Use of supercritical co2 and r134a as solvent for extraction of beta-carotene and alpha-tocopherols from crude palm oil

Supercritical fluid extraction of α-tocopherol and β-carotenoids from crude palm oil offers an excellent method over other existing conventional methods. Supercritical fluid extraction was developed in the early and mid-1980s to reduce the use of harmful organic solvent in the laboratory. The presen...

Full description

Bibliographic Details
Main Authors: Mohd. Setapar, Siti Hamidah, Khatoon, Asma, Ahmad, Akil M., Che Yunus, Mohd. Azizi, Ahmad Zaini, Muhammad Abbas
Format: Article
Published: Chemical Publishing Co. 2014
Subjects:
_version_ 1796861413821513728
author Mohd. Setapar, Siti Hamidah
Khatoon, Asma
Ahmad, Akil M.
Che Yunus, Mohd. Azizi
Ahmad Zaini, Muhammad Abbas
author_facet Mohd. Setapar, Siti Hamidah
Khatoon, Asma
Ahmad, Akil M.
Che Yunus, Mohd. Azizi
Ahmad Zaini, Muhammad Abbas
author_sort Mohd. Setapar, Siti Hamidah
collection ePrints
description Supercritical fluid extraction of α-tocopherol and β-carotenoids from crude palm oil offers an excellent method over other existing conventional methods. Supercritical fluid extraction was developed in the early and mid-1980s to reduce the use of harmful organic solvent in the laboratory. The present paper reviews the applications of supercritical fluid extraction technology in extraction of palm oil using CO2and R 134a fluids. Carbon dioxide is non- toxic, having low critical pressure (74 bar) and temperature (32°C) which minimize the thermal degradation of product but it has a limited dissolving power for solutes of high polarity and high molecular weight in the supercritical state and it also requires higher pressure of upto 500 bar and this high pressure operation requires high operation cost and high capital cost. R134a is an alternative low pressure, non-reactive, non-flammable, non-toxic, non-ozone depleting and has comparable solvent properties as that of CO2. R-134a needs only its temperature or pressure to be controlled in order to control the conditions of extraction or product isolation. This allows simple control of the process.
first_indexed 2024-03-05T19:55:56Z
format Article
id utm.eprints-63181
institution Universiti Teknologi Malaysia - ePrints
last_indexed 2024-03-05T19:55:56Z
publishDate 2014
publisher Chemical Publishing Co.
record_format dspace
spelling utm.eprints-631812017-06-15T02:26:07Z http://eprints.utm.my/63181/ Use of supercritical co2 and r134a as solvent for extraction of beta-carotene and alpha-tocopherols from crude palm oil Mohd. Setapar, Siti Hamidah Khatoon, Asma Ahmad, Akil M. Che Yunus, Mohd. Azizi Ahmad Zaini, Muhammad Abbas QP Physiology Supercritical fluid extraction of α-tocopherol and β-carotenoids from crude palm oil offers an excellent method over other existing conventional methods. Supercritical fluid extraction was developed in the early and mid-1980s to reduce the use of harmful organic solvent in the laboratory. The present paper reviews the applications of supercritical fluid extraction technology in extraction of palm oil using CO2and R 134a fluids. Carbon dioxide is non- toxic, having low critical pressure (74 bar) and temperature (32°C) which minimize the thermal degradation of product but it has a limited dissolving power for solutes of high polarity and high molecular weight in the supercritical state and it also requires higher pressure of upto 500 bar and this high pressure operation requires high operation cost and high capital cost. R134a is an alternative low pressure, non-reactive, non-flammable, non-toxic, non-ozone depleting and has comparable solvent properties as that of CO2. R-134a needs only its temperature or pressure to be controlled in order to control the conditions of extraction or product isolation. This allows simple control of the process. Chemical Publishing Co. 2014 Article PeerReviewed Mohd. Setapar, Siti Hamidah and Khatoon, Asma and Ahmad, Akil M. and Che Yunus, Mohd. Azizi and Ahmad Zaini, Muhammad Abbas (2014) Use of supercritical co2 and r134a as solvent for extraction of beta-carotene and alpha-tocopherols from crude palm oil. Asian Journal of Chemistry, 26 (18). pp. 5911-5916. ISSN 0970-7077 http://dx.doi.org/10.14233/ajchem.2014.16650 DOI :10.14233/ajchem.2014.16650
spellingShingle QP Physiology
Mohd. Setapar, Siti Hamidah
Khatoon, Asma
Ahmad, Akil M.
Che Yunus, Mohd. Azizi
Ahmad Zaini, Muhammad Abbas
Use of supercritical co2 and r134a as solvent for extraction of beta-carotene and alpha-tocopherols from crude palm oil
title Use of supercritical co2 and r134a as solvent for extraction of beta-carotene and alpha-tocopherols from crude palm oil
title_full Use of supercritical co2 and r134a as solvent for extraction of beta-carotene and alpha-tocopherols from crude palm oil
title_fullStr Use of supercritical co2 and r134a as solvent for extraction of beta-carotene and alpha-tocopherols from crude palm oil
title_full_unstemmed Use of supercritical co2 and r134a as solvent for extraction of beta-carotene and alpha-tocopherols from crude palm oil
title_short Use of supercritical co2 and r134a as solvent for extraction of beta-carotene and alpha-tocopherols from crude palm oil
title_sort use of supercritical co2 and r134a as solvent for extraction of beta carotene and alpha tocopherols from crude palm oil
topic QP Physiology
work_keys_str_mv AT mohdsetaparsitihamidah useofsupercriticalco2andr134aassolventforextractionofbetacaroteneandalphatocopherolsfromcrudepalmoil
AT khatoonasma useofsupercriticalco2andr134aassolventforextractionofbetacaroteneandalphatocopherolsfromcrudepalmoil
AT ahmadakilm useofsupercriticalco2andr134aassolventforextractionofbetacaroteneandalphatocopherolsfromcrudepalmoil
AT cheyunusmohdazizi useofsupercriticalco2andr134aassolventforextractionofbetacaroteneandalphatocopherolsfromcrudepalmoil
AT ahmadzainimuhammadabbas useofsupercriticalco2andr134aassolventforextractionofbetacaroteneandalphatocopherolsfromcrudepalmoil