Fabrication of nanocomposites mediated from aluminium nanoparticles/Moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution

The removal of nitrate and phosphate in polluted water is a challenging environmental problem. This study was designed to use a different light spectrum to enhance carbon-based metal nanocomposites adsorbent for the augmented removal of nitrate and phosphate from aqueous solution. Synthesis of alumi...

Full description

Bibliographic Details
Main Authors: Velu, Manikandan, Balasubramanian, Balamuralikrishnan, Velmurugan, Palanivel, Kamyab, Hesam, Ravi, Arumugam Veera, Chelliapan, Shreeshivadasan, Lee, Chew Tin, Palaniyappan, Jayanthi
Format: Article
Published: Elsevier Ltd 2021
Subjects:
_version_ 1796865155650289664
author Velu, Manikandan
Balasubramanian, Balamuralikrishnan
Velmurugan, Palanivel
Kamyab, Hesam
Ravi, Arumugam Veera
Chelliapan, Shreeshivadasan
Lee, Chew Tin
Palaniyappan, Jayanthi
author_facet Velu, Manikandan
Balasubramanian, Balamuralikrishnan
Velmurugan, Palanivel
Kamyab, Hesam
Ravi, Arumugam Veera
Chelliapan, Shreeshivadasan
Lee, Chew Tin
Palaniyappan, Jayanthi
author_sort Velu, Manikandan
collection ePrints
description The removal of nitrate and phosphate in polluted water is a challenging environmental problem. This study was designed to use a different light spectrum to enhance carbon-based metal nanocomposites adsorbent for the augmented removal of nitrate and phosphate from aqueous solution. Synthesis of aluminium oxide nanoparticle (Al2O3NPs)/Moringa oleifera gum activated carbon (MOGAC) based nanocomposites was conducted using sol-gel method. Incidentally, prepared nanocomposite was subject to evaluate the photocatalytic removal of nitrate and phosphate under different LED light irradiations. The microscopic image of MOGAC showed the pores on its surface, which resembles a honeycomb-like structure. The bandgap energy values of the Al2O3 and Al2O3/MOGAC were 3.16 and 3.22 eV, which corresponded to the reflectance edge of 420 nm. The surface area of Al2O3/MOGAC nanocomposites resolute was recorded as 176.92 m2/g−1. Photocatalytic activity against nitrate and phosphate was carried out by the synthesized nanocomposites under the different LED light spectrum. The red LED light spectrum and 10 mg/L of nanocomposite removed nitrate and phosphate ions up to 94% and 95% after 105 min and 75 min of irradiation, respectively. Overall, the Al2O3/MOGAC nanocomposites maintained good stability after four cycles of nitrate and phosphate reduction.
first_indexed 2024-03-05T20:52:39Z
format Article
id utm.eprints-91073
institution Universiti Teknologi Malaysia - ePrints
last_indexed 2024-03-05T20:52:39Z
publishDate 2021
publisher Elsevier Ltd
record_format dspace
spelling utm.eprints-910732021-05-31T13:51:21Z http://eprints.utm.my/91073/ Fabrication of nanocomposites mediated from aluminium nanoparticles/Moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution Velu, Manikandan Balasubramanian, Balamuralikrishnan Velmurugan, Palanivel Kamyab, Hesam Ravi, Arumugam Veera Chelliapan, Shreeshivadasan Lee, Chew Tin Palaniyappan, Jayanthi T Technology (General) The removal of nitrate and phosphate in polluted water is a challenging environmental problem. This study was designed to use a different light spectrum to enhance carbon-based metal nanocomposites adsorbent for the augmented removal of nitrate and phosphate from aqueous solution. Synthesis of aluminium oxide nanoparticle (Al2O3NPs)/Moringa oleifera gum activated carbon (MOGAC) based nanocomposites was conducted using sol-gel method. Incidentally, prepared nanocomposite was subject to evaluate the photocatalytic removal of nitrate and phosphate under different LED light irradiations. The microscopic image of MOGAC showed the pores on its surface, which resembles a honeycomb-like structure. The bandgap energy values of the Al2O3 and