Heterogeneous transesterification of rubber seed oil biodiesel production
An experimental investigation was conducted to explore the effects of using waste cockle shells as a heterogeneous catalyst on the transesterification process of very high free fatty acid (FFA) rubber seeds oil with methanol. The waste cockle was calcined at 900°C for 4 hours and was employed as a s...
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Penerbit UTM Press
2016
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Online Access: | http://eprints.utm.my/74298/1/MahanumMohdZamberi2016_HeterogeneousTransesterificationofRubberSeedOil.pdf |
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author | Zamberi, M. M. Ani, F. N. Abdollah, M. F. |
author_facet | Zamberi, M. M. Ani, F. N. Abdollah, M. F. |
author_sort | Zamberi, M. M. |
collection | ePrints |
description | An experimental investigation was conducted to explore the effects of using waste cockle shells as a heterogeneous catalyst on the transesterification process of very high free fatty acid (FFA) rubber seeds oil with methanol. The waste cockle was calcined at 900°C for 4 hours and was employed as a source of calcium oxide (CaO). SEM, XRD and XRF were adopted to analyze the catalyst characterization. The process variables namely oil molar ratio, catalyst concentration and reaction time were optimized using response surface methodology (RSM) based on central composite design (CCD) method. The optimum yield of 88.06% was obtained for the final product of biodiesel with optimal conditions was obtained as: molar ratio of methanol to oil of around 15.57:1, 9% catalyst weight percentage with 2.81 hours reaction time. All the fuel properties were analyzed according to the ASTM D6751 and EN-14214 standards in terms of viscosity, acid value, density and flash point. |
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format | Article |
id | utm.eprints-74298 |
institution | Universiti Teknologi Malaysia - ePrints |
language | English |
last_indexed | 2024-03-05T20:07:48Z |
publishDate | 2016 |
publisher | Penerbit UTM Press |
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spelling | utm.eprints-742982017-11-22T12:07:41Z http://eprints.utm.my/74298/ Heterogeneous transesterification of rubber seed oil biodiesel production Zamberi, M. M. Ani, F. N. Abdollah, M. F. TJ Mechanical engineering and machinery An experimental investigation was conducted to explore the effects of using waste cockle shells as a heterogeneous catalyst on the transesterification process of very high free fatty acid (FFA) rubber seeds oil with methanol. The waste cockle was calcined at 900°C for 4 hours and was employed as a source of calcium oxide (CaO). SEM, XRD and XRF were adopted to analyze the catalyst characterization. The process variables namely oil molar ratio, catalyst concentration and reaction time were optimized using response surface methodology (RSM) based on central composite design (CCD) method. The optimum yield of 88.06% was obtained for the final product of biodiesel with optimal conditions was obtained as: molar ratio of methanol to oil of around 15.57:1, 9% catalyst weight percentage with 2.81 hours reaction time. All the fuel properties were analyzed according to the ASTM D6751 and EN-14214 standards in terms of viscosity, acid value, density and flash point. Penerbit UTM Press 2016 Article PeerReviewed application/pdf en http://eprints.utm.my/74298/1/MahanumMohdZamberi2016_HeterogeneousTransesterificationofRubberSeedOil.pdf Zamberi, M. M. and Ani, F. N. and Abdollah, M. F. (2016) Heterogeneous transesterification of rubber seed oil biodiesel production. Jurnal Teknologi, 78 (6-10). pp. 105-110. ISSN 0127-9696 https://www.scopus.com/inward/record.uri?eid=2-s2.0-84975720731&partnerID=40&md5=718aba2ea37760a3bb69a5f0299cd96e |
spellingShingle | TJ Mechanical engineering and machinery Zamberi, M. M. Ani, F. N. Abdollah, M. F. Heterogeneous transesterification of rubber seed oil biodiesel production |
title | Heterogeneous transesterification of rubber seed oil biodiesel production |
title_full | Heterogeneous transesterification of rubber seed oil biodiesel production |
title_fullStr | Heterogeneous transesterification of rubber seed oil biodiesel production |
title_full_unstemmed | Heterogeneous transesterification of rubber seed oil biodiesel production |
title_short | Heterogeneous transesterification of rubber seed oil biodiesel production |
title_sort | heterogeneous transesterification of rubber seed oil biodiesel production |
topic | TJ Mechanical engineering and machinery |
url | http://eprints.utm.my/74298/1/MahanumMohdZamberi2016_HeterogeneousTransesterificationofRubberSeedOil.pdf |
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