In situ generated palladium seeds lead to single step bioinspired growth of Au(sbnd)Pd bimetallic nanoparticles with catalytic performance
Au[sbnd]Pd bimetallic nanospheres were synthesized via a green approach based on an in situ seed-mediated growth method using Etlingera elatior (EE) leaf extract as a bioreducing and capping agent. The synthesized bimetallic Au1Pd1, Au1Pd10, Au10Pd1 and monometallic Au and Pd nanoparticles were char...
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| Format: | Article |
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Elsevier Ltd
2016
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| author | Wong, S. T. Shamsuddin, M. Alizadeh, A. Yun, Y. S. |
| author_facet | Wong, S. T. Shamsuddin, M. Alizadeh, A. Yun, Y. S. |
| author_sort | Wong, S. T. |
| collection | ePrints |
| description | Au[sbnd]Pd bimetallic nanospheres were synthesized via a green approach based on an in situ seed-mediated growth method using Etlingera elatior (EE) leaf extract as a bioreducing and capping agent. The synthesized bimetallic Au1Pd1, Au1Pd10, Au10Pd1 and monometallic Au and Pd nanoparticles were characterized using various spectroscopic and microscopic techniques. This study reveals the morphology control of anisotropic Au nanoparticles, which can be achieved by the addition of palladium into the aqueous reaction mixture. Furthermore, the catalytic ability of each nanoparticle to catalyze the reduction of 4-nitrophenol to 4-aminophenol were investigated. The bimetallic nanoparticles are more efficient in catalyzing the reduction of 4-nitrophenol than monometallic Au and Pd whereby the Au1Pd1 was the most efficient, with a rate constant, k, of 24.0 × 10−3 min−1. |
| first_indexed | 2024-03-05T20:02:16Z |
| format | Article |
| id | utm.eprints-71773 |
| institution | Universiti Teknologi Malaysia - ePrints |
| last_indexed | 2024-03-05T20:02:16Z |
| publishDate | 2016 |
| publisher | Elsevier Ltd |
| record_format | dspace |
| spelling | utm.eprints-717732017-11-15T03:10:55Z http://eprints.utm.my/71773/ In situ generated palladium seeds lead to single step bioinspired growth of Au(sbnd)Pd bimetallic nanoparticles with catalytic performance Wong, S. T. Shamsuddin, M. Alizadeh, A. Yun, Y. S. QD Chemistry Au[sbnd]Pd bimetallic nanospheres were synthesized via a green approach based on an in situ seed-mediated growth method using Etlingera elatior (EE) leaf extract as a bioreducing and capping agent. The synthesized bimetallic Au1Pd1, Au1Pd10, Au10Pd1 and monometallic Au and Pd nanoparticles were characterized using various spectroscopic and microscopic techniques. This study reveals the morphology control of anisotropic Au nanoparticles, which can be achieved by the addition of palladium into the aqueous reaction mixture. Furthermore, the catalytic ability of each nanoparticle to catalyze the reduction of 4-nitrophenol to 4-aminophenol were investigated. The bimetallic nanoparticles are more efficient in catalyzing the reduction of 4-nitrophenol than monometallic Au and Pd whereby the Au1Pd1 was the most efficient, with a rate constant, k, of 24.0 × 10−3 min−1. Elsevier Ltd 2016 Article PeerReviewed Wong, S. T. and Shamsuddin, M. and Alizadeh, A. and Yun, Y. S. (2016) In situ generated palladium seeds lead to single step bioinspired growth of Au(sbnd)Pd bimetallic nanoparticles with catalytic performance. Materials Chemistry and Physics, 183 . pp. 356-365. ISSN 0254-0584 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84994004750&doi=10.1016%2fj.matchemphys.2016.08.039&partnerID=40&md5=5d0cea8da404b32d50e3ba3e1eec6178 |
| spellingShingle | QD Chemistry Wong, S. T. Shamsuddin, M. Alizadeh, A. Yun, Y. S. In situ generated palladium seeds lead to single step bioinspired growth of Au(sbnd)Pd bimetallic nanoparticles with catalytic performance |
| title | In situ generated palladium seeds lead to single step bioinspired growth of Au(sbnd)Pd bimetallic nanoparticles with catalytic performance |
| title_full | In situ generated palladium seeds lead to single step bioinspired growth of Au(sbnd)Pd bimetallic nanoparticles with catalytic performance |
| title_fullStr | In situ generated palladium seeds lead to single step bioinspired growth of Au(sbnd)Pd bimetallic nanoparticles with catalytic performance |
| title_full_unstemmed | In situ generated palladium seeds lead to single step bioinspired growth of Au(sbnd)Pd bimetallic nanoparticles with catalytic performance |
| title_short | In situ generated palladium seeds lead to single step bioinspired growth of Au(sbnd)Pd bimetallic nanoparticles with catalytic performance |
| title_sort | in situ generated palladium seeds lead to single step bioinspired growth of au sbnd pd bimetallic nanoparticles with catalytic performance |
| topic | QD Chemistry |
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