Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites

The effects of natural rubber (NR) on the mechanical, thermal, and morphological properties of multiwalled carbon nanotube (CNT) reinforced poly(lactic acid) (PLA) nanocomposites prepared by melt blending were investigated. A PLA/NR blend and PLA/CNT nanocomposites were also produced for comparison....

Full description

Bibliographic Details
Main Authors: Mat Desa, M. S. Z., Hassan, A., Arsad, A., Arjmandi, R., Mohammad, N. N. B.
Format: Article
Published: John Wiley and Sons Inc. 2016
Subjects:
_version_ 1796861776648732672
author Mat Desa, M. S. Z.
Hassan, A.
Arsad, A.
Arjmandi, R.
Mohammad, N. N. B.
author_facet Mat Desa, M. S. Z.
Hassan, A.
Arsad, A.
Arjmandi, R.
Mohammad, N. N. B.
author_sort Mat Desa, M. S. Z.
collection ePrints
description The effects of natural rubber (NR) on the mechanical, thermal, and morphological properties of multiwalled carbon nanotube (CNT) reinforced poly(lactic acid) (PLA) nanocomposites prepared by melt blending were investigated. A PLA/NR blend and PLA/CNT nanocomposites were also produced for comparison. The tensile strength and Youngs modulus of PLA/CNT nanocomposites improved significantly, whereas the impact strength decreased compared to neat PLA. The incorporation of NR into PLA/CNT significantly improved the impact strength and elongation at break of the nanocomposites, which showed approximately 200 and 850 increases at 20 wt NR, respectively. However, the tensile strength and Youngs modulus of PLA/NR/CNT nanocomposites decreased compared to PLA/CNT nanocomposites. The morphology analysis showed the homogeneous dispersion of NR particles in PLA/NR/CNT nanocomposites, while CNTs preferentially reside in the NR phase rather than the PLA matrix. In addition, the incorporation of NR into PLA/CNT lowered the thermal stability and glass-transition temperature of the nanocomposites.
first_indexed 2024-03-05T20:01:32Z
format Article
id utm.eprints-71510
institution Universiti Teknologi Malaysia - ePrints
last_indexed 2024-03-05T20:01:32Z
publishDate 2016
publisher John Wiley and Sons Inc.
record_format dspace
spelling utm.eprints-715102017-11-15T03:37:08Z http://eprints.utm.my/71510/ Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites Mat Desa, M. S. Z. Hassan, A. Arsad, A. Arjmandi, R. Mohammad, N. N. B. TP Chemical technology The effects of natural rubber (NR) on the mechanical, thermal, and morphological properties of multiwalled carbon nanotube (CNT) reinforced poly(lactic acid) (PLA) nanocomposites prepared by melt blending were investigated. A PLA/NR blend and PLA/CNT nanocomposites were also produced for comparison. The tensile strength and Youngs modulus of PLA/CNT nanocomposites improved significantly, whereas the impact strength decreased compared to neat PLA. The incorporation of NR into PLA/CNT significantly improved the impact strength and elongation at break of the nanocomposites, which showed approximately 200 and 850 increases at 20 wt NR, respectively. However, the tensile strength and Youngs modulus of PLA/NR/CNT nanocomposites decreased compared to PLA/CNT nanocomposites. The morphology analysis showed the homogeneous dispersion of NR particles in PLA/NR/CNT nanocomposites, while CNTs preferentially reside in the NR phase rather than the PLA matrix. In addition, the incorporation of NR into PLA/CNT lowered the thermal stability and glass-transition temperature of the nanocomposites. John Wiley and Sons Inc. 2016 Article PeerReviewed Mat Desa, M. S. Z. and Hassan, A. and Arsad, A. and Arjmandi, R. and Mohammad, N. N. B. (2016) Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites. Journal of Applied Polymer Science, 133 (48). ISSN 0021-8995 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84983770648&doi=10.1002%2fapp.44344&partnerID=40&md5=c5da4f01be68e9a7f5a79435668c9519
spellingShingle TP Chemical technology
Mat Desa, M. S. Z.
Hassan, A.
Arsad, A.
Arjmandi, R.
Mohammad, N. N. B.
Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites
title Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites
title_full Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites
title_fullStr Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites
title_full_unstemmed Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites
title_short Influence of rubber content on mechanical, thermal, and morphological behavior of natural rubber toughened poly(lactic acid)-multiwalled carbon nanotube nanocomposites
title_sort influence of rubber content on mechanical thermal and morphological behavior of natural rubber toughened poly lactic acid multiwalled carbon nanotube nanocomposites
topic TP Chemical technology
work_keys_str_mv AT matdesamsz influenceofrubbercontentonmechanicalthermalandmorphologicalbehaviorofnaturalrubbertoughenedpolylacticacidmultiwalledcarbonnanotubenanocomposites
AT hassana influenceofrubbercontentonmechanicalthermalandmorphologicalbehaviorofnaturalrubbertoughenedpolylacticacidmultiwalledcarbonnanotubenanocomposites
AT arsada influenceofrubbercontentonmechanicalthermalandmorphologicalbehaviorofnaturalrubbertoughenedpolylacticacidmultiwalledcarbonnanotubenanocomposites
AT arjmandir influenceofrubbercontentonmechanicalthermalandmorphologicalbehaviorofnaturalrubbertoughenedpolylacticacidmultiwalledcarbonnanotubenanocomposites
AT mohammadnnb influenceofrubbercontentonmechanicalthermalandmorphologicalbehaviorofnaturalrubbertoughenedpolylacticacidmultiwalledcarbonnanotubenanocomposites