Negishi Coupling of Secondary Alkylzinc Halides with Aryl Bromides and Chlorides by Han, Chong, Buchwald, Stephen Leffler

“…An efficient palladium-catalyzed process has been developed for Negishi coupling of secondary alkylzinc halides with a wide range of aryl bromides and activated aryl chlorides. …”
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Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis by Koh, Ming Joo, Nguyen, Thach T., Zhang, Hanmo, Hoveyda, Amir H., Schrock, Richard Royce

“…Olefin metathesis has had a large impact on modern organic chemistry, but important shortcomings remain: for example, the lack of efficient processes that can be used to generate acyclic alkenyl halides. Halo-substituted ruthenium carbene complexes decompose rapidly or deliver low activity and/or minimal stereoselectivity, and our understanding of the corresponding high-oxidation-state systems is limited. …”
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Mild Palladium-Catalyzed Cyanation of (Hetero)aryl Halides and Triflates in Aqueous Media by Cohen, Daniel Tzvi, Buchwald, Stephen Leffler

“…A mild, efficient, and low-temperature palladium-catalyzed cyanation of (hetero)aryl halides and triflates is reported. Previous palladium-catalyzed cyanations of (hetero)aryl halides have required higher temperatures to achieve good catalytic activity. …”
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Triplet-Sensitization by Lead Halide Perovskite Thin Films for Near-Infrared-to-Visible Upconversion by Nienhaus, Lea, Correa-Baena, Juan-Pablo, Wieghold, Sarah, Einzinger, Markus, Lin, Ting-An, Shulenberger, Katherine, Klein, Nathan, Wu, Mengfei, Bulovic, Vladimir, Buonassisi, Tonio, Baldo, Marc A, Bawendi, Moungi G

“…Lead halide-based perovskite thin films have attracted great attention due to the rapid increase in perovskite solar cell efficiencies. …”
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Coherent single-photon emission from colloidal lead halide perovskite quantum dots by Utzat, Hendrik, Sun, Weiwei, Kaplan, Alexander EK, Krieg, Franziska, Ginterseder, Matthias, Spokoyny, Boris, Klein, Nathan D., Shulenberger, Katherine E., Perkinson, Collin Fisher, Kovalenko, Maksym, Bawendi, Moungi G

“…We now demonstrate that individual colloidal lead halide perovskite quantum dots (PQDs) display highly efficient single-photon emission with optical coherence times as long as 80 picoseconds, an appreciable fraction of their 210-picosecond radiative lifetimes. …”
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Palladium-Catalyzed Hydroxylation of Aryl and Heteroaryl Halides Enabled by the Use of a Palladacycle Precatalyst by Cheung, Chi Wai, Buchwald, Stephen Leffler

“…A method for the hydroxylation of aryl and heteroaryl halides, promoted by a catalyst based on a biarylphosphine ligand tBuBrettPhos (L5) and its corresponding palladium precatalyst (1), is described. …”
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Highly Selective Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents with Heteroaryl Halides by Yang, Yang, Niedermann, Katrin, Han, Chong, Buchwald, Stephen Leffler

“…The highly selective palladium-catalyzed Negishi coupling of secondary alkylzinc reagents with heteroaryl halides is described. The development of a series of biarylphosphine ligands has led to the identification of an improved catalyst for the coupling of electron-deficient heterocyclic substrates. …”
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Interfacial Trap‐Assisted Triplet Generation in Lead Halide Perovskite Sensitized Solid‐State Upconversion by Wang, Lili, Yoo, Jason J., Lin, Ting‐An, Perkinson, Collin F., Lu, Yongli, Baldo, Marc A., Bawendi, Moungi G.

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Ligand-Controlled Palladium-Catalyzed Regiodivergent Suzuki–Miyaura Cross-Coupling of Allylboronates and Aryl Halides by Yang, Yang, Buchwald, Stephen Leffler

“…An orthogonal set of catalyst systems has been developed for the Suzuki–Miyaura coupling of 3,3-disubstituted and 3-monosubstituted allylboronates with (hetero)aryl halides. These methods allow for the highly selective preparation of either the α- or the γ-isomeric coupling product.…”
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Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations by Fu, Gregory C., Zultanski, Susan

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Palladium-Catalyzed Completely Linear-Selective Negishi Cross-Coupling of Allylzinc Halides with Aryl and Vinyl Electrophiles by Yang, Yang, Mustard, Thomas J. L., Cheong, Paul Ha-Yeon, Buchwald, Stephen Leffler

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A dual palladium and copper hydride catalyzed approach for alkyl-aryl cross-coupling of aryl halides and olefins by Friis, Stig During, Pirnot, Michael T, Dupuis, Lauren N., Buchwald, Stephen Leffler

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The mechanism of the reaction of aryl halides with metallic amides. II. Transannular effects in the solvolysis of cis- and trans-cycloöctene oxide by Simmons, Howard E.

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Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, To Generate Carbon–Boron Bonds by Dudnik, Alexander S., Fu, Gregory C.

“…In contrast to seemingly related nickel-catalyzed C–C bond-forming processes, tertiary halides are more reactive than secondary or primary halides in this nickel-catalyzed C–B bond-forming reaction; this divergence is particularly noteworthy in view of the likelihood that both transformations follow an inner-sphere electron-transfer pathway for oxidative addition.…”
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Palladium-catalyzed coupling of functionalized primary and secondary amines with aryl and heteroaryl halides: two ligands suffice in most cases by Maiti, Debabrata, Fors, Brett P., Henderson, Jaclyn L., Nakamura, Yoshinori, Buchwald, Stephen Leffler

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Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene by Hoveyda, Amir, Lam, Jonathan K, Zhu, Congqing, Bukhryakov, Konstantin, Mueller, Peter, Schrock, Richard Royce

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Single-Ion Li[superscript +], Na[superscript +], and Mg[superscript 2+] Solid Electrolytes Supported by a Mesoporous Anionic Cu–Azolate Metal–Organic Framework by Park, Sarah Sunah, Tulchinsky, Yuri, Dinca, Mircea

“…Whereas the halide/pseudohalide anions are bound to the metal centers and thus stationary, the cations move freely within the one-dimensional pores, giving rise to single-ion solid electrolytes. …”
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Computational Explorations of Mechanisms and Ligand-Directed Selectivities of Copper-Catalyzed Ullmann-Type Reactions by Buchwald, Stephen Leffler, Jones, Gavin O., Houk, K. N., Liu, Peng

“…Density functional theory calculations using several functionals were performed on both the nucleophile formation and aryl halide activation steps of these reactions. The origin of ligand-directed selectivities in N- versus O-arylation reactions as described in a previous publication (J. …”
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Palladium–peptide oxidative addition complexes for bioconjugation by Rojas, Anthony J, Wolfe, Justin M, Dhanjee, Heemal H, Buslov, Ivan, Truex, Nicholas L, Liu, Richard Y, Massefski, Walter, Pentelute, Bradley L, Buchwald, Stephen L

“…<jats:p>Peptides bearing palladium oxidative addition complexes can be synthesized from the parent aryl halide containing substrates and react with thiol functional groups of small molecules, peptides, and proteins at low micromolar concentrations.…”
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A time-domain view of charge carriers in semiconductor nanocrystal solids by Shcherbakov-Wu, Wenbi, Tisdale, William A

“…Finally, we close with a forward-looking assessment of emerging nanocrystal systems, including anisotropic nanocrystals, such as nanoplatelets, and colloidal lead halide perovskites.…”
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