Bio-inspired, fouling resistant, tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation

Superficial functionalization of the hollow fiber membrane with progressive nanomaterials exhibits increased hydrophilicity, outstanding selectivity, and permeability. In the present study, a simple and novel loose nanofiltration (NF) membranes were prepared by the addition of tannic acid functional...

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Main Authors: Ibrahim, G. P. S., Isloor, A. M., Moslehyani, A., Ismail, A. F.
Format: Article
Published: Elsevier Ltd 2017
Subjects:
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author Ibrahim, G. P. S.
Isloor, A. M.
Moslehyani, A.
Ismail, A. F.
author_facet Ibrahim, G. P. S.
Isloor, A. M.
Moslehyani, A.
Ismail, A. F.
author_sort Ibrahim, G. P. S.
collection ePrints
description Superficial functionalization of the hollow fiber membrane with progressive nanomaterials exhibits increased hydrophilicity, outstanding selectivity, and permeability. In the present study, a simple and novel loose nanofiltration (NF) membranes were prepared by the addition of tannic acid functionalized halloysite nanotubes (THNTs) in polysulfone (PSf) membrane matrix via phase inversion method. The successful modification of halloysite (HNTs) was confirmed by FT-IR, zeta potential measurement, TGA, TEM and EDX analysis. The membrane permeation studies were carried out with a sequence of salts (NaCl and Na2SO4) and dyes (reactive black 5 and reactive orange 16). The resulted membranes exhibited increased hydrophilicity, porosity, water uptake, antifouling performance, along with higher dye rejection (>99% for reactive black 5 and >90% of reactive orange 16) and low salt rejection (2.5% of NaCl and 7.5% of Na2SO4) properties. The nanocomposite membrane also exhibited the highest pure water flux of 92 L/m2 h compared to the pristine membrane of 18 L/m2 h made it a worthy candidate for the wastewater purification.
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spelling utm.eprints-766752018-04-30T13:48:48Z http://eprints.utm.my/76675/ Bio-inspired, fouling resistant, tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation Ibrahim, G. P. S. Isloor, A. M. Moslehyani, A. Ismail, A. F. TP Chemical technology Superficial functionalization of the hollow fiber membrane with progressive nanomaterials exhibits increased hydrophilicity, outstanding selectivity, and permeability. In the present study, a simple and novel loose nanofiltration (NF) membranes were prepared by the addition of tannic acid functionalized halloysite nanotubes (THNTs) in polysulfone (PSf) membrane matrix via phase inversion method. The successful modification of halloysite (HNTs) was confirmed by FT-IR, zeta potential measurement, TGA, TEM and EDX analysis. The membrane permeation studies were carried out with a sequence of salts (NaCl and Na2SO4) and dyes (reactive black 5 and reactive orange 16). The resulted membranes exhibited increased hydrophilicity, porosity, water uptake, antifouling performance, along with higher dye rejection (>99% for reactive black 5 and >90% of reactive orange 16) and low salt rejection (2.5% of NaCl and 7.5% of Na2SO4) properties. The nanocomposite membrane also exhibited the highest pure water flux of 92 L/m2 h compared to the pristine membrane of 18 L/m2 h made it a worthy candidate for the wastewater purification. Elsevier Ltd 2017 Article PeerReviewed Ibrahim, G. P. S. and Isloor, A. M. and Moslehyani, A. and Ismail, A. F. (2017) Bio-inspired, fouling resistant, tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation. Journal of Water Process Engineering, 20 . pp. 138-148. ISSN 2214-7144 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85032290871&doi=10.1016%2fj.jwpe.2017.09.015&partnerID=40&md5=0203713b1814c09fccb8f3b3eb93095e DOI:10.1016/j.jwpe.2017.09.015
spellingShingle TP Chemical technology
Ibrahim, G. P. S.
Isloor, A. M.
Moslehyani, A.
Ismail, A. F.
Bio-inspired, fouling resistant, tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation
title Bio-inspired, fouling resistant, tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation
title_full Bio-inspired, fouling resistant, tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation
title_fullStr Bio-inspired, fouling resistant, tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation
title_full_unstemmed Bio-inspired, fouling resistant, tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation
title_short Bio-inspired, fouling resistant, tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation
title_sort bio inspired fouling resistant tannic acid functionalized halloysite nanotube reinforced polysulfone loose nanofiltration hollow fiber membranes for efficient dye and salt separation
topic TP Chemical technology
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