Comparing the degradation of Poly-B-(hydroxybutyrate), poly-B-(hydroxbutyrate-co-valerate)(PHBV) and PHBV/cellulose tricate blend
The hydrolytic degradation of poly-b-(hydroxybutyrate) PHB, poly-b- (hydroxybutyrate-co-b-valerate) (PHBV) and PHBV/cellulose triacetate blend was sutnuddeire dd ifferent pH at 37 °C. PHBV showed a similar trend of degradation to PHB but at rhaitgehse irn alkaline medium. The presence of cellulo...
Main Authors: | , , |
---|---|
Format: | Article |
Language: | English |
Published: |
Plastics and Rubber Institute of Malaysia
2006
|
Subjects: | |
Online Access: | http://eprints.utm.my/8108/1/8108.pdf |
_version_ | 1825910149232984064 |
---|---|
author | Muhamad, Ida Idayu Lee, Kar Joon Mohd. Noor, Mohd. Azemi |
author_facet | Muhamad, Ida Idayu Lee, Kar Joon Mohd. Noor, Mohd. Azemi |
author_sort | Muhamad, Ida Idayu |
collection | ePrints |
description | The hydrolytic degradation of poly-b-(hydroxybutyrate) PHB, poly-b-
(hydroxybutyrate-co-b-valerate) (PHBV) and PHBV/cellulose triacetate blend was
sutnuddeire dd ifferent pH at 37 °C. PHBV showed a similar trend of degradation to PHB but at
rhaitgehse irn alkaline medium. The presence of cellulose triacetate in the blend increased the
water uptake and permeability which favoured the hydrolytic degradation especially in
lpoHw mere dium. In the surface hydrolysis of PHB and its blends, the overall degradation rate was
increased with higher pH values. The melting temperature, crystallinity and tensile properties
were also determined. The blend, PHBV/CTAc had the lowest crystallinity values and
hPaHdB t he highest. However, the blends were mechanically better in strength and
toughness |
first_indexed | 2024-03-05T18:12:43Z |
format | Article |
id | utm.eprints-8108 |
institution | Universiti Teknologi Malaysia - ePrints |
language | English |
last_indexed | 2024-03-05T18:12:43Z |
publishDate | 2006 |
publisher | Plastics and Rubber Institute of Malaysia |
record_format | dspace |
spelling | utm.eprints-81082012-08-28T02:29:14Z http://eprints.utm.my/8108/ Comparing the degradation of Poly-B-(hydroxybutyrate), poly-B-(hydroxbutyrate-co-valerate)(PHBV) and PHBV/cellulose tricate blend Muhamad, Ida Idayu Lee, Kar Joon Mohd. Noor, Mohd. Azemi TP Chemical technology The hydrolytic degradation of poly-b-(hydroxybutyrate) PHB, poly-b- (hydroxybutyrate-co-b-valerate) (PHBV) and PHBV/cellulose triacetate blend was sutnuddeire dd ifferent pH at 37 °C. PHBV showed a similar trend of degradation to PHB but at rhaitgehse irn alkaline medium. The presence of cellulose triacetate in the blend increased the water uptake and permeability which favoured the hydrolytic degradation especially in lpoHw mere dium. In the surface hydrolysis of PHB and its blends, the overall degradation rate was increased with higher pH values. The melting temperature, crystallinity and tensile properties were also determined. The blend, PHBV/CTAc had the lowest crystallinity values and hPaHdB t he highest. However, the blends were mechanically better in strength and toughness Plastics and Rubber Institute of Malaysia 2006 Article PeerReviewed application/pdf en http://eprints.utm.my/8108/1/8108.pdf Muhamad, Ida Idayu and Lee, Kar Joon and Mohd. Noor, Mohd. Azemi (2006) Comparing the degradation of Poly-B-(hydroxybutyrate), poly-B-(hydroxbutyrate-co-valerate)(PHBV) and PHBV/cellulose tricate blend. Malaysian Polymer Journal, 1 (1). pp. 39-46. ISSN 1823-7789 http://www.fkkksa.utm.my/mpj/images/04idayu.pdf |
spellingShingle | TP Chemical technology Muhamad, Ida Idayu Lee, Kar Joon Mohd. Noor, Mohd. Azemi Comparing the degradation of Poly-B-(hydroxybutyrate), poly-B-(hydroxbutyrate-co-valerate)(PHBV) and PHBV/cellulose tricate blend |
title | Comparing the degradation of Poly-B-(hydroxybutyrate), poly-B-(hydroxbutyrate-co-valerate)(PHBV) and PHBV/cellulose tricate blend |
title_full | Comparing the degradation of Poly-B-(hydroxybutyrate), poly-B-(hydroxbutyrate-co-valerate)(PHBV) and PHBV/cellulose tricate blend |
title_fullStr | Comparing the degradation of Poly-B-(hydroxybutyrate), poly-B-(hydroxbutyrate-co-valerate)(PHBV) and PHBV/cellulose tricate blend |
title_full_unstemmed | Comparing the degradation of Poly-B-(hydroxybutyrate), poly-B-(hydroxbutyrate-co-valerate)(PHBV) and PHBV/cellulose tricate blend |
title_short | Comparing the degradation of Poly-B-(hydroxybutyrate), poly-B-(hydroxbutyrate-co-valerate)(PHBV) and PHBV/cellulose tricate blend |
title_sort | comparing the degradation of poly b hydroxybutyrate poly b hydroxbutyrate co valerate phbv and phbv cellulose tricate blend |
topic | TP Chemical technology |
url | http://eprints.utm.my/8108/1/8108.pdf |
work_keys_str_mv | AT muhamadidaidayu comparingthedegradationofpolybhydroxybutyratepolybhydroxbutyratecovaleratephbvandphbvcellulosetricateblend AT leekarjoon comparingthedegradationofpolybhydroxybutyratepolybhydroxbutyratecovaleratephbvandphbvcellulosetricateblend AT mohdnoormohdazemi comparingthedegradationofpolybhydroxybutyratepolybhydroxbutyratecovaleratephbvandphbvcellulosetricateblend |