The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes
Free standing solid polymer electrolyte films based on poly (methyl methacrylate) PMMA and Poly (vinyl chloride), PVC can be obtained when blend with 10% and 50% of 50% epoxidised natural rubber, ENR 50 respectively. This work conducted impedance spectroscopy studies on PVC / ENR 50 and PMMA / ENR 5...
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| Format: | Article |
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Scitec Publications Ltd.
2006
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| _version_ | 1796854496918241280 |
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| author | Aziz, M. Latif, F. Chew, C. L. Katun, N. |
| author_facet | Aziz, M. Latif, F. Chew, C. L. Katun, N. |
| author_sort | Aziz, M. |
| collection | ePrints |
| description | Free standing solid polymer electrolyte films based on poly (methyl methacrylate) PMMA and Poly (vinyl chloride), PVC can be obtained when blend with 10% and 50% of 50% epoxidised natural rubber, ENR 50 respectively. This work conducted impedance spectroscopy studies on PVC / ENR 50 and PMMA / ENR 50 based electrolyte systems when doped with lithium triflate, LiCF 3SO3 salt. PVC / ENR 50 / LiCF3SO3 exhibited higher bulk resistance, Rb and lower conductivity values than PMMA / ENR 50 based electrolytes. The highest conductivity achieved for PMMA / ENR 50 blend is 5.09 × 10-5 S/cm and 3.64 × 10-8 S/cm for PVC / ENR 50 blend when doped with 60% of LiCF3SO3 salt. The plots of logarithm of ionic conductivity against the reciprocal of absolute temperature revealed that the ionic conduction in PVC / ENR 50 / LiCF3SO3 electrolyte follows the WLF theory and PMMA / ENR 50 / LiCF3SO3 electrolyte obeyed the Arrhenius behavior. |
| first_indexed | 2024-03-05T18:14:57Z |
| format | Article |
| id | utm.eprints-9165 |
| institution | Universiti Teknologi Malaysia - ePrints |
| last_indexed | 2024-03-05T18:14:57Z |
| publishDate | 2006 |
| publisher | Scitec Publications Ltd. |
| record_format | dspace |
| spelling | utm.eprints-91652018-03-07T21:10:47Z http://eprints.utm.my/9165/ The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes Aziz, M. Latif, F. Chew, C. L. Katun, N. Q Science (General) Free standing solid polymer electrolyte films based on poly (methyl methacrylate) PMMA and Poly (vinyl chloride), PVC can be obtained when blend with 10% and 50% of 50% epoxidised natural rubber, ENR 50 respectively. This work conducted impedance spectroscopy studies on PVC / ENR 50 and PMMA / ENR 50 based electrolyte systems when doped with lithium triflate, LiCF 3SO3 salt. PVC / ENR 50 / LiCF3SO3 exhibited higher bulk resistance, Rb and lower conductivity values than PMMA / ENR 50 based electrolytes. The highest conductivity achieved for PMMA / ENR 50 blend is 5.09 × 10-5 S/cm and 3.64 × 10-8 S/cm for PVC / ENR 50 blend when doped with 60% of LiCF3SO3 salt. The plots of logarithm of ionic conductivity against the reciprocal of absolute temperature revealed that the ionic conduction in PVC / ENR 50 / LiCF3SO3 electrolyte follows the WLF theory and PMMA / ENR 50 / LiCF3SO3 electrolyte obeyed the Arrhenius behavior. Scitec Publications Ltd. 2006 Article PeerReviewed Aziz, M. and Latif, F. and Chew, C. L. and Katun, N. (2006) The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes. Diffusion and Defect Data Pt.B: Solid State Phenomena, 111 . pp. 67-70. ISSN 1012-0394 http://dx.doi.org/10.4028/3-908451-18-3.67 10.4028/3-908451-18-3.67 |
| spellingShingle | Q Science (General) Aziz, M. Latif, F. Chew, C. L. Katun, N. The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes |
| title | The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes |
| title_full | The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes |
| title_fullStr | The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes |
| title_full_unstemmed | The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes |
| title_short | The impedance spectroscopy studies of PVC / ENR 50 / LiCF 3so3 and PMMA / ENR 50 / LiCF3so3 electrolytes |
| title_sort | impedance spectroscopy studies of pvc enr 50 licf 3so3 and pmma enr 50 licf3so3 electrolytes |
| topic | Q Science (General) |
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