Negative Ion Photoelectron Spectroscopy of P₂N₃⁻: Electron Affinity and Electronic Structures of P₂N₃˙ by Hou, Gao-Lei, Chen, Bo, Hrovat, David A., Borden, Weston Thatcher, Wang, Xue-Bin, Transue, Wesley, Cummins, Christopher C

“…Ab initio electronic structure calculations reveal the existence of five, low-lying, electronic states in the neutral P₂N₃ radical. Calculation of the Franck-Condon factors (FCFs) for each anion-to-neutral electronic transition and comparison of the resulting simulated NIPE spectrum with the vibrational structure in the observed spectrum allows the first four excited states of P₂N₃ to be determined to lie 6.2, 6.7, 11.5, and 22.8 kcal mol⁻¹ above the ground state of the radical, which is found to be a 6π-electron, ²A₁, σ state.…”
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Negative ion photoelectron spectroscopy of P[subscript 2]N[subscript 3]−: electron affinity and electronic structures of P[subscript 2]N[subscript 3]˙ by Hou, Gao-Lei, Chen, Bo, Hrovat, David A., Borden, Weston Thatcher, Wang, Xue-Bin, Cummins, Christopher C, Transue, Wesley

“…Ab initio electronic structure calculations reveal the existence of five, low-lying, electronic states in the neutral P[subscript 2]N[subscript 3]˙ radical. …”
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