Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar

The present study evaluates the effect of sodium hydroxide concentrations on strength, bond properties, reaction products and the microstructures of binary blended alkali-activated volcanic natural pozzolan and limestone powder (AANL) mortar. Six AANL mortar were prepared with alkaline activators of...

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Main Authors: Adewumi, Adeshina Adewale, Mohd. Ariffin, Mohd. Azreen, Yusuf, Moruf Olalekan, Maslehuddin, Mohammed, Mohammad Ismail, Mohammad Ismail
Format: Article
Published: Elsevier Ltd 2021
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author Adewumi, Adeshina Adewale
Mohd. Ariffin, Mohd. Azreen
Yusuf, Moruf Olalekan
Maslehuddin, Mohammed
Mohammad Ismail, Mohammad Ismail
author_facet Adewumi, Adeshina Adewale
Mohd. Ariffin, Mohd. Azreen
Yusuf, Moruf Olalekan
Maslehuddin, Mohammed
Mohammad Ismail, Mohammad Ismail
author_sort Adewumi, Adeshina Adewale
collection ePrints
description The present study evaluates the effect of sodium hydroxide concentrations on strength, bond properties, reaction products and the microstructures of binary blended alkali-activated volcanic natural pozzolan and limestone powder (AANL) mortar. Six AANL mortar were prepared with alkaline activators of 4–14 M NaOH(aq) and Na2SiO3(aq) such that the activators ratio was 1:1. Curing was done at 75 °C for 24 h duration. The maximum 90-day compressive strength of 31.3 MPa was achieved with 10 M NaOH(aq) while 76% of the strength could be achieved within three days when 10 M NaOH was used. The 28-day tensile strength of 2.32 MPa was achieved with 14 M NaOH(aq). XRD characterizations revealed that activation with a strong concentration of sodium hydroxide (10 M NaOH(aq)) led to the formation of anorthite (CaAl2Si2O8) and gehlenite (Ca0.Al2O3SiO2). SEM + EDX indicated that strong alkali (10 M NaOH) enhanced microstructural density compared to that of mild alkali (4 M NaOH(aq)).
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spelling utm.eprints-902412021-03-31T06:22:54Z http://eprints.utm.my/90241/ Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar Adewumi, Adeshina Adewale Mohd. Ariffin, Mohd. Azreen Yusuf, Moruf Olalekan Maslehuddin, Mohammed Mohammad Ismail, Mohammad Ismail TA Engineering (General). Civil engineering (General) The present study evaluates the effect of sodium hydroxide concentrations on strength, bond properties, reaction products and the microstructures of binary blended alkali-activated volcanic natural pozzolan and limestone powder (AANL) mortar. Six AANL mortar were prepared with alkaline activators of 4–14 M NaOH(aq) and Na2SiO3(aq) such that the activators ratio was 1:1. Curing was done at 75 °C for 24 h duration. The maximum 90-day compressive strength of 31.3 MPa was achieved with 10 M NaOH(aq) while 76% of the strength could be achieved within three days when 10 M NaOH was used. The 28-day tensile strength of 2.32 MPa was achieved with 14 M NaOH(aq). XRD characterizations revealed that activation with a strong concentration of sodium hydroxide (10 M NaOH(aq)) led to the formation of anorthite (CaAl2Si2O8) and gehlenite (Ca0.Al2O3SiO2). SEM + EDX indicated that strong alkali (10 M NaOH) enhanced microstructural density compared to that of mild alkali (4 M NaOH(aq)). Elsevier Ltd 2021-02 Article PeerReviewed Adewumi, Adeshina Adewale and Mohd. Ariffin, Mohd. Azreen and Yusuf, Moruf Olalekan and Maslehuddin, Mohammed and Mohammad Ismail, Mohammad Ismail (2021) Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar. Construction and Building Materials, 271 . p. 121530. ISSN 0950-0618 http://dx.doi.org/10.1016/j.conbuildmat.2020.121530
spellingShingle TA Engineering (General). Civil engineering (General)
Adewumi, Adeshina Adewale
Mohd. Ariffin, Mohd. Azreen
Yusuf, Moruf Olalekan
Maslehuddin, Mohammed
Mohammad Ismail, Mohammad Ismail
Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar
title Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar
title_full Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar
title_fullStr Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar
title_full_unstemmed Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar
title_short Effect of sodium hydroxide concentration on strength and microstructure of alkali-activated natural pozzolan and limestone powder mortar
title_sort effect of sodium hydroxide concentration on strength and microstructure of alkali activated natural pozzolan and limestone powder mortar
topic TA Engineering (General). Civil engineering (General)
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