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Palladium-catalyzed direct alkynylation of N-vinylacetamides
Published 2014“…A direct ethynylation reaction between N-vinylacetamides and (bromoethynyl)triisopropylsilane catalyzed by palladium is reported. A broad scope of cyclic N-vinylacetamide derivatives was tolerated and the corresponding products could be obtained in acceptable yields. …”
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2
Palladium-catalyzed direct C-H arylation of enamides with simple arenes
Published 2013“…The Z/E selectivity of the palladium-catalyzed monoarylation is absolute (step A in scheme), and the molecular complexity of the products can be further endowed by a sequential second arylation, which requires the use of trifluoracetic acid (TFA; step B).…”
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3
Bioinspired deamination of α-amino acid derivatives catalyzed by a palladium/nickel complex
Published 2020“…The reaction is realized with two transition metal catalysts (palladium and Nickel) in‐easy handling procedure. A possible reaction pathway is also proposed and the control experiments support the involvement of the palladium‐catalyzed inert sp3 C−H activation as one of the key steps.…”
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4
Palladium-catalyzed dialkylation of C-C triple bonds : access to multi-functionalized indenes
Published 2021“…A palladium-catalyzed dialkylation of 1,3-dien-5-ynes was developed using alkenyl double bonds as the initiator and terminator for the synthesis of functionalized indene derivatives. …”
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5
Palladium-catalyzed anti-michael reductive heck reaction of α,β-unsaturated esters
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6
Palladium(II)-catalyzed stereospecific alkenyl C-H bond alkylation of allylamines with alkyl iodides
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Palladium(II)-catalyzed stereospecific alkenyl C-H bond alkylation of allylamines with alkyl iodides
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Palladium-catalyzed cross-coupling of unactivated alkenes with Acrylates: application to the synthesis of the C13-C21 fragment of Palmerolide A
Published 2013“…Diene to meet: A palladium-catalyzed cross-coupling reaction between alkyl-substituted olefins and acrylates gives the corresponding butadienes in moderate yield and stereoselectivity. …”
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Metallic salt-catalyzed direct indium insertion into alkyl iodides and their applications in cross-coupling reactions
Published 2021“…An efficient method for the synthesis of alkyl indium reagents by means of an indium(III) or lead(II) halidecatalyzed direct insertion of indium into alkyl iodides and their applications in palladium-catalyzed crosscoupling reactions with aryl halides is developed. …”
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