Effect of additive acid on seeded growth of gold nanobipyramids

The presence of sharp tips and edges of gold nanobipyramids (GNBPs) lead to strong local electromagnetic field enhancement. Herein for the first time we present a study on efficacy of additive acid on the formation of GNBPs. The effect of additive acid type and its concentration in growth solution w...

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Main Authors: Nafisah, Suratun, Morsin, Marlia, Sanudin, Rahmat, Nayan, Nafarizal, Mohd. Yusop, Mohd. Zamri, Razali, Nur Liyana, Md. Shah, Nur Zehan An’Nisa
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Published: Elsevier Ltd 2021
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author Nafisah, Suratun
Morsin, Marlia
Sanudin, Rahmat
Nayan, Nafarizal
Mohd. Yusop, Mohd. Zamri
Razali, Nur Liyana
Md. Shah, Nur Zehan An’Nisa
author_facet Nafisah, Suratun
Morsin, Marlia
Sanudin, Rahmat
Nayan, Nafarizal
Mohd. Yusop, Mohd. Zamri
Razali, Nur Liyana
Md. Shah, Nur Zehan An’Nisa
author_sort Nafisah, Suratun
collection ePrints
description The presence of sharp tips and edges of gold nanobipyramids (GNBPs) lead to strong local electromagnetic field enhancement. Herein for the first time we present a study on efficacy of additive acid on the formation of GNBPs. The effect of additive acid type and its concentration in growth solution were investigated to obtain various yield and aspect ratio of GNBPs. Morphological characterization shows the nanoseeds that were grown in growth solution prepared using HCl, H2SO4, and HF at concentration from 0 to 1 mL produced GNBPs with yield ranges from 5.21 ± 0.44 to 91.46 ± 3.32% and aspect ratio from 2.00 ± 0.02 to 2.76 ± 0.05. The optical response of GNBPs exhibit dual plasmon band at wavelength around 550 nm–570 nm, corresponding to transverse surface plasmon resonance (t-SPR) and at wavelength around 700 nm–800 nm, corresponding to longitudinal surface plasmon resonance (l-SPR). The presented approach may be used to produce tunable morphological GNBPs nanostructures which potentially used in sensors, SERS, catalysis, and photonics.
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spelling utm.eprints-978342022-11-02T09:58:18Z http://eprints.utm.my/97834/ Effect of additive acid on seeded growth of gold nanobipyramids Nafisah, Suratun Morsin, Marlia Sanudin, Rahmat Nayan, Nafarizal Mohd. Yusop, Mohd. Zamri Razali, Nur Liyana Md. Shah, Nur Zehan An’Nisa TJ Mechanical engineering and machinery The presence of sharp tips and edges of gold nanobipyramids (GNBPs) lead to strong local electromagnetic field enhancement. Herein for the first time we present a study on efficacy of additive acid on the formation of GNBPs. The effect of additive acid type and its concentration in growth solution were investigated to obtain various yield and aspect ratio of GNBPs. Morphological characterization shows the nanoseeds that were grown in growth solution prepared using HCl, H2SO4, and HF at concentration from 0 to 1 mL produced GNBPs with yield ranges from 5.21 ± 0.44 to 91.46 ± 3.32% and aspect ratio from 2.00 ± 0.02 to 2.76 ± 0.05. The optical response of GNBPs exhibit dual plasmon band at wavelength around 550 nm–570 nm, corresponding to transverse surface plasmon resonance (t-SPR) and at wavelength around 700 nm–800 nm, corresponding to longitudinal surface plasmon resonance (l-SPR). The presented approach may be used to produce tunable morphological GNBPs nanostructures which potentially used in sensors, SERS, catalysis, and photonics. Elsevier Ltd 2021 Article PeerReviewed Nafisah, Suratun and Morsin, Marlia and Sanudin, Rahmat and Nayan, Nafarizal and Mohd. Yusop, Mohd. Zamri and Razali, Nur Liyana and Md. Shah, Nur Zehan An’Nisa (2021) Effect of additive acid on seeded growth of gold nanobipyramids. Journal of Physics and Chemistry of Solids, 148 (NA). pp. 1-11. ISSN 0022-3697 http://dx.doi.org/10.1016/j.jpcs.2020.109764 DOI : 10.1016/j.jpcs.2020.109764
spellingShingle TJ Mechanical engineering and machinery
Nafisah, Suratun
Morsin, Marlia
Sanudin, Rahmat
Nayan, Nafarizal
Mohd. Yusop, Mohd. Zamri
Razali, Nur Liyana
Md. Shah, Nur Zehan An’Nisa
Effect of additive acid on seeded growth of gold nanobipyramids
title Effect of additive acid on seeded growth of gold nanobipyramids
title_full Effect of additive acid on seeded growth of gold nanobipyramids
title_fullStr Effect of additive acid on seeded growth of gold nanobipyramids
title_full_unstemmed Effect of additive acid on seeded growth of gold nanobipyramids
title_short Effect of additive acid on seeded growth of gold nanobipyramids
title_sort effect of additive acid on seeded growth of gold nanobipyramids
topic TJ Mechanical engineering and machinery
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