Extraction of reactive dye via synergistic aliquat 336/d2ehpa using emulsion liquid membrane system

Facilitated transport of Orange 3R was performed by means of emulsion liquid membrane (ELM) technique containing double extractants of Aliquat 336 and D2EHPA as extractant and synergist extractant, respectively. Cooking palm oil, sorbitan monooleate (Span 80), and sodium hydroxide were used as dilue...

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Main Authors: Sulaiman, R. N. R., Rahman, H. A., Othman, N., Rosly, M. B., Jusoh, N., Noah, N. F. M.
Format: Article
Published: Springer 2020
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author Sulaiman, R. N. R.
Rahman, H. A.
Othman, N.
Rosly, M. B.
Jusoh, N.
Noah, N. F. M.
author_facet Sulaiman, R. N. R.
Rahman, H. A.
Othman, N.
Rosly, M. B.
Jusoh, N.
Noah, N. F. M.
author_sort Sulaiman, R. N. R.
collection ePrints
description Facilitated transport of Orange 3R was performed by means of emulsion liquid membrane (ELM) technique containing double extractants of Aliquat 336 and D2EHPA as extractant and synergist extractant, respectively. Cooking palm oil, sorbitan monooleate (Span 80), and sodium hydroxide were used as diluent, surfactant and stripping agent, respectively. Several parameters influencing the extraction of Orange 3R via ELM, namely effect of extraction time, agitator speed, Span 80 concentration and treatment ratio, were experimentally investigated and optimized using response surface methodology (RSM). Results demonstrated that about 91% of Orange 3R was successfully extracted under optimum conditions of 12 minutes of extraction time, 413 rpm of agitator speed, 3.2% (w/v) of sorbitan monooleate, and 1:9.8 of treatment ratio. Additionally, the aforementioned optimum conditions were found to be more suitable to treat low concentration of Orange 3R (less than 100 ppm) from simulated textile wastewater. The findings reveal that reactive Orange 3R dye is able to be selectively extracted using double extractants via sustainable ELM process as well as providing high potential application in the dye removal from industrial textile wastewater.
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spelling utm.eprints-860842020-10-13T01:11:14Z http://eprints.utm.my/86084/ Extraction of reactive dye via synergistic aliquat 336/d2ehpa using emulsion liquid membrane system Sulaiman, R. N. R. Rahman, H. A. Othman, N. Rosly, M. B. Jusoh, N. Noah, N. F. M. TP Chemical technology Facilitated transport of Orange 3R was performed by means of emulsion liquid membrane (ELM) technique containing double extractants of Aliquat 336 and D2EHPA as extractant and synergist extractant, respectively. Cooking palm oil, sorbitan monooleate (Span 80), and sodium hydroxide were used as diluent, surfactant and stripping agent, respectively. Several parameters influencing the extraction of Orange 3R via ELM, namely effect of extraction time, agitator speed, Span 80 concentration and treatment ratio, were experimentally investigated and optimized using response surface methodology (RSM). Results demonstrated that about 91% of Orange 3R was successfully extracted under optimum conditions of 12 minutes of extraction time, 413 rpm of agitator speed, 3.2% (w/v) of sorbitan monooleate, and 1:9.8 of treatment ratio. Additionally, the aforementioned optimum conditions were found to be more suitable to treat low concentration of Orange 3R (less than 100 ppm) from simulated textile wastewater. The findings reveal that reactive Orange 3R dye is able to be selectively extracted using double extractants via sustainable ELM process as well as providing high potential application in the dye removal from industrial textile wastewater. Springer 2020-01 Article PeerReviewed Sulaiman, R. N. R. and Rahman, H. A. and Othman, N. and Rosly, M. B. and Jusoh, N. and Noah, N. F. M. (2020) Extraction of reactive dye via synergistic aliquat 336/d2ehpa using emulsion liquid membrane system. Korean Journal of Chemical Engineering, 37 (1). pp. 141-150. ISSN 0256-1115 https://dx.doi.org/10.1007/s11814-019-0418-4 DOI:10.1007/s11814-019-0418-4
spellingShingle TP Chemical technology
Sulaiman, R. N. R.
Rahman, H. A.
Othman, N.
Rosly, M. B.
Jusoh, N.
Noah, N. F. M.
Extraction of reactive dye via synergistic aliquat 336/d2ehpa using emulsion liquid membrane system
title Extraction of reactive dye via synergistic aliquat 336/d2ehpa using emulsion liquid membrane system
title_full Extraction of reactive dye via synergistic aliquat 336/d2ehpa using emulsion liquid membrane system
title_fullStr Extraction of reactive dye via synergistic aliquat 336/d2ehpa using emulsion liquid membrane system
title_full_unstemmed Extraction of reactive dye via synergistic aliquat 336/d2ehpa using emulsion liquid membrane system
title_short Extraction of reactive dye via synergistic aliquat 336/d2ehpa using emulsion liquid membrane system
title_sort extraction of reactive dye via synergistic aliquat 336 d2ehpa using emulsion liquid membrane system
topic TP Chemical technology
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