Enhancement of anti‐fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration

BACKGROUND: Treatment of paper mill effluent is crucial owing to its high organic constituents which necessitate the use of efficient membranes having greater anti-fouling ability. In this study, functionalized zeolite and activated carbon incorporated polyethersulfone (PES) membranes were developed...

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Main Authors: Saranya, Rameshkumar, Arthanareeswaran, Gangasalam, Ismail, Ahmad Fauzi
Format: Article
Published: John Wiley and Sons Inc. 2019
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author Saranya, Rameshkumar
Arthanareeswaran, Gangasalam
Ismail, Ahmad Fauzi
author_facet Saranya, Rameshkumar
Arthanareeswaran, Gangasalam
Ismail, Ahmad Fauzi
author_sort Saranya, Rameshkumar
collection ePrints
description BACKGROUND: Treatment of paper mill effluent is crucial owing to its high organic constituents which necessitate the use of efficient membranes having greater anti-fouling ability. In this study, functionalized zeolite and activated carbon incorporated polyethersulfone (PES) membranes were developed to maximize the fouling resistance and rejection efficiency thereby to achieve greater reduction levels of chemical oxygen demand (COD), biological oxygen demand (BOD) and total dissolved solids (TDS) in the effluent. RESULTS: The synthesized inorganic modifiers such as functionalized copper (Cu)-zeolite, iron (Fe)-zeolite and calcium alginate functionalized activated carbon were incorporated into PES in distinct wt% of 0.25, 0.5, 0.75 and 1. The high pure water flux of 38.9 L m−2 h−1 was observed with 0.25 wt% of Cu-zeolite when compared to 24.3 L m−2 h−1 of virgin PES. The addition of 0.5 wt% of functionalized activated carbon resulted in reduction levels of about 90.2%, 92% and 80% of COD, BOD and TDS respectively. CONCLUSIONS: Facile functionalization of zeolite and activated carbon using metal salts and calcium alginate was achieved. Functionalized Cu-zeolite imparted increased hydrophilicity, anti-fouling property and increased pore size compared to that of Fe-zeolite and functionalized activated carbon.
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spelling utm.eprints-874172020-11-08T04:04:55Z http://eprints.utm.my/87417/ Enhancement of anti‐fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration Saranya, Rameshkumar Arthanareeswaran, Gangasalam Ismail, Ahmad Fauzi TP Chemical technology BACKGROUND: Treatment of paper mill effluent is crucial owing to its high organic constituents which necessitate the use of efficient membranes having greater anti-fouling ability. In this study, functionalized zeolite and activated carbon incorporated polyethersulfone (PES) membranes were developed to maximize the fouling resistance and rejection efficiency thereby to achieve greater reduction levels of chemical oxygen demand (COD), biological oxygen demand (BOD) and total dissolved solids (TDS) in the effluent. RESULTS: The synthesized inorganic modifiers such as functionalized copper (Cu)-zeolite, iron (Fe)-zeolite and calcium alginate functionalized activated carbon were incorporated into PES in distinct wt% of 0.25, 0.5, 0.75 and 1. The high pure water flux of 38.9 L m−2 h−1 was observed with 0.25 wt% of Cu-zeolite when compared to 24.3 L m−2 h−1 of virgin PES. The addition of 0.5 wt% of functionalized activated carbon resulted in reduction levels of about 90.2%, 92% and 80% of COD, BOD and TDS respectively. CONCLUSIONS: Facile functionalization of zeolite and activated carbon using metal salts and calcium alginate was achieved. Functionalized Cu-zeolite imparted increased hydrophilicity, anti-fouling property and increased pore size compared to that of Fe-zeolite and functionalized activated carbon. John Wiley and Sons Inc. 2019 Article PeerReviewed Saranya, Rameshkumar and Arthanareeswaran, Gangasalam and Ismail, Ahmad Fauzi (2019) Enhancement of anti‐fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration. Journal of Chemical Technology and Biotechnology, 94 (9). pp. 2805-2815. ISSN 0268-2575 http://dx.doi.org/10.1002/jctb.6020
spellingShingle TP Chemical technology
Saranya, Rameshkumar
Arthanareeswaran, Gangasalam
Ismail, Ahmad Fauzi
Enhancement of anti‐fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration
title Enhancement of anti‐fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration
title_full Enhancement of anti‐fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration
title_fullStr Enhancement of anti‐fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration
title_full_unstemmed Enhancement of anti‐fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration
title_short Enhancement of anti‐fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration
title_sort enhancement of anti fouling properties during the treatment of paper mill effluent using functionalized zeolite and activated carbon nanomaterials based ultrafiltration
topic TP Chemical technology
work_keys_str_mv AT saranyarameshkumar enhancementofantifoulingpropertiesduringthetreatmentofpapermilleffluentusingfunctionalizedzeoliteandactivatedcarbonnanomaterialsbasedultrafiltration
AT arthanareeswarangangasalam enhancementofantifoulingpropertiesduringthetreatmentofpapermilleffluentusingfunctionalizedzeoliteandactivatedcarbonnanomaterialsbasedultrafiltration
AT ismailahmadfauzi enhancementofantifoulingpropertiesduringthetreatmentofpapermilleffluentusingfunctionalizedzeoliteandactivatedcarbonnanomaterialsbasedultrafiltration