Thermal and tensile properties of poly(3- hydroxybutyrate)/ sepiolite nanocomposites

Sepiolite treated using microwave and chemical technique were obtained and compounded with poly(3-hydroxybutyrate) (PHB). The effect of reaction times exposing to the microwave rays was studied and characterized through multipychonometer and scanning electron microscopy (SEM). 12 minutes was found t...

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Main Authors: Ramli, Siti Aishah, Adam, Safirah, Othman, Norhayani
Format: Conference or Workshop Item
Published: 2015
Subjects:
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author Ramli, Siti Aishah
Adam, Safirah
Othman, Norhayani
author_facet Ramli, Siti Aishah
Adam, Safirah
Othman, Norhayani
author_sort Ramli, Siti Aishah
collection ePrints
description Sepiolite treated using microwave and chemical technique were obtained and compounded with poly(3-hydroxybutyrate) (PHB). The effect of reaction times exposing to the microwave rays was studied and characterized through multipychonometer and scanning electron microscopy (SEM). 12 minutes was found to be the optimum reaction time in the microwave. Nanocomposites of PHB with different sepiolite loading (2, 4, 6, 8 and 10 wt %) were prepared using melt mixing. The thermal properties of the PHB nanocommposites were characterized through Differential Scanning Calorimeter (DSC) and Thermogravimetric Analysis (TGA). Addition of 2 wt% sepiolite into PHB increased the melting temperature and percent crystallinity of pure PHB. The crystallinity and melting temperature of PHB nanocomposites increased until 4 wt% loading and remained constant beyond 4 wt% sepiolite. Thermal stability of the nanocomposites slightly improved in the presence of sepiolite. Addition of sepiolite into PHB improved the tensile strength of pure PHB.
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spelling utm.eprints-634552017-05-30T03:52:05Z http://eprints.utm.my/63455/ Thermal and tensile properties of poly(3- hydroxybutyrate)/ sepiolite nanocomposites Ramli, Siti Aishah Adam, Safirah Othman, Norhayani TP Chemical technology Sepiolite treated using microwave and chemical technique were obtained and compounded with poly(3-hydroxybutyrate) (PHB). The effect of reaction times exposing to the microwave rays was studied and characterized through multipychonometer and scanning electron microscopy (SEM). 12 minutes was found to be the optimum reaction time in the microwave. Nanocomposites of PHB with different sepiolite loading (2, 4, 6, 8 and 10 wt %) were prepared using melt mixing. The thermal properties of the PHB nanocommposites were characterized through Differential Scanning Calorimeter (DSC) and Thermogravimetric Analysis (TGA). Addition of 2 wt% sepiolite into PHB increased the melting temperature and percent crystallinity of pure PHB. The crystallinity and melting temperature of PHB nanocomposites increased until 4 wt% loading and remained constant beyond 4 wt% sepiolite. Thermal stability of the nanocomposites slightly improved in the presence of sepiolite. Addition of sepiolite into PHB improved the tensile strength of pure PHB. 2015 Conference or Workshop Item PeerReviewed Ramli, Siti Aishah and Adam, Safirah and Othman, Norhayani (2015) Thermal and tensile properties of poly(3- hydroxybutyrate)/ sepiolite nanocomposites. In: Malaysia Polymer International Conference (MPIC2015), 10-11 June, 2015, Kuala Lumpur, Malaysia. https://conferencealerts.com/show-event?id=146980
spellingShingle TP Chemical technology
Ramli, Siti Aishah
Adam, Safirah
Othman, Norhayani
Thermal and tensile properties of poly(3- hydroxybutyrate)/ sepiolite nanocomposites
title Thermal and tensile properties of poly(3- hydroxybutyrate)/ sepiolite nanocomposites
title_full Thermal and tensile properties of poly(3- hydroxybutyrate)/ sepiolite nanocomposites
title_fullStr Thermal and tensile properties of poly(3- hydroxybutyrate)/ sepiolite nanocomposites
title_full_unstemmed Thermal and tensile properties of poly(3- hydroxybutyrate)/ sepiolite nanocomposites
title_short Thermal and tensile properties of poly(3- hydroxybutyrate)/ sepiolite nanocomposites
title_sort thermal and tensile properties of poly 3 hydroxybutyrate sepiolite nanocomposites
topic TP Chemical technology
work_keys_str_mv AT ramlisitiaishah thermalandtensilepropertiesofpoly3hydroxybutyratesepiolitenanocomposites
AT adamsafirah thermalandtensilepropertiesofpoly3hydroxybutyratesepiolitenanocomposites
AT othmannorhayani thermalandtensilepropertiesofpoly3hydroxybutyratesepiolitenanocomposites