Systematic selection of material for an amperometric glucose biosensor
The internal selective membrane for an amperometric glucose biosensor was selected quantitatively based on its transport properties. A rotating disk electrode was used to obtain the permeability of acetaminophen, a common interferent for peroxide-based glucose biosensor, and hydrogen peroxide throug...
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| Format: | Article |
| Language: | English |
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Penerbit UTM Press
2009
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| Online Access: | http://eprints.utm.my/9999/1/UTMjurnalTEK_51F_DIS%5B09%5D.pdf |
| _version_ | 1825910418129813504 |
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| author | Abd. Aziz, Azila |
| author_facet | Abd. Aziz, Azila |
| author_sort | Abd. Aziz, Azila |
| collection | ePrints |
| description | The internal selective membrane for an amperometric glucose biosensor was selected quantitatively based on its transport properties. A rotating disk electrode was used to obtain the permeability of acetaminophen, a common interferent for peroxide-based glucose biosensor, and hydrogen peroxide through cross-linked poly(vinyl alcohol) (PVA). All diffusion experiments were performed using a gold rotating electrode as platinum electrode exhibited slow electron transfer on its surface during the oxidation of acetaminophen, thus rendering it ineffective for this work. Selectivity of crosslinked PVA to peroxide was based on the permeability of peroxide compared to that acetaminophen. As hydrogen peroxide is small, its permeability was only affected when the mesh size of cross-linked PVA was significantly reduced. The permeability of the bigger acetaminophen, on the other hand, was linearly proportional to the mesh size of the cross-linked PVA. Cross-linked PVA membrane was found to display marginal selectivity towards peroxide. |
| first_indexed | 2024-03-05T18:16:48Z |
| format | Article |
| id | utm.eprints-9999 |
| institution | Universiti Teknologi Malaysia - ePrints |
| language | English |
| last_indexed | 2024-03-05T18:16:48Z |
| publishDate | 2009 |
| publisher | Penerbit UTM Press |
| record_format | dspace |
| spelling | utm.eprints-99992010-10-14T04:39:34Z http://eprints.utm.my/9999/ Systematic selection of material for an amperometric glucose biosensor Abd. Aziz, Azila TP Chemical technology The internal selective membrane for an amperometric glucose biosensor was selected quantitatively based on its transport properties. A rotating disk electrode was used to obtain the permeability of acetaminophen, a common interferent for peroxide-based glucose biosensor, and hydrogen peroxide through cross-linked poly(vinyl alcohol) (PVA). All diffusion experiments were performed using a gold rotating electrode as platinum electrode exhibited slow electron transfer on its surface during the oxidation of acetaminophen, thus rendering it ineffective for this work. Selectivity of crosslinked PVA to peroxide was based on the permeability of peroxide compared to that acetaminophen. As hydrogen peroxide is small, its permeability was only affected when the mesh size of cross-linked PVA was significantly reduced. The permeability of the bigger acetaminophen, on the other hand, was linearly proportional to the mesh size of the cross-linked PVA. Cross-linked PVA membrane was found to display marginal selectivity towards peroxide. Penerbit UTM Press 2009-12 Article PeerReviewed application/pdf en http://eprints.utm.my/9999/1/UTMjurnalTEK_51F_DIS%5B09%5D.pdf Abd. Aziz, Azila (2009) Systematic selection of material for an amperometric glucose biosensor. Jurnal Teknologi F (51F). pp. 107-120. ISSN 0127-9696 http://www.penerbit.utm.my/onlinejournal/51/F/51sirif09.pdf |
| spellingShingle | TP Chemical technology Abd. Aziz, Azila Systematic selection of material for an amperometric glucose biosensor |
| title | Systematic selection of material for an amperometric glucose biosensor |
| title_full | Systematic selection of material for an amperometric glucose biosensor |
| title_fullStr | Systematic selection of material for an amperometric glucose biosensor |
| title_full_unstemmed | Systematic selection of material for an amperometric glucose biosensor |
| title_short | Systematic selection of material for an amperometric glucose biosensor |
| title_sort | systematic selection of material for an amperometric glucose biosensor |
| topic | TP Chemical technology |
| url | http://eprints.utm.my/9999/1/UTMjurnalTEK_51F_DIS%5B09%5D.pdf |
| work_keys_str_mv | AT abdazizazila systematicselectionofmaterialforanamperometricglucosebiosensor |