A review of heterogeneous catalysts for syngas production via dry reforming

One of the significant approaches for syngas (hydrogen and carbon monoxide) production is through dry reforming process in which CO2 reacted with hydrocarbons such as methane. Current research focuses on new strategies for preparation of new hybrid catalyst with enhanced activity and highly resistan...

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Main Authors: A. Aziz, M. A., Setiabudi, H. D., Teh, L. P., Annuar, N. H. R., A. Jalil, A.
Format: Article
Published: Taiwan Institute of Chemical Engineers, Elsevier B.V. 2019
Subjects:
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author A. Aziz, M. A.
Setiabudi, H. D.
Teh, L. P.
Annuar, N. H. R.
A. Jalil, A.
author_facet A. Aziz, M. A.
Setiabudi, H. D.
Teh, L. P.
Annuar, N. H. R.
A. Jalil, A.
author_sort A. Aziz, M. A.
collection ePrints
description One of the significant approaches for syngas (hydrogen and carbon monoxide) production is through dry reforming process in which CO2 reacted with hydrocarbons such as methane. Current research focuses on new strategies for preparation of new hybrid catalyst with enhanced activity and highly resistant toward carbon deposition. Noble metal catalysts such as ruthenium has shown to be the most active and stable. However, these noble metals are not preferable for industrial scale considering of their high cost. On the other hand, non-noble metal catalysts such as nickel and cobalt are commonly studied because of their low cost as well as inherent availability. However, they suffer from severe deactivation mainly due to carbon deposition. The key factors to enhance the catalytic activity and suppress carbon deposition were depending on metal/active sites, type of support, metal-support interaction, promoter and preparation method. This review is an attempt to analyze the recent development of dry reforming of hydrocarbons over various heterogeneous catalytic systems. The present review also provides current understanding on the reaction mechanism as well as the future opportunities on dry reforming catalysts.
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spelling utm.eprints-879982020-12-14T22:58:24Z http://eprints.utm.my/87998/ A review of heterogeneous catalysts for syngas production via dry reforming A. Aziz, M. A. Setiabudi, H. D. Teh, L. P. Annuar, N. H. R. A. Jalil, A. TP Chemical technology One of the significant approaches for syngas (hydrogen and carbon monoxide) production is through dry reforming process in which CO2 reacted with hydrocarbons such as methane. Current research focuses on new strategies for preparation of new hybrid catalyst with enhanced activity and highly resistant toward carbon deposition. Noble metal catalysts such as ruthenium has shown to be the most active and stable. However, these noble metals are not preferable for industrial scale considering of their high cost. On the other hand, non-noble metal catalysts such as nickel and cobalt are commonly studied because of their low cost as well as inherent availability. However, they suffer from severe deactivation mainly due to carbon deposition. The key factors to enhance the catalytic activity and suppress carbon deposition were depending on metal/active sites, type of support, metal-support interaction, promoter and preparation method. This review is an attempt to analyze the recent development of dry reforming of hydrocarbons over various heterogeneous catalytic systems. The present review also provides current understanding on the reaction mechanism as well as the future opportunities on dry reforming catalysts. Taiwan Institute of Chemical Engineers, Elsevier B.V. 2019-08 Article PeerReviewed A. Aziz, M. A. and Setiabudi, H. D. and Teh, L. P. and Annuar, N. H. R. and A. Jalil, A. (2019) A review of heterogeneous catalysts for syngas production via dry reforming. Journal of the Taiwan Institute of Chemical Engineers, 101 . pp. 139-158. ISSN 1876-1070 http://dx.doi.org/10.1016/j.jtice.2019.04.047 DOI:10.1016/j.jtice.2019.04.047
spellingShingle TP Chemical technology
A. Aziz, M. A.
Setiabudi, H. D.
Teh, L. P.
Annuar, N. H. R.
A. Jalil, A.
A review of heterogeneous catalysts for syngas production via dry reforming
title A review of heterogeneous catalysts for syngas production via dry reforming
title_full A review of heterogeneous catalysts for syngas production via dry reforming
title_fullStr A review of heterogeneous catalysts for syngas production via dry reforming
title_full_unstemmed A review of heterogeneous catalysts for syngas production via dry reforming
title_short A review of heterogeneous catalysts for syngas production via dry reforming
title_sort review of heterogeneous catalysts for syngas production via dry reforming
topic TP Chemical technology
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