Dry reforming of methane to hydrogen-rich syngas over robust fibrous KCC-1 stabilized nickel catalyst with high activity and coke resistance
A remarkably stable and active nickel (Ni) catalyst, supported on fibrous KCC-1 silica particles, was prepared by in situ one-pot hydrothermal method to produce a hydrogen-rich syngas. The catalysts’ properties were characterized by BET, XRD, FESEM-mapping, FTIR-pyrrole, FTIR-KBr, and XPS, while cok...
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| Format: | Article |
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Elsevier
2020
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| _version_ | 1796865635559407616 |
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| author | Abdulrasheed, A. A. Jalil, A. A. Hamid, M. Y. S. Siang, T. J. Fatah, N. A. A. Izan, S. M. Hassan, N. S. |
| author_facet | Abdulrasheed, A. A. Jalil, A. A. Hamid, M. Y. S. Siang, T. J. Fatah, N. A. A. Izan, S. M. Hassan, N. S. |
| author_sort | Abdulrasheed, A. A. |
| collection | ePrints |
| description | A remarkably stable and active nickel (Ni) catalyst, supported on fibrous KCC-1 silica particles, was prepared by in situ one-pot hydrothermal method to produce a hydrogen-rich syngas. The catalysts’ properties were characterized by BET, XRD, FESEM-mapping, FTIR-pyrrole, FTIR-KBr, and XPS, while coke deposition was evaluated using Raman spectra, TEM and TGA/DTA. The high dispersion of Ni crystallites, enhanced basicity, strong Ni-KCC-1 interaction, and encapsulation of Ni particles contributed to the enhanced catalyst stability and activity. The one-pot catalyst produced high CH4 and CO2 conversions at 92% and 88% respectively, with high H2/CO ratio, and an extended stability over 72 h at 750 °C. There was limited coke deposition, predominantly of the amorphous type, owing to its synthesis method and support morphology. |
| first_indexed | 2024-03-05T21:00:00Z |
| format | Article |
| id | utm.eprints-93508 |
| institution | Universiti Teknologi Malaysia - ePrints |
| last_indexed | 2024-03-05T21:00:00Z |
| publishDate | 2020 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | utm.eprints-935082021-11-30T08:28:59Z http://eprints.utm.my/93508/ Dry reforming of methane to hydrogen-rich syngas over robust fibrous KCC-1 stabilized nickel catalyst with high activity and coke resistance Abdulrasheed, A. A. Jalil, A. A. Hamid, M. Y. S. Siang, T. J. Fatah, N. A. A. Izan, S. M. Hassan, N. S. TP Chemical technology A remarkably stable and active nickel (Ni) catalyst, supported on fibrous KCC-1 silica particles, was prepared by in situ one-pot hydrothermal method to produce a hydrogen-rich syngas. The catalysts’ properties were characterized by BET, XRD, FESEM-mapping, FTIR-pyrrole, FTIR-KBr, and XPS, while coke deposition was evaluated using Raman spectra, TEM and TGA/DTA. The high dispersion of Ni crystallites, enhanced basicity, strong Ni-KCC-1 interaction, and encapsulation of Ni particles contributed to the enhanced catalyst stability and activity. The one-pot catalyst produced high CH4 and CO2 conversions at 92% and 88% respectively, with high H2/CO ratio, and an extended stability over 72 h at 750 °C. There was limited coke deposition, predominantly of the amorphous type, owing to its synthesis method and support morphology. Elsevier 2020 Article PeerReviewed Abdulrasheed, A. A. and Jalil, A. A. and Hamid, M. Y. S. and Siang, T. J. and Fatah, N. A. A. and Izan, S. M. and Hassan, N. S. (2020) Dry reforming of methane to hydrogen-rich syngas over robust fibrous KCC-1 stabilized nickel catalyst with high activity and coke resistance. International Journal of Hydrogen Energy, 45 (36). pp. 18549-18561. ISSN 0360-3199 http://dx.doi.org/10.1016/j.ijhydene.2019.04.126 |
| spellingShingle | TP Chemical technology Abdulrasheed, A. A. Jalil, A. A. Hamid, M. Y. S. Siang, T. J. Fatah, N. A. A. Izan, S. M. Hassan, N. S. Dry reforming of methane to hydrogen-rich syngas over robust fibrous KCC-1 stabilized nickel catalyst with high activity and coke resistance |
| title | Dry reforming of methane to hydrogen-rich syngas over robust fibrous KCC-1 stabilized nickel catalyst with high activity and coke resistance |
| title_full | Dry reforming of methane to hydrogen-rich syngas over robust fibrous KCC-1 stabilized nickel catalyst with high activity and coke resistance |
| title_fullStr | Dry reforming of methane to hydrogen-rich syngas over robust fibrous KCC-1 stabilized nickel catalyst with high activity and coke resistance |
| title_full_unstemmed | Dry reforming of methane to hydrogen-rich syngas over robust fibrous KCC-1 stabilized nickel catalyst with high activity and coke resistance |
| title_short | Dry reforming of methane to hydrogen-rich syngas over robust fibrous KCC-1 stabilized nickel catalyst with high activity and coke resistance |
| title_sort | dry reforming of methane to hydrogen rich syngas over robust fibrous kcc 1 stabilized nickel catalyst with high activity and coke resistance |
| topic | TP Chemical technology |
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