Flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite/chitin hybrid nanomaterial

The substrate of RO thin film composite membranes offers support for rejection layer formation. It remarkably affects the physicochemical and structural properties of the developed rejection layer. This denotes the relevance of substrates modification in realizing optimized substrate structure in te...

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Main Authors: Mamah, Stanley Chinedu, Goh, Pei Sean, Ismail, Ahmad Fauzi, Suzaimi, Nur Diyana, Ahmad, Nor Akalili, Lee, Wei Jie
Format: Article
Published: Elsevier Ltd 2021
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author Mamah, Stanley Chinedu
Goh, Pei Sean
Ismail, Ahmad Fauzi
Suzaimi, Nur Diyana
Ahmad, Nor Akalili
Lee, Wei Jie
author_facet Mamah, Stanley Chinedu
Goh, Pei Sean
Ismail, Ahmad Fauzi
Suzaimi, Nur Diyana
Ahmad, Nor Akalili
Lee, Wei Jie
author_sort Mamah, Stanley Chinedu
collection ePrints
description The substrate of RO thin film composite membranes offers support for rejection layer formation. It remarkably affects the physicochemical and structural properties of the developed rejection layer. This denotes the relevance of substrates modification in realizing optimized substrate structure in terms of porosity, thickness and tortuosity with the goal of obtaining highly selective and enhanced hydrophilic membrane. Polyamide thin film nanocomposite (TFN) membranes with its polysulfone (PSF) substrate embedded with palygorskite-chitin (PAL-CH) hybrid nanomaterial have been fabricated in this study. The hybridization of palygorskite and chitin nanofibers was performed under the collision as well as the shear force of ball mill. The TFN membranes with different loadings of PAL-CH in the PSF layer were characterized and applied for desalination process. The incorporation of PAL-CH hybrid increased the finger like structure formation and improved the overall hydrophilicity besides highly cross linked and thinner PA layer. The flux of the neat and PAL-CH membranes was 0.82 L m-2h-1and 2.4 L m-2h-1respectively. The developed membranes exhibited remarkably improved pure water flux without compromising the salt rejection. Flux enhancement of 192.7% was achieved using 0.01 wt% PAL-CH3 hybrid nanomaterial.
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spelling utm.eprints-956692022-05-31T13:04:34Z http://eprints.utm.my/95669/ Flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite/chitin hybrid nanomaterial Mamah, Stanley Chinedu Goh, Pei Sean Ismail, Ahmad Fauzi Suzaimi, Nur Diyana Ahmad, Nor Akalili Lee, Wei Jie Q Science (General) TP Chemical technology The substrate of RO thin film composite membranes offers support for rejection layer formation. It remarkably affects the physicochemical and structural properties of the developed rejection layer. This denotes the relevance of substrates modification in realizing optimized substrate structure in terms of porosity, thickness and tortuosity with the goal of obtaining highly selective and enhanced hydrophilic membrane. Polyamide thin film nanocomposite (TFN) membranes with its polysulfone (PSF) substrate embedded with palygorskite-chitin (PAL-CH) hybrid nanomaterial have been fabricated in this study. The hybridization of palygorskite and chitin nanofibers was performed under the collision as well as the shear force of ball mill. The TFN membranes with different loadings of PAL-CH in the PSF layer were characterized and applied for desalination process. The incorporation of PAL-CH hybrid increased the finger like structure formation and improved the overall hydrophilicity besides highly cross linked and thinner PA layer. The flux of the neat and PAL-CH membranes was 0.82 L m-2h-1and 2.4 L m-2h-1respectively. The developed membranes exhibited remarkably improved pure water flux without compromising the salt rejection. Flux enhancement of 192.7% was achieved using 0.01 wt% PAL-CH3 hybrid nanomaterial. Elsevier Ltd 2021-08 Article PeerReviewed Mamah, Stanley Chinedu and Goh, Pei Sean and Ismail, Ahmad Fauzi and Suzaimi, Nur Diyana and Ahmad, Nor Akalili and Lee, Wei Jie (2021) Flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite/chitin hybrid nanomaterial. Journal of Environmental Chemical Engineering, 9 (4). pp. 1-12. ISSN 2213-3437 http://dx.doi.org/10.1016/j.jece.2021.105432 DOI:10.1016/j.jece.2021.105432
spellingShingle Q Science (General)
TP Chemical technology
Mamah, Stanley Chinedu
Goh, Pei Sean
Ismail, Ahmad Fauzi
Suzaimi, Nur Diyana
Ahmad, Nor Akalili
Lee, Wei Jie
Flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite/chitin hybrid nanomaterial
title Flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite/chitin hybrid nanomaterial
title_full Flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite/chitin hybrid nanomaterial
title_fullStr Flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite/chitin hybrid nanomaterial
title_full_unstemmed Flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite/chitin hybrid nanomaterial
title_short Flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite/chitin hybrid nanomaterial
title_sort flux enhancement in reverse osmosis membranes induced by synergistic effect of incorporated palygorskite chitin hybrid nanomaterial
topic Q Science (General)
TP Chemical technology
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