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Synthesis and characterization of three dimensionally connected actinide frameworks.
Published 2002Journal article -
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[(Th2F5)(NC7H5O4)2(H2O)][NO3]: an actinide-organic open framework.
Published 2003“…We believe [(Th2F5)(NC7H5O4)2(H2O)][NO3] is the first three-dimensionally connected, actinide-organic framework solid. The structure is composed of thorium oxyfluoride chains, each of which connected to pyridinedicarboxylate groups to give a 3D cross-linked network with cavities containing nitrate anions.…”
Journal article -
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[NC4H12]2[(UO2)6(H2O)2(SO4)7]: the first organically templated actinide sulfate with a three-dimensional framework structure.
Published 2002“…[NC4H12][(UO2)6(H2O)2(SO4)7] is the first organically templated actinide sulfate with a three-dimensional framework structure; it has channels of dimensions 8.5 A x 8.5 A, running along the [001] direction, containing tetramethylammonium cations.…”
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Synthesis and characterisation of (C4N2H12)(UO2)2(PO3H)2(PO2(OH)H)2: a three dimensionally connected actinide framework.
Published 2001Journal article -
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From molecules to frameworks: Variable dimensionality in the UO2(CH3COO)(2)center dot 2H(2)O/HF(aq)/piperazine system. Syntheses, structures, and characterization of zero-dimension...
Published 1999“…MUF-1 also represents the first open-framework actinide material. In addition, the structural topologies of both UFO-10 and MUF-1 are completely unprecedented with respect to uranium materials.…”
Journal article