Electromechanically reconfigurable terahertz stereo metasurfaces by Prakash, Saurav, Pitchappa, Prakash, Agrawal, Piyush, Jani, Hariom, Zhao, Yunshan, Kumar, Abhishek, Thong, John, Linke, Jian, Ariando, Ariando, Singh, Ranjan, Venkatesan, Thirumalai

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Stereo-controlled anti-hydromagnesiation of aryl alkynes by magnesium hydrides by Wang, Bin, Ong, Derek Yiren, Li, Yihang, Pang, Jia Hao, Watanabe, Kohei, Takita, Ryo, Chiba, Shunsuke

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Superbase-catalyzed stereo- and regioselective glycosylation with 2‑nitroglycals : facile access to 2‑amino-2-deoxy‑O‑glycosides by Pal, Kumar Bhaskar, Guo, Aoxin, Das, Mrinmoy, Báti, Gábor, Liu, Xue-Wei

“…An efficient superbase-catalyzed stereo- and regio-selective glycosylation of 2-nitroglycals with high functional group compatibility is reported. …”
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Palladium catalyzed asymmetric hydrophosphination of α,β- and α,β,γ,δ-unsaturated malonate esters : efficient control of reactivity, stereo- and regio-selectivity by Leung, Pak-Hing, Yang, Xiang-Yuan, Gan, Jun Hao, Li, Yongxin, Pullarkat, Sumod A.

“…Our studies on the asymmetric P–H addition of diphenylphosphine to malonate ester and α,β,γ,δ-alkylidenemalonate ester revealed for the first time that the catalyst choice can have a dramatic impact in terms of reactivity as well as regio- and stereo-control for this asymmetric hydrofunctionalization reaction. …”
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NHC-catalyzed activation of aldehydes for asymmetric reactions by Chen, Xingkuan

“…We have shown that cis-enals can offer different stereo-selectivities and somewhat surprisingly distinct reactivity patterns.…”
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Rapid access to bicyclic δ-lactones via carbene-catalyzed activation and cascade reaction of unsaturated carboxylic esters by Fu, Zhenqian, Wu, Xingxing, Chi, Robin Yonggui

“…The iridoid-type lactone products are obtained with high stereo-selectivities, and can readily undergo further transformations.…”
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Asymmetric catalytic 1,2-dihydrophosphination of secondary 1,2-diphosphines - direct access to free P*- and P*,C*-diphosphines by Teo, Ronald Hong Xiang, Chen, Jeremy Houguang, Li, Yongxin, Pullarkat, Sumod A., Leung, Pak-Hing

“…The synthesized ligands can also undergo direct complexation onto palladium affording complexes with complete retention of stereo-integrity. (Figure presented.).…”
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Transition metal-catalyzed functionalization of alkynes and arenes by Bathoju Chandra Chary

“…To extend this approach, application of this methodology on haloalkynes provided Z-halo vinyl phosphates in a regio- and stereo-selective manner, whereas consecutive Pd-catalyzed cross-coupling reaction of Z-halo vinyl phosphates gave stereodefined trisubstituted olefins. …”
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Access to cyclic β-amino acids by amine-catalyzed enantioselective addition of the γ-carbon atoms of α,β-unsaturated imines to enals by Luo, Guoyong, Huang, Zhijian, Zhuo, Shitian, Mou, Chengli, Wu, Jian, Jin, Zhichao, Chi, Robin Yonggui

“…This highly chemo- and stereo-selective reaction affords cyclic β-amino aldehydes that can be converted to amino acids bearing quaternary stereocenters with exceptional optical purities. …”
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Reversible [4 + 2] cycloaddition reaction of 1,3,2,5-diazadiborinine with ethylene by Wu, Di, Ganguly, Rakesh, Li, Yongxin, Hoo, Sin Ni, Hirao, Hajime, Kinjo, Rei

“…Compound 1 reacted regio-selectively and stereo-selectively with styrene derivatives and norbornene, respectively, and these processes were found to be reversible too. …”
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Recent advances in reagent-controlled stereoselective/stereospecific glycosylation by Yao, Hui, Vu, Minh Duy, Liu, Xue-Wei

“…This mini-review discusses selected recent novel methodologies on reagent-mediated stereo-controlled glycosylation in the last decade, classified by the types of glycosyl donors.…”
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Carbon–carbon bond activation of cyclobutenones enabled by the addition of chiral organocatalyst to ketone by Li, Bao-Sheng, Wang, Yuhuang, Jin, Zhichao, Zheng, Pengcheng, Ganguly, Rakesh, Chi, Robin Yonggui

“…Here we describe an organocatalytic activation of C–C bonds through the addition of an NHC to a ketone moiety that initiates a C–C single bond cleavage as a key step to generate an NHC-bound intermediate for chemo- and stereo-selective reactions. This reaction constitutes an asymmetric functionalization of cyclobutenones using organocatalysts via a C–C bond activation process. …”
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Catalytic atroposelective synthesis of axially chiral benzonitriles via chirality control during bond dissociation and CN group formation by Lv, Ya, Luo, Guoyong, Liu, Qian, Jin, Zhichao, Zhang, Xinglong, Chi, Robin Yonggui

“…DFT calculations suggest that the loss of p-toluenesulfinate group is both the rate-determining and stereo-determining step. The axial chirality is controlled during the bond dissociation and CN group formation. …”
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