Characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times

Palm shells, which are agricultural by-products from palm oil processing, were used to produce low-cost activated carbons. Effect of different carbonization times (1–4 h) on the biochar and activated carbon properties was investigated. The carbonization was carried out at 700°C followed by CO2 activ...

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Main Authors: Hamza, Usman D., Nasri, Noor S., S. Amin, Nor Aishah, Mohammed, Jibril, M. Zain, Husna
Format: Article
Published: Taylor and Francis Inc. 2016
Subjects:
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author Hamza, Usman D.
Nasri, Noor S.
S. Amin, Nor Aishah
Mohammed, Jibril
M. Zain, Husna
author_facet Hamza, Usman D.
Nasri, Noor S.
S. Amin, Nor Aishah
Mohammed, Jibril
M. Zain, Husna
author_sort Hamza, Usman D.
collection ePrints
description Palm shells, which are agricultural by-products from palm oil processing, were used to produce low-cost activated carbons. Effect of different carbonization times (1–4 h) on the biochar and activated carbon properties was investigated. The carbonization was carried out at 700°C followed by CO2 activation. Carbons were characterized using Fourier transform infrared spectroscopy, ultimate analysis, scanning electron microscopy (SEM), proximate analysis and nitrogen adsorption. The proximate analysis of the palm shell showed low moisture content (5.5%), high percentage of volatile matter (70%), average contents of fixed carbon (23%) and ash content (4.28%). Carbonization times (1–4 h) within the range investigated have little influence on the char yield, thermal and chemical properties of the material but had more effect on the textural properties. SEM micrographs revealed that more pore networks and cavities were formed after carbonization and activation of the palm shells. The textural characteristics of the biochars and activated carbon reveal that the pore size is predominantly mesoporous. The properties of the palm shell activated carbon prepared at 700°C for 2 h indicated its ability to be used in volatile organics removal from wastewater and in gas-related adsorption applications.
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spelling utm.eprints-726352017-11-22T12:07:33Z http://eprints.utm.my/72635/ Characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times Hamza, Usman D. Nasri, Noor S. S. Amin, Nor Aishah Mohammed, Jibril M. Zain, Husna TP Chemical technology Palm shells, which are agricultural by-products from palm oil processing, were used to produce low-cost activated carbons. Effect of different carbonization times (1–4 h) on the biochar and activated carbon properties was investigated. The carbonization was carried out at 700°C followed by CO2 activation. Carbons were characterized using Fourier transform infrared spectroscopy, ultimate analysis, scanning electron microscopy (SEM), proximate analysis and nitrogen adsorption. The proximate analysis of the palm shell showed low moisture content (5.5%), high percentage of volatile matter (70%), average contents of fixed carbon (23%) and ash content (4.28%). Carbonization times (1–4 h) within the range investigated have little influence on the char yield, thermal and chemical properties of the material but had more effect on the textural properties. SEM micrographs revealed that more pore networks and cavities were formed after carbonization and activation of the palm shells. The textural characteristics of the biochars and activated carbon reveal that the pore size is predominantly mesoporous. The properties of the palm shell activated carbon prepared at 700°C for 2 h indicated its ability to be used in volatile organics removal from wastewater and in gas-related adsorption applications. Taylor and Francis Inc. 2016 Article PeerReviewed Hamza, Usman D. and Nasri, Noor S. and S. Amin, Nor Aishah and Mohammed, Jibril and M. Zain, Husna (2016) Characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times. Desalination and Water Treatment, 57 (17). pp. 7999-8006. ISSN 1944-3994 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84957839066&doi=10.1080%2f19443994.2015.1042068&partnerID=40&md5=819a5d09937084319ab36f4cb5a5400f
spellingShingle TP Chemical technology
Hamza, Usman D.
Nasri, Noor S.
S. Amin, Nor Aishah
Mohammed, Jibril
M. Zain, Husna
Characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times
title Characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times
title_full Characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times
title_fullStr Characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times
title_full_unstemmed Characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times
title_short Characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times
title_sort characteristics of oil palm shell biochar and activated carbon prepared at different carbonization times
topic TP Chemical technology
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AT saminnoraishah characteristicsofoilpalmshellbiocharandactivatedcarbonpreparedatdifferentcarbonizationtimes
AT mohammedjibril characteristicsofoilpalmshellbiocharandactivatedcarbonpreparedatdifferentcarbonizationtimes
AT mzainhusna characteristicsofoilpalmshellbiocharandactivatedcarbonpreparedatdifferentcarbonizationtimes