PVDF/Fe2O3 mixed matrix membrane for oily wastewater treatment

Oily wastewater has been recognized as one of the most concerned environmental pollutions that come from a variety of sources. The increasing of these uncontrollable oily wastewater discharges consequently leads to environmental problems. The current barrier in this situation is when dealing with fi...

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Main Authors: Ismail, Nor Hafiza, Wan Salleh, Wan Norharyati, Rosman, Nurafiqah, Awang, Nor Asikin, Hasbullah, Hasrinah, Aziz, Farhana, Yusof, Norhaniza
Format: Article
Language:English
Published: Penerbit UTM Press 2019
Subjects:
Online Access:http://eprints.utm.my/85041/1/WanNorharyatiWanSalleh2019_PVDFFe2O3mixedMatrixMembraneforOily.pdf
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author Ismail, Nor Hafiza
Wan Salleh, Wan Norharyati
Rosman, Nurafiqah
Awang, Nor Asikin
Hasbullah, Hasrinah
Aziz, Farhana
Yusof, Norhaniza
author_facet Ismail, Nor Hafiza
Wan Salleh, Wan Norharyati
Rosman, Nurafiqah
Awang, Nor Asikin
Hasbullah, Hasrinah
Aziz, Farhana
Yusof, Norhaniza
author_sort Ismail, Nor Hafiza
collection ePrints
description Oily wastewater has been recognized as one of the most concerned environmental pollutions that come from a variety of sources. The increasing of these uncontrollable oily wastewater discharges consequently leads to environmental problems. The current barrier in this situation is when dealing with finely emulsified oily wastewater streams with small droplet size (< 20 μm in diameter). To tackle this issue, it is found that the utilization of the membrane technology is most effective due to its highly effective separation process and simplicity. Nevertheless, traditional filtration membranes are mostly afflicted with low flux and rejection rate as a consequence of easy fouling caused by the plugging of oil and surfactant. Thus, the wettability and antifouling properties of the membrane play an important role in dealing with this issue. The aim of this study was to evaluate the performance and operation of the membrane when treating oily wastewater. PVDF was chosen as the host polymer based on its outstanding properties and 0.2 wt% of Fe2O3 loading was utilized to enhance the hydrophilicity of the membrane. The effects of mixed matrix membrane (MMM) and neat poly (vinylidene fluoride) (PVDF) membrane relating to their differences in the SEM images, water flux and oil rejection were studied. The presence of additive in the polymeric composition has helped to achieve 40% higher flux increment with an oil removal efficacy of ~97 %, as compared to the unmodified PVDF membrane.
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spelling utm.eprints-850412020-02-29T13:22:35Z http://eprints.utm.my/85041/ PVDF/Fe2O3 mixed matrix membrane for oily wastewater treatment Ismail, Nor Hafiza Wan Salleh, Wan Norharyati Rosman, Nurafiqah Awang, Nor Asikin Hasbullah, Hasrinah Aziz, Farhana Yusof, Norhaniza TP Chemical technology Oily wastewater has been recognized as one of the most concerned environmental pollutions that come from a variety of sources. The increasing of these uncontrollable oily wastewater discharges consequently leads to environmental problems. The current barrier in this situation is when dealing with finely emulsified oily wastewater streams with small droplet size (< 20 μm in diameter). To tackle this issue, it is found that the utilization of the membrane technology is most effective due to its highly effective separation process and simplicity. Nevertheless, traditional filtration membranes are mostly afflicted with low flux and rejection rate as a consequence of easy fouling caused by the plugging of oil and surfactant. Thus, the wettability and antifouling properties of the membrane play an important role in dealing with this issue. The aim of this study was to evaluate the performance and operation of the membrane when treating oily wastewater. PVDF was chosen as the host polymer based on its outstanding properties and 0.2 wt% of Fe2O3 loading was utilized to enhance the hydrophilicity of the membrane. The effects of mixed matrix membrane (MMM) and neat poly (vinylidene fluoride) (PVDF) membrane relating to their differences in the SEM images, water flux and oil rejection were studied. The presence of additive in the polymeric composition has helped to achieve 40% higher flux increment with an oil removal efficacy of ~97 %, as compared to the unmodified PVDF membrane. Penerbit UTM Press 2019 Article PeerReviewed application/pdf en http://eprints.utm.my/85041/1/WanNorharyatiWanSalleh2019_PVDFFe2O3mixedMatrixMembraneforOily.pdf Ismail, Nor Hafiza and Wan Salleh, Wan Norharyati and Rosman, Nurafiqah and Awang, Nor Asikin and Hasbullah, Hasrinah and Aziz, Farhana and Yusof, Norhaniza (2019) PVDF/Fe2O3 mixed matrix membrane for oily wastewater treatment. Malaysian Journal of Fundamental and Applied Sciences, 15 (5). pp. 703-707. ISSN 2289-5981 https://mjfas.utm.my/index.php/mjfas/article/download/1468/pdf
spellingShingle TP Chemical technology
Ismail, Nor Hafiza
Wan Salleh, Wan Norharyati
Rosman, Nurafiqah
Awang, Nor Asikin
Hasbullah, Hasrinah
Aziz, Farhana
Yusof, Norhaniza
PVDF/Fe2O3 mixed matrix membrane for oily wastewater treatment
title PVDF/Fe2O3 mixed matrix membrane for oily wastewater treatment
title_full PVDF/Fe2O3 mixed matrix membrane for oily wastewater treatment
title_fullStr PVDF/Fe2O3 mixed matrix membrane for oily wastewater treatment
title_full_unstemmed PVDF/Fe2O3 mixed matrix membrane for oily wastewater treatment
title_short PVDF/Fe2O3 mixed matrix membrane for oily wastewater treatment
title_sort pvdf fe2o3 mixed matrix membrane for oily wastewater treatment
topic TP Chemical technology
url http://eprints.utm.my/85041/1/WanNorharyatiWanSalleh2019_PVDFFe2O3mixedMatrixMembraneforOily.pdf
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