0.15 mass %, 13.00 mass %, and 13.50 mass % of the initiator, cross-linker, sodium hydroxide, and cotton microfiber, respectively. Cotton microfiber has a prominent effect on the swelling rate, re-swelling capacity, and biodegradability of PHG. Okra plant growth and ULLR were positively affected by PHGC and the best leaching loss rate of 33.3 mass % was observed for the lowest urea loaded sample.
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spelling utm.eprints-627982017-06-15T03:06:26Z http://eprints.utm.my/62798/ Synthesis, optimization, characterization, and potential agricultural application of polymer hydrogel composites based on cotton microfiber Laftah, Waham Ashaier Hashim, Shahrir TP Chemical technology The optimum content of cotton microfiber, initiator, cross-linker, and sodium hydroxide were determined using the central composite design method. Polymer hydrogels (PHGs) were characterized using Fourier-transform infrared (FT-IR), scanning electron microscopy, and thermal gravimetric analysis. A comparison between plain PHG and the polymer hydrogel composite (PHGC) in terms of biodegradation, swelling rate, and re-swelling capacity was carried out. The effect of PHGC on the sandy soil holding capacity, urea leaching loss rate (ULLR), and okra plant growth were evaluated. The highest water absorption capacity was obtained at 1.30 mass %, 0.15 mass %, 13.00 mass %, and 13.50 mass % of the initiator, cross-linker, sodium hydroxide, and cotton microfiber, respectively. Cotton microfiber has a prominent effect on the swelling rate, re-swelling capacity, and biodegradability of PHG. Okra plant growth and ULLR were positively affected by PHGC and the best leaching loss rate of 33.3 mass % was observed for the lowest urea loaded sample. Walter De Gruyter 2014 Article PeerReviewed Laftah, Waham Ashaier and Hashim, Shahrir (2014) Synthesis, optimization, characterization, and potential agricultural application of polymer hydrogel composites based on cotton microfiber. Chemical Papers, 68 (6). pp. 798-808. ISSN 0366-6352 http://dx.doi.org/10.2478/s11696-013-0507-5 DOI:10.2478/s11696-013-0507-5
spellingShingle TP Chemical technology
Laftah, Waham Ashaier
Hashim, Shahrir
Synthesis, optimization, characterization, and potential agricultural application of polymer hydrogel composites based on cotton microfiber
title Synthesis, optimization, characterization, and potential agricultural application of polymer hydrogel composites based on cotton microfiber
title_full Synthesis, optimization, characterization, and potential agricultural application of polymer hydrogel composites based on cotton microfiber
title_fullStr Synthesis, optimization, characterization, and potential agricultural application of polymer hydrogel composites based on cotton microfiber
title_full_unstemmed Synthesis, optimization, characterization, and potential agricultural application of polymer hydrogel composites based on cotton microfiber
title_short Synthesis, optimization, characterization, and potential agricultural application of polymer hydrogel composites based on cotton microfiber
title_sort synthesis optimization characterization and potential agricultural application of polymer hydrogel composites based on cotton microfiber
topic TP Chemical technology
work_keys_str_mv AT laftahwahamashaier synthesisoptimizationcharacterizationandpotentialagriculturalapplicationofpolymerhydrogelcompositesbasedoncottonmicrofiber
AT hashimshahrir synthesisoptimizationcharacterizationandpotentialagriculturalapplicationofpolymerhydrogelcompositesbasedoncottonmicrofiber