Preparation and Characterization of New Oxide Ion Conductors in Bi2O3-As2O5 System
Materials in xBi2O3-As2O5 binary system: 1 < x < 7, were prepared by solid state reaction. XRD shows that single phase materials were formed when x = 5, 5.5, 5.667, 5.75, 6 and 7. The symmetry and space group of the materials were determined. Compositions with 5 < x < 6.25 are solid solu...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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Institut Kimia Malaysia
2005
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| Online Access: | http://eprints.utm.my/6329/1/paper_Lee_malaysian_journal2005.pdf |
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| author | Lee, S. L. Lee, C. K. Sinclair, D. C. Chong, F. K. Halim, S. A. Yap, T. |
| author_facet | Lee, S. L. Lee, C. K. Sinclair, D. C. Chong, F. K. Halim, S. A. Yap, T. |
| author_sort | Lee, S. L. |
| collection | ePrints |
| description | Materials in xBi2O3-As2O5 binary system: 1 < x < 7, were prepared by solid state reaction. XRD shows that single phase materials were formed when x = 5, 5.5, 5.667, 5.75, 6 and 7. The symmetry and space group of the materials were determined. Compositions with 5 < x < 6.25 are solid solutions. Electrical properties of the single phase materials were studied using ac impedance spectroscopy at a frequency range of 10 Hz to 13 MHz. These materials are thermally stable and appear to be oxide ion conductors. Highest conductivity was obtained in Bi23As4O44.5 with s value of 5.66 x 10-5 ohm-1 cm-1, Ea = 0.72 eV at 300oC. |
| first_indexed | 2024-03-05T18:08:41Z |
| format | Article |
| id | utm.eprints-6329 |
| institution | Universiti Teknologi Malaysia - ePrints |
| language | English |
| last_indexed | 2024-03-05T18:08:41Z |
| publishDate | 2005 |
| publisher | Institut Kimia Malaysia |
| record_format | dspace |
| spelling | utm.eprints-63292010-10-26T04:31:02Z http://eprints.utm.my/6329/ Preparation and Characterization of New Oxide Ion Conductors in Bi2O3-As2O5 System Lee, S. L. Lee, C. K. Sinclair, D. C. Chong, F. K. Halim, S. A. Yap, T. QD Chemistry Materials in xBi2O3-As2O5 binary system: 1 < x < 7, were prepared by solid state reaction. XRD shows that single phase materials were formed when x = 5, 5.5, 5.667, 5.75, 6 and 7. The symmetry and space group of the materials were determined. Compositions with 5 < x < 6.25 are solid solutions. Electrical properties of the single phase materials were studied using ac impedance spectroscopy at a frequency range of 10 Hz to 13 MHz. These materials are thermally stable and appear to be oxide ion conductors. Highest conductivity was obtained in Bi23As4O44.5 with s value of 5.66 x 10-5 ohm-1 cm-1, Ea = 0.72 eV at 300oC. Institut Kimia Malaysia 2005 Article PeerReviewed application/pdf en http://eprints.utm.my/6329/1/paper_Lee_malaysian_journal2005.pdf Lee, S. L. and Lee, C. K. and Sinclair, D. C. and Chong, F. K. and Halim, S. A. and Yap, T. (2005) Preparation and Characterization of New Oxide Ion Conductors in Bi2O3-As2O5 System. Malaysian Journal of Chemistry, 7 (1). pp. 1-10. http://www.ikm.org.my/downloads/JournalPDFs/MJC7_001_010_LeeChnoongKheng.pdf |
| spellingShingle | QD Chemistry Lee, S. L. Lee, C. K. Sinclair, D. C. Chong, F. K. Halim, S. A. Yap, T. Preparation and Characterization of New Oxide Ion Conductors in Bi2O3-As2O5 System |
| title | Preparation and Characterization of New Oxide Ion Conductors in Bi2O3-As2O5 System |
| title_full | Preparation and Characterization of New Oxide Ion Conductors in Bi2O3-As2O5 System |
| title_fullStr | Preparation and Characterization of New Oxide Ion Conductors in Bi2O3-As2O5 System |
| title_full_unstemmed | Preparation and Characterization of New Oxide Ion Conductors in Bi2O3-As2O5 System |
| title_short | Preparation and Characterization of New Oxide Ion Conductors in Bi2O3-As2O5 System |
| title_sort | preparation and characterization of new oxide ion conductors in bi2o3 as2o5 system |
| topic | QD Chemistry |
| url | http://eprints.utm.my/6329/1/paper_Lee_malaysian_journal2005.pdf |
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