Adsorption study of Rhodamine B and methylene blue dyes with ZSM-5 directly synthesized from Bangka kaolin without organic template

Rhodamine B (RB) and Methylene Blue (MB) dyes adsorption using adsorbent ZSM-5 synthesized from Bangka kaolin were investigated in this study. The effects of the initial concentration, contact time, and temperature on the adsorption process were also analyzed. The effect of the initial concentration...

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Main Authors: Ani Iryani, Ani Iryani, Nur, Hadi, Santoso, Mardi, Hartanto, Djoko
Format: Article
Language:English
Published: Gadjah Mada University 2020
Subjects:
Online Access:http://eprints.utm.my/90858/1/HadiNur2020_AdsorptionStudyofRhodamineBandMethylene.pdf
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author Ani Iryani, Ani Iryani
Nur, Hadi
Santoso, Mardi
Hartanto, Djoko
author_facet Ani Iryani, Ani Iryani
Nur, Hadi
Santoso, Mardi
Hartanto, Djoko
author_sort Ani Iryani, Ani Iryani
collection ePrints
description Rhodamine B (RB) and Methylene Blue (MB) dyes adsorption using adsorbent ZSM-5 synthesized from Bangka kaolin were investigated in this study. The effects of the initial concentration, contact time, and temperature on the adsorption process were also analyzed. The effect of the initial concentration and contact time played an important role in the adsorption process; however, the effect differs significantly in both dyes. The temperature plays little role in the dye adsorption process. The results showed that the adsorption process occurred in ZSM-5 adhere to Langmuir isothermal adsorption model showing that the adsorption process occurred to be monolayer. Based on the kinetics studies, the pseudo-first-order kinetic model represents the adsorption kinetics that occurs for both dyes onto the synthesized ZSM-5. Thermodynamic parameters namely Gibbs free energy (ΔG°), standard entropy changes (ΔS°) and standard enthalpy (ΔH°) reveal that the adsorption process onto ZSM-5 for both dyes was spontaneous and exothermic.
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spelling utm.eprints-908582021-05-31T13:22:06Z http://eprints.utm.my/90858/ Adsorption study of Rhodamine B and methylene blue dyes with ZSM-5 directly synthesized from Bangka kaolin without organic template Ani Iryani, Ani Iryani Nur, Hadi Santoso, Mardi Hartanto, Djoko QD Chemistry Rhodamine B (RB) and Methylene Blue (MB) dyes adsorption using adsorbent ZSM-5 synthesized from Bangka kaolin were investigated in this study. The effects of the initial concentration, contact time, and temperature on the adsorption process were also analyzed. The effect of the initial concentration and contact time played an important role in the adsorption process; however, the effect differs significantly in both dyes. The temperature plays little role in the dye adsorption process. The results showed that the adsorption process occurred in ZSM-5 adhere to Langmuir isothermal adsorption model showing that the adsorption process occurred to be monolayer. Based on the kinetics studies, the pseudo-first-order kinetic model represents the adsorption kinetics that occurs for both dyes onto the synthesized ZSM-5. Thermodynamic parameters namely Gibbs free energy (ΔG°), standard entropy changes (ΔS°) and standard enthalpy (ΔH°) reveal that the adsorption process onto ZSM-5 for both dyes was spontaneous and exothermic. Gadjah Mada University 2020 Article PeerReviewed application/pdf en http://eprints.utm.my/90858/1/HadiNur2020_AdsorptionStudyofRhodamineBandMethylene.pdf Ani Iryani, Ani Iryani and Nur, Hadi and Santoso, Mardi and Hartanto, Djoko (2020) Adsorption study of Rhodamine B and methylene blue dyes with ZSM-5 directly synthesized from Bangka kaolin without organic template. Indonesian Journal of Chemistry, 20 (1). pp. 130-140. ISSN 1411-9420 http://dx.doi.org/10.22146/ijc.41369
spellingShingle QD Chemistry
Ani Iryani, Ani Iryani
Nur, Hadi
Santoso, Mardi
Hartanto, Djoko
Adsorption study of Rhodamine B and methylene blue dyes with ZSM-5 directly synthesized from Bangka kaolin without organic template
title Adsorption study of Rhodamine B and methylene blue dyes with ZSM-5 directly synthesized from Bangka kaolin without organic template
title_full Adsorption study of Rhodamine B and methylene blue dyes with ZSM-5 directly synthesized from Bangka kaolin without organic template
title_fullStr Adsorption study of Rhodamine B and methylene blue dyes with ZSM-5 directly synthesized from Bangka kaolin without organic template
title_full_unstemmed Adsorption study of Rhodamine B and methylene blue dyes with ZSM-5 directly synthesized from Bangka kaolin without organic template
title_short Adsorption study of Rhodamine B and methylene blue dyes with ZSM-5 directly synthesized from Bangka kaolin without organic template
title_sort adsorption study of rhodamine b and methylene blue dyes with zsm 5 directly synthesized from bangka kaolin without organic template
topic QD Chemistry
url http://eprints.utm.my/90858/1/HadiNur2020_AdsorptionStudyofRhodamineBandMethylene.pdf
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