Geoff Cloke at 65: a pioneer in organometallic chemistry by Arnold, P, Green, J, Green, M, Kilpatrick, A, Layfield, R, Love, J, O'Hare, D, Turner, J

Structural, electronic and kinetics on organometallic intercalates of metal dichalcogenides by Wong, H, Wong, Heng-Vee

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The hexamethylpentalene dianion and other reagents for organometallic pentalene chemistry. by Ashley, A, Cowley, A, O'Hare, D

“…Novel permethylated pentalenide anions are reported which offer exciting new opportunities for the future development of organometallic pentalene chemistry.…”

Electronic communication through unsaturated hydrocarbon bridges in homobimetallic organometallic complexes. by Aguirre-Etcheverry, P, O'Hare, D

Olefin polymerisation using group 4 permethylindenyl complexes by Thomas Williams

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η8-Permethylpentalene Titanium Chemistry by Cooper, RT

Subjects: “…Organometallic Chemistry…”

(eta 5-Cyclopentadienyl)(kappa 3-hydrotris(pyrazolyl)borate)cobalt(II)--the first high-spin cobalt organometallic complex. by Brunker, T, Barlow, S, O'Hare, D

“…(eta 5-Cyclopentadienyl)(kappa 3-hydrotris(pyrazolyl)borate)-cobalt(II) has been synthesised; magnetic and crystallographic data indicate this to be the first example of a high-spin cobalt organometallic complex whilst its pentamethylcyclopentadienyl analogue is found to have a low-spin electronic configuration.…”

Pentalene complexes of group 7 metal carbonyls: an organometallic mixed-valence system with very large metal-metal electronic coupling. by Jones, S, Hascall, T, Barlow, S, O'Hare, D

Group four permethylindenyl-phenoxy (PHENI*) complexes for the synthesis of polyolefins by Collins Rice, CG

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Group 4 permethylpentalene complexes as polymerisation catalysts by Georges, M

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Uranium, zirconium and hafnium eta8-permethylpentalene chemistry by Chadwick, F, Frederick Mark Chadwick

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Indenyl and diazene chemistry by Ransom, P

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Bulk synthesis of octa- and nonamethylfluorene (Flu '' H and Flu*H) and the characterization of the organometallic derivatives Flu*SnMe3, [(FeCp)(2)Flu*H][PF6](2), and [(FeCp)(2)Flu '' H][PF6](2) by Moss, J, Thomas, J, Ashley, A, Cowley, A, O'Hare, D

“…Both fluorenes may be deprotonated at the 9 position to yield useful organometallic synthons; the Sn derivative, Flu*SnMe3, is synthesized using this reagent, and its molecular structure has been elucidated. …”

Synthesis and characterisation of permethylpentalene complexes and permethylpentalene derivatives by Binding, S, Samantha Binding

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Synthesis and characterisation of permethylpentalene complexes and permethylpentalene derivatives by Binding, S, Samantha Binding

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Convenient solution route to alkylated pentalene ligands: New metal monoalkylpentalenyl complexes by Jones, S, Roussel, P, Hascall, T, O'Hare, D

“…X-ray crystallographic studies of the dinuclear Mn organometallics anti-[Mn(CO3]2(C8H 5R) synthesized from the Li salts confirm that these alkylated pentalene ligands are substituted at the 1-position exclusively. …”

Bonding in pentalene complexes and their recent applications by Cloke, F, Green, J, Kilpatrick, A, O'Hare, D

“…Recent applications of pentalene complexes are also reviewed, in the areas of small molecule activation and catalysis and as molecular models for conducting organometallic polymers.…”

Triple-decker transition metal complexes bridged by a single carbocyclic ring by Beck, V, O'Hare, D

“…Studies of the complexes' properties are described where applicable. Triple-decker organometallic complexes of transition metals have attracted interest since 1972, when Werner and Salzer prepared the tris(cyclopentadienyl)dinickel cation, the first example of this class of compound. …”

Permethylpentalene chemistry by Ashley, A, Cowley, A, O'Hare, D

“…A rational solution-phase synthesis of a permethylpentalene (Pn*) ligand precursor for use in organometallic chemistry has been devised through the novel peripheral alkylation of the bicyclo[3.3.0]octane ring system. …”

Controlling the surface hydroxyl concentration by thermal treatment of layered double hydroxides. by Wright, CMR, Ruengkajorn, K, Kilpatrick, AFR, Buffet, JC, O'Hare, D

“…These materials appear to be suitable candidates for use as single-site organometallic catalyst supports.…”