Luminescence emission in borotellurite glass containing manganese nanoparticles doped Eu3+ Ions

A series of europium doped magnesium borotellurite glasses embedded with manganese nanoparticles (Mn3O4 NPs) of composition (59-x)TeO2-30B2O3-10MgO-x1Eu2O3-1Mn3O4 with 0.5 ≤ x ≤ 1.5 mol % are prepared using melt quenching technique. The existence of broad hump in X-ray diffraction (XRD) pattern veri...

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Main Authors: Aziz, Siti Maisarah, Sahar, M. R.
Format: Conference or Workshop Item
Published: 2017
Subjects:
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author Aziz, Siti Maisarah
Sahar, M. R.
author_facet Aziz, Siti Maisarah
Sahar, M. R.
author_sort Aziz, Siti Maisarah
collection ePrints
description A series of europium doped magnesium borotellurite glasses embedded with manganese nanoparticles (Mn3O4 NPs) of composition (59-x)TeO2-30B2O3-10MgO-x1Eu2O3-1Mn3O4 with 0.5 ≤ x ≤ 1.5 mol % are prepared using melt quenching technique. The existence of broad hump in X-ray diffraction (XRD) pattern verifies the amorphous nature of glasses. The presence of Mn3O4 NPs with average diameter of ~11 nm and (1 0 3) lattice plane having 0.276 nm spacing in the glass matrix is confirmed by high resolution transmission electron microscope (HRTEM) image. The glass samples are excited under 390 nm excitation wavelength and the emission spectra are found to consist of four emission peaks centred at 587 nm, 610 nm, 651 nm and 700 nm assigned to the transition from 5D0 → 7FJ (J = 1, 2, 3, 4) states. The schematic energy level diagram is proposed. All results will be discussed with respect to the composition of Eu3+ ion.
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spelling utm.eprints-973392022-09-28T08:32:14Z http://eprints.utm.my/97339/ Luminescence emission in borotellurite glass containing manganese nanoparticles doped Eu3+ Ions Aziz, Siti Maisarah Sahar, M. R. QC Physics A series of europium doped magnesium borotellurite glasses embedded with manganese nanoparticles (Mn3O4 NPs) of composition (59-x)TeO2-30B2O3-10MgO-x1Eu2O3-1Mn3O4 with 0.5 ≤ x ≤ 1.5 mol % are prepared using melt quenching technique. The existence of broad hump in X-ray diffraction (XRD) pattern verifies the amorphous nature of glasses. The presence of Mn3O4 NPs with average diameter of ~11 nm and (1 0 3) lattice plane having 0.276 nm spacing in the glass matrix is confirmed by high resolution transmission electron microscope (HRTEM) image. The glass samples are excited under 390 nm excitation wavelength and the emission spectra are found to consist of four emission peaks centred at 587 nm, 610 nm, 651 nm and 700 nm assigned to the transition from 5D0 → 7FJ (J = 1, 2, 3, 4) states. The schematic energy level diagram is proposed. All results will be discussed with respect to the composition of Eu3+ ion. 2017 Conference or Workshop Item PeerReviewed Aziz, Siti Maisarah and Sahar, M. R. (2017) Luminescence emission in borotellurite glass containing manganese nanoparticles doped Eu3+ Ions. In: 29th Regional Conference of Solid State Science and Technology, RCSSST 2016J, 15- 17 November 2016, Johor Bahru, Johor. http://dx.doi.org/10.4028/www.scientific.net/SSP.268.106
spellingShingle QC Physics
Aziz, Siti Maisarah
Sahar, M. R.
Luminescence emission in borotellurite glass containing manganese nanoparticles doped Eu3+ Ions
title Luminescence emission in borotellurite glass containing manganese nanoparticles doped Eu3+ Ions
title_full Luminescence emission in borotellurite glass containing manganese nanoparticles doped Eu3+ Ions
title_fullStr Luminescence emission in borotellurite glass containing manganese nanoparticles doped Eu3+ Ions
title_full_unstemmed Luminescence emission in borotellurite glass containing manganese nanoparticles doped Eu3+ Ions
title_short Luminescence emission in borotellurite glass containing manganese nanoparticles doped Eu3+ Ions
title_sort luminescence emission in borotellurite glass containing manganese nanoparticles doped eu3 ions
topic QC Physics
work_keys_str_mv AT azizsitimaisarah luminescenceemissioninborotelluriteglasscontainingmanganesenanoparticlesdopedeu3ions
AT saharmr luminescenceemissioninborotelluriteglasscontainingmanganesenanoparticlesdopedeu3ions