Spectroscopic studies of TeO2-ZnO-Er2O3 glass system

Series of glass based on the (80 − x)TeO2–20ZnO–(x)Er2O3 system (0.5 mol% ≤ x ≤ 2.5 mol%) has successfully been made by melt quenching technique. The optical properties of glass have been investigated by means of IR and Raman spectroscopy. It is observed that as the Er2O3 content is being...

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Main Authors: Sahar, Md Rahim, Sulhadi, K., Rohani, M.S.
Format: Article
Language:English
Published: Springer Netherlands 2007
Subjects:
Online Access:http://eprints.utm.my/7528/1/Md_Rahim_Sahar_2007_Spectroscopic_Studies_of_TeO2%C3%A2%E2%82%AC%E2%80%9CZnO%C3%A2%E2%82%AC%E2%80%9CEr2O3.pdf
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author Sahar, Md Rahim
Sulhadi, K.
Rohani, M.S.
author_facet Sahar, Md Rahim
Sulhadi, K.
Rohani, M.S.
author_sort Sahar, Md Rahim
collection ePrints
description Series of glass based on the (80 − x)TeO2–20ZnO–(x)Er2O3 system (0.5 mol% ≤ x ≤ 2.5 mol%) has successfully been made by melt quenching technique. The optical properties of glass have been investigated by means of IR and Raman spectroscopy. It is observed that as the Er2O3 content is being increased, the sharp IR absorption peaks are consistently shifted from 650 to 672 cm−1 while the Raman shift intensity around 640–670 cm−1 is decreases but increases around 720–740 cm−1. It is found out that both phenomenons are related to the structural changes between the stretching vibration mode of TeO4 tbp and TeO3 tp, and bending vibration mode of Te–O bonds in the glass linkages.
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spelling utm.eprints-75282017-10-23T03:55:54Z http://eprints.utm.my/7528/ Spectroscopic studies of TeO2-ZnO-Er2O3 glass system Sahar, Md Rahim Sulhadi, K. Rohani, M.S. QD Chemistry Series of glass based on the (80 − x)TeO2–20ZnO–(x)Er2O3 system (0.5 mol% ≤ x ≤ 2.5 mol%) has successfully been made by melt quenching technique. The optical properties of glass have been investigated by means of IR and Raman spectroscopy. It is observed that as the Er2O3 content is being increased, the sharp IR absorption peaks are consistently shifted from 650 to 672 cm−1 while the Raman shift intensity around 640–670 cm−1 is decreases but increases around 720–740 cm−1. It is found out that both phenomenons are related to the structural changes between the stretching vibration mode of TeO4 tbp and TeO3 tp, and bending vibration mode of Te–O bonds in the glass linkages. Springer Netherlands 2007-02 Article PeerReviewed application/pdf en http://eprints.utm.my/7528/1/Md_Rahim_Sahar_2007_Spectroscopic_Studies_of_TeO2%C3%A2%E2%82%AC%E2%80%9CZnO%C3%A2%E2%82%AC%E2%80%9CEr2O3.pdf Sahar, Md Rahim and Sulhadi, K. and Rohani, M.S. (2007) Spectroscopic studies of TeO2-ZnO-Er2O3 glass system. Journal of Materials Science, 42 (3). pp. 824-827. ISSN 1573-4803 http://dx.doi.org/10.1007/s10853-006-0095-7 10.1007/s10853-006-0095-7
spellingShingle QD Chemistry
Sahar, Md Rahim
Sulhadi, K.
Rohani, M.S.
Spectroscopic studies of TeO2-ZnO-Er2O3 glass system
title Spectroscopic studies of TeO2-ZnO-Er2O3 glass system
title_full Spectroscopic studies of TeO2-ZnO-Er2O3 glass system
title_fullStr Spectroscopic studies of TeO2-ZnO-Er2O3 glass system
title_full_unstemmed Spectroscopic studies of TeO2-ZnO-Er2O3 glass system
title_short Spectroscopic studies of TeO2-ZnO-Er2O3 glass system
title_sort spectroscopic studies of teo2 zno er2o3 glass system
topic QD Chemistry
url http://eprints.utm.my/7528/1/Md_Rahim_Sahar_2007_Spectroscopic_Studies_of_TeO2%C3%A2%E2%82%AC%E2%80%9CZnO%C3%A2%E2%82%AC%E2%80%9CEr2O3.pdf
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