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Nickel-Borate Oxygen-Evolving Catalyst that Functions under Benign Conditions
Published 2011“…Thin catalyst films with electrocatalytic water oxidation properties similar to those of a recently reported Co-based catalyst can be electrodeposited from dilute Ni2+ solutions in borate electrolyte at pH 9.2 (Bi). The Ni-Bi films can be prepared with precise thickness control and operate at modest overpotential providing an alternative to the Co catalyst for applications in solar energy conversion.…”
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A General Method for Suzuki–Miyaura Coupling Reactions Using Lithium Triisopropyl Borates
Published 2013“…Conditions for the Suzuki–Miyaura coupling of lithium triisopropyl borates are reported, as well as a procedure for a one-pot lithiation, borylation, and subsequent Suzuki–Miyaura coupling of various heterocycles with aryl halides. …”
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Tetraarylborate polymer networks as single-ion conducting solid electrolytes
Published 2017“…A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported. …”
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Modeling integrated photovoltaic-electrochemical devices using steady-state equivalent circuits
Published 2013“…This predictive utility is demonstrated in the case of water oxidation at the surface of a Si solar cell, using a Co–borate catalyst.…”
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Interplay of oxygen-evolution kinetics and photovoltaic power curves on the construction of artificial leaves
Published 2013“…For such a condition, we show here that the current density-voltage characteristic of the catalyst is a key determinant of the solar-to-fuels efficiency (SFE). Oxidic Co and Ni borate (Co-B[subscript i] and Ni-B[subscript i]) thin films electrodeposited from solution yield oxygen-evolving catalysts with Tafel slopes of 52 mV/decade and 30 mV/decade, respectively. …”
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