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Aerosol size distribution changes in FIREX-AQ biomass burning plumes: the impact of plume concentration on coagulation and OA condensation/evaporation
Published 2022-09-01“…Observations of OA and <span class="inline-formula">O:C</span> suggest that evaporation and/or secondary OA formation was greater in less concentrated smoke prior to the first measurement (5–57 min after emission). …”
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Heterogeneity and chemical reactivity of the remote troposphere defined by aircraft measurements – corrected
Published 2023-01-01“…In this paper we present and analyze a data set of 10 s (2 km) merged and gap-filled observations of the key reactive species driving the chemical budgets of O<span class="inline-formula"><sub>3</sub></span> and CH<span class="inline-formula"><sub>4</sub></span> (O<span class="inline-formula"><sub>3</sub></span>, CH<span class="inline-formula"><sub>4</sub></span>, CO, H<span class="inline-formula"><sub>2</sub></span>O, HCHO, H<span class="inline-formula"><sub>2</sub></span>O<span class="inline-formula"><sub>2</sub></span>, CH<span class="inline-formula"><sub>3</sub></span>OOH, C<span class="inline-formula"><sub>2</sub></span>H<span class="inline-formula"><sub>6</sub></span>, higher alkanes, alkenes, aromatics, NO<span class="inline-formula"><sub><i>x</i></sub></span>, HNO<span class="inline-formula"><sub>3</sub></span>, HNO<span class="inline-formula"><sub>4</sub></span>, peroxyacetyl nitrate, and other organic nitrates), consisting of 146 494 distinct air parcels from ATom deployments 1 through 4. …”
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Observations of cyanogen bromide (BrCN) in the global troposphere and their relation to polar surface O<sub>3</sub> destruction
Published 2024-03-01“…Liquid-phase reactions of <span class="inline-formula">BrCN</span> are more likely to convert <span class="inline-formula">Br</span> to bromide (<span class="inline-formula">Br<sup>−</sup></span>) or form a <span class="inline-formula">C</span>–<span class="inline-formula">Br</span> bonded organic species, as these are the known condensed-phase reactions of <span class="inline-formula">BrCN</span> and would therefore constitute a loss of atmospheric active Br. …”
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