Organometallic chemistry and application of palladacycles in asymmetric hydrophosphination reactions by Seah, Jeffery Wee Kiong, Teo, Ronald Hong Xiang, Leung, Pak-Hing

“…This review highlights the unique stereoelectronic features and the important organometallic chemistry of palladacycle catalysts which are essential to their synthetic operations.…”
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Stability and Reactivity of Cyclometallated Naphthylamine Complexes in Pd–C Bond Insertion Reactions with Coordinated Alkynylphosphanes by Chen, Shuli, Chiew, Jun Xuan, Pullarkat, Sumod A., Li, Yongxin, Leung, Pak-Hing

Subjects: “…DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds…”
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Synthesis, optical resolution, and stereochemical properties of a rationally designed chiral C–N palladacycle by Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing, Yap, Jeanette See Leng, Chen, Houguang Jeremy

Subjects: “…DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds…”
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Versatile syntheses of optically pure PCE pincer ligands : facile modifications of the pendant arms and ligand backbones by Pullarkat, Sumod Appukuttan, Yang, Xiang-Yuan, Tay, Wee Shan, Li, Yongxin, Leung, Pak-Hing

Subjects: “…DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds…”
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Asymmetric hydroarsination reactions toward synthesis of alcohol functionalised C-chiral As–P ligands promoted by chiral cyclometallated complexes by Cheow, Yuen Lin, Li, Yongxin, Leung, Pak-Hing, Pullarkat, Sumod A.

Subjects: “…DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds…”
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Access to a chiral phosphine-NHC palladium(II) complex via the asymmetric hydrophosphination of achiral vinyl azoles by Seah, Jeffrey Wee Kiong, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing

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Stereogenic lock in 1-naphthylethanamine complexes for catalyst and auxiliary design : structural and reactivity analysis for cycloiridated pseudotetrahedral complexes by Chen, Jeremy Houguang, Teo, Ronald Hong Xiang, Li, Yongxin, Pullarkat, Sumod Appukuttan, Leung, Pak-Hing

“…In comparison to its phenyl derivative, the structural lock prevented oxidation of the amine moiety within the five-membered organometallic ring during its synthesis. With up to three stereogenic centers in one of the naphthalene complexes, the stereochemistry of the metallacycle remained stable to both thermal and chemical changes. …”
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Palladacycle-catalyzed asymmetric intermolecular construction of chiral tertiary p-heterocycles by stepwise addition of H–P–H bonds to bis(enones) by Pullarkat, Sumod A., Huang, Yinhua, Teong, Siewping, Chew, Renta Jonathan, Li, Yongxin, Leung, Pak-Hing

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Chiral phosphapalladacycles as efficient catalysts for the asymmetric hydrophosphination of substituted methylidenemalonate esters : direct access to functionalized tertiary chiral... by Pullarkat, Sumod A., Xu, Chang, Gan, Kennard Jun Hao, Hennersdorf, Felix, Li, Yongxin, Leung, Pak-Hing

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Synthesis of stereoprojecting, chiral N-C(sp3)-E type pincer complexes by Balázs, László B., Tay, Wee Shan, Li, Yongxin, Pullarkat, Sumod Appukuttan, Leung, Pak-Hing

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Access to C-Stereogenic PN(sp²)P Pincer Ligands via Phosphapalladacycle Catalyzed Asymmetric Hydrophosphination by Foo, Ce Qing, Sadeer, Abdul, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing

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Reactivity of cycloplatinated amine complexes : intramolecular C–C bond formation, C–H activation, and PPh2 migration in coordinated alkynylphosphines by Tan, Kien-Wee, Yang, Xiang-Yuan, Li, Yongxin, Huang, Yinhua, Leung, Pak-Hing, Pullarkat, Sumod A.

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Synthesis, structural characterisation and stereochemical investigation of chiral sulfur-functionalised N-heterocyclic carbene complexes of palladium and platinum by Krishnan, Deepa, Wu, Meiyi, Li, Yongxin, Leung, Pak-Hing, Pullarkat, Sumod A.

“…The absolute conformations of these novel organometallic S-NHC chelates were determined by X-ray structural analyses and solution-phase 2D 1H–1H ROESY NMR spectroscopy. …”
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