Effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil

The present work is aimed to study the influence of membrane internal structure on the extracting performance of hollow fiber membrane contactor system in removing free fatty acid (FFA) from crude palm oil (CPO). Polyphenylsulfone (PPSU) hollow fiber membrane were prepared via wet spinning method. D...

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Main Authors: Noor Hidayu, O., Ahmadilfitri Md., N., Mohd. Suria Affandi, Y., Pei Sean, G., Ahmad Fauzi, I., Woei Jye, L., Be Cheer, N., Norafiqah, I.
Format: Article
Published: Malaysian Society of Analytical Sciences 2017
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author Noor Hidayu, O.
Ahmadilfitri Md., N.
Mohd. Suria Affandi, Y.
Pei Sean, G.
Ahmad Fauzi, I.
Woei Jye, L.
Be Cheer, N.
Norafiqah, I.
author_facet Noor Hidayu, O.
Ahmadilfitri Md., N.
Mohd. Suria Affandi, Y.
Pei Sean, G.
Ahmad Fauzi, I.
Woei Jye, L.
Be Cheer, N.
Norafiqah, I.
author_sort Noor Hidayu, O.
collection ePrints
description The present work is aimed to study the influence of membrane internal structure on the extracting performance of hollow fiber membrane contactor system in removing free fatty acid (FFA) from crude palm oil (CPO). Polyphenylsulfone (PPSU) hollow fiber membrane were prepared via wet spinning method. Different bore fluid composition were employed mainly consisted of distilled water in combination with 0, 20, 30 and 40 wt.% N-methyl-2pyrrolidone (NMP). The resulting membranes structure were characterized for membrane morphology, membrane wettability and membrane pore size. The used of pure distilled water as membrane BF had created a large macrovoid structure with uniform and tiny finger-liked morphology at the outer membrane layer. Meanwhile, the present of NMP in BF composition had obviously changed the internal layer of 14PPSU membrane to more interconnected double-layers of finger-liked morphology. However, there are not much different in membrane wettability and pore size of 14PPSU membrane were recorded. All PPSU hollow fiber membranes were further evaluated for deacidification performance through membrane contactor with sodium hydroxide (NaOH) as liquid extractant. 14PPSU-100:0 membrane contactor that prepared from100% distilled water as BF composition demonstrated the highest FFA removal of 16.54% without soap formation in oil permeate stream.
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spelling utm.eprints-768182018-04-30T14:10:29Z http://eprints.utm.my/76818/ Effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil Noor Hidayu, O. Ahmadilfitri Md., N. Mohd. Suria Affandi, Y. Pei Sean, G. Ahmad Fauzi, I. Woei Jye, L. Be Cheer, N. Norafiqah, I. QD Chemistry The present work is aimed to study the influence of membrane internal structure on the extracting performance of hollow fiber membrane contactor system in removing free fatty acid (FFA) from crude palm oil (CPO). Polyphenylsulfone (PPSU) hollow fiber membrane were prepared via wet spinning method. Different bore fluid composition were employed mainly consisted of distilled water in combination with 0, 20, 30 and 40 wt.% N-methyl-2pyrrolidone (NMP). The resulting membranes structure were characterized for membrane morphology, membrane wettability and membrane pore size. The used of pure distilled water as membrane BF had created a large macrovoid structure with uniform and tiny finger-liked morphology at the outer membrane layer. Meanwhile, the present of NMP in BF composition had obviously changed the internal layer of 14PPSU membrane to more interconnected double-layers of finger-liked morphology. However, there are not much different in membrane wettability and pore size of 14PPSU membrane were recorded. All PPSU hollow fiber membranes were further evaluated for deacidification performance through membrane contactor with sodium hydroxide (NaOH) as liquid extractant. 14PPSU-100:0 membrane contactor that prepared from100% distilled water as BF composition demonstrated the highest FFA removal of 16.54% without soap formation in oil permeate stream. Malaysian Society of Analytical Sciences 2017 Article PeerReviewed Noor Hidayu, O. and Ahmadilfitri Md., N. and Mohd. Suria Affandi, Y. and Pei Sean, G. and Ahmad Fauzi, I. and Woei Jye, L. and Be Cheer, N. and Norafiqah, I. (2017) Effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil. Malaysian Journal of Analytical Sciences, 21 (3). pp. 633-642. ISSN 1394-2506 https://www.scopus.com/inward/record.uri?eid=2-s2.0-85021131901&doi=10.17576%2fmjas-2017-2103-13&partnerID=40&md5=737985bb48888f5f35375383a7d0884b DOI:10.17576/mjas-2017-2103-13
spellingShingle QD Chemistry
Noor Hidayu, O.
Ahmadilfitri Md., N.
Mohd. Suria Affandi, Y.
Pei Sean, G.
Ahmad Fauzi, I.
Woei Jye, L.
Be Cheer, N.
Norafiqah, I.
Effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil
title Effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil
title_full Effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil
title_fullStr Effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil
title_full_unstemmed Effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil
title_short Effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil
title_sort effect of bore fluid composition on structural and performance of polyphenylsulfone hollow fiber membrane contactor for deacdification of crude palm oil
topic QD Chemistry
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