Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process

Polluted sterilization condensate discharged from palm oil mill may contain polyphenols that are rich in the antioxidant property. Emulsion liquid membrane (ELM) process is a promising method for polyphenol recovery due to its several attractive features such as high selectivity, simple operation, a...

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Main Authors: Jusoh, N., Rosly, M. B., Othman, N., Rahman, H. A., Noah, N. F. M., Sulaiman, R. N. R.
Format: Article
Published: Springer 2020
Subjects:
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author Jusoh, N.
Rosly, M. B.
Othman, N.
Rahman, H. A.
Noah, N. F. M.
Sulaiman, R. N. R.
author_facet Jusoh, N.
Rosly, M. B.
Othman, N.
Rahman, H. A.
Noah, N. F. M.
Sulaiman, R. N. R.
author_sort Jusoh, N.
collection ePrints
description Polluted sterilization condensate discharged from palm oil mill may contain polyphenols that are rich in the antioxidant property. Emulsion liquid membrane (ELM) process is a promising method for polyphenol recovery due to its several attractive features such as high selectivity, simple operation, and low energy consumption. In this study, the condensate was characterized to determine its total phenolic content (TPC), ionic elements, and pH. ELM formulation containing tributylphosphate (TBP) as a carrier, kerosene as a diluent, sorbitan monooleate (Span 80) as a surfactant, and sodium hydroxide (NaOH) as a stripping agent was developed. The results show that sterilization condensate contains 700–1500 mg GAE/L of TPC. During the ELM process, more than 91% of extraction with 83% recovery and 8.3 enrichment were achieved at the favorable condition of 0.1 M TBP, external phase pH 5, 1 M NaOH, 1:5 treat ratio, 5% v/v of octanol as a modifier, and 100 mg GAE/L external phase concentrations. Thus, ELM offers a potential alternative technology to extract and recover polyphenols from palm oil mill sterilization condensate while contributing to sustainable production.
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spelling utm.eprints-865412021-02-23T03:44:39Z http://eprints.utm.my/86541/ Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process Jusoh, N. Rosly, M. B. Othman, N. Rahman, H. A. Noah, N. F. M. Sulaiman, R. N. R. TP Chemical technology Polluted sterilization condensate discharged from palm oil mill may contain polyphenols that are rich in the antioxidant property. Emulsion liquid membrane (ELM) process is a promising method for polyphenol recovery due to its several attractive features such as high selectivity, simple operation, and low energy consumption. In this study, the condensate was characterized to determine its total phenolic content (TPC), ionic elements, and pH. ELM formulation containing tributylphosphate (TBP) as a carrier, kerosene as a diluent, sorbitan monooleate (Span 80) as a surfactant, and sodium hydroxide (NaOH) as a stripping agent was developed. The results show that sterilization condensate contains 700–1500 mg GAE/L of TPC. During the ELM process, more than 91% of extraction with 83% recovery and 8.3 enrichment were achieved at the favorable condition of 0.1 M TBP, external phase pH 5, 1 M NaOH, 1:5 treat ratio, 5% v/v of octanol as a modifier, and 100 mg GAE/L external phase concentrations. Thus, ELM offers a potential alternative technology to extract and recover polyphenols from palm oil mill sterilization condensate while contributing to sustainable production. Springer 2020-06 Article PeerReviewed Jusoh, N. and Rosly, M. B. and Othman, N. and Rahman, H. A. and Noah, N. F. M. and Sulaiman, R. N. R. (2020) Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process. Environmental Science and Pollution Research, 27 (18). pp. 23246-23257. ISSN 0944-1344 https://dx.doi.org/10.1007/s11356-020-07972-5 DOI: 10.1007/s11356-020-07972-5
spellingShingle TP Chemical technology
Jusoh, N.
Rosly, M. B.
Othman, N.
Rahman, H. A.
Noah, N. F. M.
Sulaiman, R. N. R.
Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process
title Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process
title_full Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process
title_fullStr Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process
title_full_unstemmed Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process
title_short Selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process
title_sort selective extraction and recovery of polyphenols from palm oil mill sterilization condensate using emulsion liquid membrane process
topic TP Chemical technology
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