The study and comparison of power-dependent nonlinear optical behaviours of α-mangostin with Sheik-Bahae formalism and thermal lens model using Z-Scan technique

The pericarp of Garcinia mangostana (mangosteen) contains a -mangostin (a -MG), which is an essential compound derived from the family of xanthone. This study aimed to determine the nonlinear optical response of the extracted a -MG using Z-scan technique (532 nm, 0.5–1.0 W). A series of characterisa...

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Main Authors: Rosli, M. I., Basar, N., Mohd. Rozi, N., Krishnan, G., Harun, S. W., Sazali, E. S., Aziz, M. S.
Format: Article
Published: Elsevier B.V. 2021
Subjects:
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author Rosli, M. I.
Basar, N.
Mohd. Rozi, N.
Krishnan, G.
Harun, S. W.
Sazali, E. S.
Aziz, M. S.
author_facet Rosli, M. I.
Basar, N.
Mohd. Rozi, N.
Krishnan, G.
Harun, S. W.
Sazali, E. S.
Aziz, M. S.
author_sort Rosli, M. I.
collection ePrints
description The pericarp of Garcinia mangostana (mangosteen) contains a -mangostin (a -MG), which is an essential compound derived from the family of xanthone. This study aimed to determine the nonlinear optical response of the extracted a -MG using Z-scan technique (532 nm, 0.5–1.0 W). A series of characterisations were also done by using 1H & 13C nuclear magnetic resonance (NMR), electron impact mass spectrometry (EIMS), ultraviolet-visible (UV–vis) and Fourier transform infrared (FTIR) to validate the identity of the extracted a -MG. The results showed that only nonlinear refraction (NLR) was successfully captured and measured by the closed-aperture signal. The localized absorption across the media enabled the a -MG to exhibit a self-defocusing effect. The recorded values of the nonlinear refractive index, which were denoted as n2, were then compared with two different theoretical fitting curves, which were Sheikh-Bahae Formalism (SBF) and Thermal Lens Model (TLM). The values of n2 obtained were in the order of 10-9 and 10-10 for SBF and TLM, respectively. The NLO characteristics of the a -MG were observed at the excitation wavelength of 532 nm.
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spelling utm.eprints-953352022-04-29T22:26:35Z http://eprints.utm.my/95335/ The study and comparison of power-dependent nonlinear optical behaviours of α-mangostin with Sheik-Bahae formalism and thermal lens model using Z-Scan technique Rosli, M. I. Basar, N. Mohd. Rozi, N. Krishnan, G. Harun, S. W. Sazali, E. S. Aziz, M. S. QC Physics The pericarp of Garcinia mangostana (mangosteen) contains a -mangostin (a -MG), which is an essential compound derived from the family of xanthone. This study aimed to determine the nonlinear optical response of the extracted a -MG using Z-scan technique (532 nm, 0.5–1.0 W). A series of characterisations were also done by using 1H & 13C nuclear magnetic resonance (NMR), electron impact mass spectrometry (EIMS), ultraviolet-visible (UV–vis) and Fourier transform infrared (FTIR) to validate the identity of the extracted a -MG. The results showed that only nonlinear refraction (NLR) was successfully captured and measured by the closed-aperture signal. The localized absorption across the media enabled the a -MG to exhibit a self-defocusing effect. The recorded values of the nonlinear refractive index, which were denoted as n2, were then compared with two different theoretical fitting curves, which were Sheikh-Bahae Formalism (SBF) and Thermal Lens Model (TLM). The values of n2 obtained were in the order of 10-9 and 10-10 for SBF and TLM, respectively. The NLO characteristics of the a -MG were observed at the excitation wavelength of 532 nm. Elsevier B.V. 2021 Article PeerReviewed Rosli, M. I. and Basar, N. and Mohd. Rozi, N. and Krishnan, G. and Harun, S. W. and Sazali, E. S. and Aziz, M. S. (2021) The study and comparison of power-dependent nonlinear optical behaviours of α-mangostin with Sheik-Bahae formalism and thermal lens model using Z-Scan technique. Journal of Photochemistry and Photobiology A: Chemistry, 407 . p. 113034. ISSN 1010-6030 http://dx.doi.org/10.1016/j.jphotochem.2020.113034
spellingShingle QC Physics
Rosli, M. I.
Basar, N.
Mohd. Rozi, N.
Krishnan, G.
Harun, S. W.
Sazali, E. S.
Aziz, M. S.
The study and comparison of power-dependent nonlinear optical behaviours of α-mangostin with Sheik-Bahae formalism and thermal lens model using Z-Scan technique
title The study and comparison of power-dependent nonlinear optical behaviours of α-mangostin with Sheik-Bahae formalism and thermal lens model using Z-Scan technique
title_full The study and comparison of power-dependent nonlinear optical behaviours of α-mangostin with Sheik-Bahae formalism and thermal lens model using Z-Scan technique
title_fullStr The study and comparison of power-dependent nonlinear optical behaviours of α-mangostin with Sheik-Bahae formalism and thermal lens model using Z-Scan technique
title_full_unstemmed The study and comparison of power-dependent nonlinear optical behaviours of α-mangostin with Sheik-Bahae formalism and thermal lens model using Z-Scan technique
title_short The study and comparison of power-dependent nonlinear optical behaviours of α-mangostin with Sheik-Bahae formalism and thermal lens model using Z-Scan technique
title_sort study and comparison of power dependent nonlinear optical behaviours of α mangostin with sheik bahae formalism and thermal lens model using z scan technique
topic QC Physics
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