Mesostructured TUD-C supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition
Mesostructured Technische Universiteit Delft-Crystalline (TUD-C), a hierarchical zeolitic material with MFI framework was used for the first time as catalyst support for the olefins epoxidation. While TUD-C and molybdena doped titania showed considerably low catalytic activities, the molybdena doped...
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| Format: | Article |
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Elsevier B.V.
2016
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| _version_ | 1796861954813329408 |
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| author | Ooi, Y. K. Yuliati, L. Hartanto, D. Nur, H. Lee, S. L. |
| author_facet | Ooi, Y. K. Yuliati, L. Hartanto, D. Nur, H. Lee, S. L. |
| author_sort | Ooi, Y. K. |
| collection | ePrints |
| description | Mesostructured Technische Universiteit Delft-Crystalline (TUD-C), a hierarchical zeolitic material with MFI framework was used for the first time as catalyst support for the olefins epoxidation. While TUD-C and molybdena doped titania showed considerably low catalytic activities, the molybdena doped titania supported on TUD-C exhibited significantly improved catalytic activities with 100% selectivity. Both properties and catalytic performance of the materials were greatly affected by the molar ratio of Si/Al in the TUD-C. It has been demonstrated that Mo-TiO2 supported on TUD-C with Si/Al = 10 was an excellent oxidative catalyst for epoxidation of various types of olefins. Kinetics study revealed that the catalytic reactions followed the first order model. |
| first_indexed | 2024-03-05T20:04:14Z |
| format | Article |
| id | utm.eprints-72582 |
| institution | Universiti Teknologi Malaysia - ePrints |
| last_indexed | 2024-03-05T20:04:14Z |
| publishDate | 2016 |
| publisher | Elsevier B.V. |
| record_format | dspace |
| spelling | utm.eprints-725822017-11-27T04:10:45Z http://eprints.utm.my/72582/ Mesostructured TUD-C supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition Ooi, Y. K. Yuliati, L. Hartanto, D. Nur, H. Lee, S. L. QD Chemistry Mesostructured Technische Universiteit Delft-Crystalline (TUD-C), a hierarchical zeolitic material with MFI framework was used for the first time as catalyst support for the olefins epoxidation. While TUD-C and molybdena doped titania showed considerably low catalytic activities, the molybdena doped titania supported on TUD-C exhibited significantly improved catalytic activities with 100% selectivity. Both properties and catalytic performance of the materials were greatly affected by the molar ratio of Si/Al in the TUD-C. It has been demonstrated that Mo-TiO2 supported on TUD-C with Si/Al = 10 was an excellent oxidative catalyst for epoxidation of various types of olefins. Kinetics study revealed that the catalytic reactions followed the first order model. Elsevier B.V. 2016 Article PeerReviewed Ooi, Y. K. and Yuliati, L. and Hartanto, D. and Nur, H. and Lee, S. L. (2016) Mesostructured TUD-C supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition. Microporous and Mesoporous Materials, 225 . pp. 411-420. ISSN 1387-1811 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84960431552&doi=10.1016%2fj.micromeso.2016.01.016&partnerID=40&md5=d71c734af05ccf93c6b4288d9c93ea85 |
| spellingShingle | QD Chemistry Ooi, Y. K. Yuliati, L. Hartanto, D. Nur, H. Lee, S. L. Mesostructured TUD-C supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition |
| title | Mesostructured TUD-C supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition |
| title_full | Mesostructured TUD-C supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition |
| title_fullStr | Mesostructured TUD-C supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition |
| title_full_unstemmed | Mesostructured TUD-C supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition |
| title_short | Mesostructured TUD-C supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition |
| title_sort | mesostructured tud c supported molybdena doped titania as high selective oxidative catalyst for olefins epoxidation at ambient condition |
| topic | QD Chemistry |
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