CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state
Carbon dioxide (CO2) solubility was measured in aqueous solutions containing 0.6 wt% D(+)-galacturonic acid (GalH) or sodium D(+)-galacturonate (GalNa) by use of a recirculating apparatus at 313.4 K and at pressures up to 9.29 MPa. The solubilities of CO2 in the two solutions containing GalH or GalN...
Main Authors: | , , , , , |
---|---|
Format: | Article |
Published: |
Elsevier B.V.
2017
|
Subjects: |
_version_ | 1796862458900512768 |
---|---|
author | Tsuji, T. Shigeru, M. Hoshina, T. A. Yoneda, K. Funazukuri, T. Morad, N. A. |
author_facet | Tsuji, T. Shigeru, M. Hoshina, T. A. Yoneda, K. Funazukuri, T. Morad, N. A. |
author_sort | Tsuji, T. |
collection | ePrints |
description | Carbon dioxide (CO2) solubility was measured in aqueous solutions containing 0.6 wt% D(+)-galacturonic acid (GalH) or sodium D(+)-galacturonate (GalNa) by use of a recirculating apparatus at 313.4 K and at pressures up to 9.29 MPa. The solubilities of CO2 in the two solutions containing GalH or GalNa were similar to those in pure water. The experimental data were correlated with the Peng-Robinson-Stryjek-Vera (PRSV) equation of state. A new method was developed to estimate pH by use of the molar volume from the PRSV equation and compared with measured pH values. It gives some idea of the quantitative agreement between the equation of states and the measured pH values over the same range of conditions. |
first_indexed | 2024-03-05T20:11:56Z |
format | Article |
id | utm.eprints-76179 |
institution | Universiti Teknologi Malaysia - ePrints |
last_indexed | 2024-03-05T20:11:56Z |
publishDate | 2017 |
publisher | Elsevier B.V. |
record_format | dspace |
spelling | utm.eprints-761792018-06-25T09:06:30Z http://eprints.utm.my/76179/ CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state Tsuji, T. Shigeru, M. Hoshina, T. A. Yoneda, K. Funazukuri, T. Morad, N. A. T Technology (General) Carbon dioxide (CO2) solubility was measured in aqueous solutions containing 0.6 wt% D(+)-galacturonic acid (GalH) or sodium D(+)-galacturonate (GalNa) by use of a recirculating apparatus at 313.4 K and at pressures up to 9.29 MPa. The solubilities of CO2 in the two solutions containing GalH or GalNa were similar to those in pure water. The experimental data were correlated with the Peng-Robinson-Stryjek-Vera (PRSV) equation of state. A new method was developed to estimate pH by use of the molar volume from the PRSV equation and compared with measured pH values. It gives some idea of the quantitative agreement between the equation of states and the measured pH values over the same range of conditions. Elsevier B.V. 2017 Article PeerReviewed Tsuji, T. and Shigeru, M. and Hoshina, T. A. and Yoneda, K. and Funazukuri, T. and Morad, N. A. (2017) CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state. Fluid Phase Equilibria, 441 . pp. 9-16. ISSN 0378-3812 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85015644086&doi=10.1016%2fj.fluid.2017.03.005&partnerID=40&md5=3de1a437dc5d7d770d62ebe10e070a09 |
spellingShingle | T Technology (General) Tsuji, T. Shigeru, M. Hoshina, T. A. Yoneda, K. Funazukuri, T. Morad, N. A. CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state |
title | CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state |
title_full | CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state |
title_fullStr | CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state |
title_full_unstemmed | CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state |
title_short | CO2 solubility in water containing monosaccharides, and the prediction of pH using Peng-Robinson equation of state |
title_sort | co2 solubility in water containing monosaccharides and the prediction of ph using peng robinson equation of state |
topic | T Technology (General) |
work_keys_str_mv | AT tsujit co2solubilityinwatercontainingmonosaccharidesandthepredictionofphusingpengrobinsonequationofstate AT shigerum co2solubilityinwatercontainingmonosaccharidesandthepredictionofphusingpengrobinsonequationofstate AT hoshinata co2solubilityinwatercontainingmonosaccharidesandthepredictionofphusingpengrobinsonequationofstate AT yonedak co2solubilityinwatercontainingmonosaccharidesandthepredictionofphusingpengrobinsonequationofstate AT funazukurit co2solubilityinwatercontainingmonosaccharidesandthepredictionofphusingpengrobinsonequationofstate AT moradna co2solubilityinwatercontainingmonosaccharidesandthepredictionofphusingpengrobinsonequationofstate |