Carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene
Carbon dioxide fixation technique was developed as an alternative dechlorination method of chlorobenzenes. Electrolysis of chlorobenzene was carried out in a one-compartment cell fitted with an aluminium anode and a platinum cathode. Electrolysis in N, N-dimethylformamide (DMF) solution containing 0...
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Published: |
Chengdu Institute of Organic Chemistry
2007
|
| Subjects: |
| _version_ | 1796854438515703808 |
|---|---|
| author | Abdul Jalil, Aishah M. A., Hartini S., Normala A. M., Norhuda M. H., N. Hanis H. M., Razif T., Sugeng |
| author_facet | Abdul Jalil, Aishah M. A., Hartini S., Normala A. M., Norhuda M. H., N. Hanis H. M., Razif T., Sugeng |
| author_sort | Abdul Jalil, Aishah |
| collection | ePrints |
| description | Carbon dioxide fixation technique was developed as an alternative dechlorination method of chlorobenzenes. Electrolysis of chlorobenzene was carried out in a one-compartment cell fitted with an aluminium anode and a platinum cathode. Electrolysis in N, N-dimethylformamide (DMF) solution containing 0.1 M of tetrapropylammonium bromide (TPAB) at 0 °C, 100 ml/min of CO2 flow rate and 120 mA/cm2 of current density was found to be the optimum conditions of this electrocarboxylation, which gave 72% yield of benzoic acid from chlorobenzene. These conditions were then applied to 1,2-dichlorobenzene and 1,3-dichlorobenzene in order to convert them to their corresponding benzoic acids. |
| first_indexed | 2024-03-05T18:14:05Z |
| format | Article |
| id | utm.eprints-8686 |
| institution | Universiti Teknologi Malaysia - ePrints |
| last_indexed | 2024-03-05T18:14:05Z |
| publishDate | 2007 |
| publisher | Chengdu Institute of Organic Chemistry |
| record_format | dspace |
| spelling | utm.eprints-86862011-11-08T05:20:53Z http://eprints.utm.my/8686/ Carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene Abdul Jalil, Aishah M. A., Hartini S., Normala A. M., Norhuda M. H., N. Hanis H. M., Razif T., Sugeng TP Chemical technology Carbon dioxide fixation technique was developed as an alternative dechlorination method of chlorobenzenes. Electrolysis of chlorobenzene was carried out in a one-compartment cell fitted with an aluminium anode and a platinum cathode. Electrolysis in N, N-dimethylformamide (DMF) solution containing 0.1 M of tetrapropylammonium bromide (TPAB) at 0 °C, 100 ml/min of CO2 flow rate and 120 mA/cm2 of current density was found to be the optimum conditions of this electrocarboxylation, which gave 72% yield of benzoic acid from chlorobenzene. These conditions were then applied to 1,2-dichlorobenzene and 1,3-dichlorobenzene in order to convert them to their corresponding benzoic acids. Chengdu Institute of Organic Chemistry 2007 Article PeerReviewed Abdul Jalil, Aishah and M. A., Hartini and S., Normala and A. M., Norhuda and M. H., N. Hanis and H. M., Razif and T., Sugeng (2007) Carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene. Journal of Natural Gas Chemistry, 16 (3). pp. 273-277. ISSN 1003-9953 http://dx.doi.org/10.1016/S1003-9953(07)60059-0 10.1016/S1003-9953(07)60059-0 |
| spellingShingle | TP Chemical technology Abdul Jalil, Aishah M. A., Hartini S., Normala A. M., Norhuda M. H., N. Hanis H. M., Razif T., Sugeng Carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene |
| title | Carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene |
| title_full | Carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene |
| title_fullStr | Carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene |
| title_full_unstemmed | Carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene |
| title_short | Carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene |
| title_sort | carbon dioxide fixation method for electrosynthesis of benzoic acid from chlorobenzene |
| topic | TP Chemical technology |
| work_keys_str_mv | AT abduljalilaishah carbondioxidefixationmethodforelectrosynthesisofbenzoicacidfromchlorobenzene AT mahartini carbondioxidefixationmethodforelectrosynthesisofbenzoicacidfromchlorobenzene AT snormala carbondioxidefixationmethodforelectrosynthesisofbenzoicacidfromchlorobenzene AT amnorhuda carbondioxidefixationmethodforelectrosynthesisofbenzoicacidfromchlorobenzene AT mhnhanis carbondioxidefixationmethodforelectrosynthesisofbenzoicacidfromchlorobenzene AT hmrazif carbondioxidefixationmethodforelectrosynthesisofbenzoicacidfromchlorobenzene AT tsugeng carbondioxidefixationmethodforelectrosynthesisofbenzoicacidfromchlorobenzene |