Al2O3/MOGAC were 3.16 and 3.22 eV, which corresponded to the reflectance edge of 420 nm. The surface area of Al2O3/MOGAC nanocomposites resolute was recorded as 176.92 m2/g−1. Photocatalytic activity against nitrate and phosphate was carried out by the synthesized nanocomposites under the different LED light spectrum. The red LED light spectrum and 10 mg/L of nanocomposite removed nitrate and phosphate ions up to 94% and 95% after 105 min and 75 min of irradiation, respectively. Overall, the Al2O3/MOGAC nanocomposites maintained good stability after four cycles of nitrate and phosphate reduction. Elsevier Ltd 2021-01 Article PeerReviewed Velu, Manikandan and Balasubramanian, Balamuralikrishnan and Velmurugan, Palanivel and Kamyab, Hesam and Ravi, Arumugam Veera and Chelliapan, Shreeshivadasan and Lee, Chew Tin and Palaniyappan, Jayanthi (2021) Fabrication of nanocomposites mediated from aluminium nanoparticles/Moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution. Journal of Cleaner Production, 281 . p. 124553. ISSN 09596526 http://dx.doi.org/10.1016/j.jclepro.2020.124553
spellingShingle T Technology (General)
Velu, Manikandan
Balasubramanian, Balamuralikrishnan
Velmurugan, Palanivel
Kamyab, Hesam
Ravi, Arumugam Veera
Chelliapan, Shreeshivadasan
Lee, Chew Tin
Palaniyappan, Jayanthi
Fabrication of nanocomposites mediated from aluminium nanoparticles/Moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution
title Fabrication of nanocomposites mediated from aluminium nanoparticles/Moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution
title_full Fabrication of nanocomposites mediated from aluminium nanoparticles/Moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution
title_fullStr Fabrication of nanocomposites mediated from aluminium nanoparticles/Moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution
title_full_unstemmed Fabrication of nanocomposites mediated from aluminium nanoparticles/Moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution
title_short Fabrication of nanocomposites mediated from aluminium nanoparticles/Moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution
title_sort fabrication of nanocomposites mediated from aluminium nanoparticles moringa oleifera gum activated carbon for effective photocatalytic removal of nitrate and phosphate in aqueous solution
topic T Technology (General)
work_keys_str_mv AT velumanikandan fabricationofnanocompositesmediatedfromaluminiumnanoparticlesmoringaoleiferagumactivatedcarbonforeffectivephotocatalyticremovalofnitrateandphosphateinaqueoussolution
AT balasubramanianbalamuralikrishnan fabricationofnanocompositesmediatedfromaluminiumnanoparticlesmoringaoleiferagumactivatedcarbonforeffectivephotocatalyticremovalofnitrateandphosphateinaqueoussolution
AT velmuruganpalanivel fabricationofnanocompositesmediatedfromaluminiumnanoparticlesmoringaoleiferagumactivatedcarbonforeffectivephotocatalyticremovalofnitrateandphosphateinaqueoussolution
AT kamyabhesam fabricationofnanocompositesmediatedfromaluminiumnanoparticlesmoringaoleiferagumactivatedcarbonforeffectivephotocatalyticremovalofnitrateandphosphateinaqueoussolution
AT raviarumugamveera fabricationofnanocompositesmediatedfromaluminiumnanoparticlesmoringaoleiferagumactivatedcarbonforeffectivephotocatalyticremovalofnitrateandphosphateinaqueoussolution
AT chelliapanshreeshivadasan fabricationofnanocompositesmediatedfromaluminiumnanoparticlesmoringaoleiferagumactivatedcarbonforeffectivephotocatalyticremovalofnitrateandphosphateinaqueoussolution
AT leechewtin fabricationofnanocompositesmediatedfromaluminiumnanoparticlesmoringaoleiferagumactivatedcarbonforeffectivephotocatalyticremovalofnitrateandphosphateinaqueoussolution
AT palaniyappanjayanthi fabricationofnanocompositesmediatedfromaluminiumnanoparticlesmoringaoleiferagumactivatedcarbonforeffectivephotocatalyticremovalofnitrateandphosphateinaqueoussolution