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Organocatalyzed living radical polymerization of itaconates and self-assemblies of rod-coil block copolymers
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Journal Article -
2
Reduction-responsive double hydrophilic block copolymer nano-capsule synthesized via RCMP-PISA
Published 2021“…A double hydrophilic block copolymer (DHBC) vesicle was synthesized via an organocatalyzed living radical polymerization, i.e., reversible complexation mediated polymerization (RCMP). …”
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Journal Article -
3
Networking of block copolymer nanoassemblies via digital light processing four-dimensional printing for programmable actuation
Published 2022“…Instead of using random copolymers, homopolymers, or natural polymers, this paper reports the first use of amphiphilic, photocurable, and pH-responsive block copolymer (BCP) nanoassemblies in digital light processing (DLP) 4D printing to fabricate smart and programmable soft actuators. …”
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Journal Article -
4
Functional polymeric assembly materials via non-transition metal iodide catalyzed controlled radical polymerization
Published 2019“…The self-assembly methods of block copolymers for generating self-assemblies and their influencing parameters have been discussed in brief. …”
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5
Reversible complexation mediated living radical polymerization using tetraalkylammonium chloride catalysts
Published 2022“…Benzyldodecyldimethylammonium chloride is further exploited to other methacrylates and yields low-dispersity block copolymers. The advantages of the chloride salt catalysts are wide monomer scope, good livingness, accessibility to block copolymers, and good solubility in organic media. …”
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Journal Article -
6
Synthesis of nano-capsules via aqueous emulsion RCMP-PISA and encapsulation
Published 2020“…Spheres and vesicles were generated depending on the degrees of polymerization of the hydrophilic and hydrophobic segments in the block copolymers. The spheres and vesicles were crosslinked using a divinyl monomer (ethylene glycol dimethacrylate (EGDMA)) as a co-monomer of MMA in situ during the polymerization. …”
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Journal Article -
7
Synthesis of core-crosslinked star polymers via organocatalyzed living radical polymerization
Published 2021“…A PBA homopolymer, an amphiphilic PMMA–PPEGA block copolymer, and a hard-soft PMMA–PBA block copolymer were synthesized as macroinitiators, where PBA is poly(butyl acrylate), PMMA is poly(methyl methacrylate), and PPEGA is poly(poly(ethylene glycol) methyl ether acrylate). …”
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Journal Article