Organocatalyzed living radical polymerization of itaconates and self-assemblies of rod-coil block copolymers by Hu, Keling, Sarkar, Jit, Zheng, Jie, Lim, Melania Yan Hui, Goto, Atsushi

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Temperature-selective dual radical generation from alkyl diiodide : applications to synthesis of asymmetric cabc multi-block copolymers and their unique assembly structures by Zheng, Jie, Wang, Chen-Gang, Yamaguchi, Yu, Miyamoto, Michihiko, Goto, Atsushi

Subjects: “…Block Copolymers…”
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Temperature-directed micellar morphological transformation using CABC-block copolymers and its applications in encapsulation and hidden segment by Zheng, Jie, Chen, Chen, Goto, Atsushi

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Polymer dispersity control by organocatalyzed living radical polymerization by Liu, Xu, Wang, Chen-Gang, Goto, Atsushi

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Reduction-responsive double hydrophilic block copolymer nano-capsule synthesized via RCMP-PISA by Sarkar, Jit, Chan, Jonathan Kai Bin, Goto, Atsushi

“…A double hydrophilic block copolymer (DHBC) vesicle was synthesized via an organocatalyzed living radical polymerization, i.e., reversible complexation mediated polymerization (RCMP). …”
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Synthesis of block copolymers using poly(methyl methacrylate) with unsaturated chain end through kinetic studies by Chang, Jun Jie, Niino, Hiroshi, Chatani, Shunsuke, Goto, Atsushi

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Toward highly trustable miniaturized semiconductor gas sensors by Zhao, Yuxin, Zhang, Haihan, Zhang, Shucai, Zhao, Yanli

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Synthesis of block copolymers by mechanistic transformation from reversible complexation mediated living radical polymerization to the photoinduced radical oxidation/addition/deactivation process by Aydogan, Canus, Aykac, F. Simal, Yilmaz, Gorkem, Chew, Ye Qiu, Goto, Atsushi, Yagci, Yusuf

“…Successful formation of the block copolymers is confirmed by 1H NMR, FT-IR, GPC, and DSC investigations.…”
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Reversible complexation mediated living radical polymerization using tetraalkylammonium chloride catalysts by Han, Shuaiyuan, Zheng, Yichao, Sarkar, Jit, Niino, Hiroshi, Chatani, Shunsuke, Goto, Atsushi

“…Benzyldodecyldimethylammonium chloride is further exploited to other methacrylates and yields low-dispersity block copolymers. The advantages of the chloride salt catalysts are wide monomer scope, good livingness, accessibility to block copolymers, and good solubility in organic media. …”
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Homo- and co-polymerization of polysytrene-block-poly(acrylic acid)-coated metal nanoparticles by Wang, Hong, Song, Xiaohui, Liu, Cuicui, He, Jiating, Chong, Wen Han, Chen, Hongyu

“…Amphiphilic block copolymers such as polystyrene-block-poly(acrylic acid) (PSPAA) give micelles that are known to undergo sphere-to-cylinder shape transformation. …”
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Modification of structural and magnetic properties of masked Co-Pt films induced by high-energy ion implantation by Kumar, Durgesh, Gupta, Surbhi, Jin, Tianli, Razia Nongjai, Asokan, Kandasami, Piramanayagam, S. N.

“…The dot patterns were fabricated using self-assembly of di-block copolymers. The effects of 14N+ and 40Ar+ ion implantation at energies as high as 40 and 100 keV, respectively, were studied. …”
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Synthesis of nano-capsules via aqueous emulsion RCMP-PISA and encapsulation by Sarkar, Jit, Jackson, Alexander W., van Herk, Alexander M., Goto, Atsushi

“…Spheres and vesicles were generated depending on the degrees of polymerization of the hydrophilic and hydrophobic segments in the block copolymers. The spheres and vesicles were crosslinked using a divinyl monomer (ethylene glycol dimethacrylate (EGDMA)) as a co-monomer of MMA in situ during the polymerization. …”
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Carboxylate, nitrate, sulfonate, and phosphate catalysts for living radical polymerization : via oxygen-iodine halogen bonding catalysis by Mao, Weijia, Wang, Chen Gang, Lu, Yunpeng, Faustinelie, Winnie, Goto, Atsushi

“…These oxyanion catalysts were amenable for methyl methacrylate, functional methacrylates, styrene, and acrylonitrile, and also afforded block copolymers with low dispersities. The catalytic activities of the oxyanions were also theoretically studied using density functional theory (DFT) calculation. …”
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Biocompatible choline iodide catalysts for green living radical polymerization of functional polymers by Wang, Chen-Gang, Hanindita, Fiona, Goto, Atsushi

“…Well-defined hydrophobic–hydrophilic and hydrophilic–hydrophilic block copolymers were also synthesized. The accessibility to a range of polymer designs is an attractive feature of this polymerization. …”
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Recyclable solid-supported catalysts for quaternary ammonium iodide-catalyzed living radical polymerization by Wang, Chen Gang, Chang, Jun Jie, Foo, Ellendea Yong Jing, Niino, Hiroshi, Chatani, Shunsuke, Hsu, Shu Yao, Goto, Atsushi

“…The supported catalysts were successfully used to synthesize homopolymers and block copolymers of methyl methacrylate, functional methacrylates, styrene, and acrylonitrile with low dispersities. …”
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Halogen-bond-driven supramolecular assemblies of quaternary-ammonium-iodide-containing polymers in three phases by Le, Hong Tho, Goto, Atsushi

“…In the solution, QAI-containing block copolymers form unique self-assembly structures such as micrometer-sized giant vesicles (up to 5-μm diameter) and a 1-dimensional (1D) structure with multiple inter-vesicular linkages via XB. …”
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Metal‐free fast azidation by using tetrabutylammonium azide : effective synthesis of alkyl azides and well‐defined azido‐end polymethacrylates by Wang, Chen-Gang, Chong, Amerlyn Ming Liing, Lu, Yunpeng, Liu, Xu, Goto, Atsushi

“…Notably, the combination of organocatalyzed living (or reversible deactivation) radical polymerization and BNN3 azidation enabled the metal‐free synthesis of azido‐end polymethacrylates, including single‐azido‐end and multi‐azido‐end functional homopolymers and block copolymers. The rapid and quantitative reaction without the requirement for a large excess of BNN3, metal‐free and polar‐solvent‐free nature, and broad polymer scope are attractive features of this azidation.…”
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Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization by Wang, Yawen, Song, Xiohui, Wang, Hong, Chen, Hongyu

“…When more than one type of nanoparticles are used, random and block “copolymers” of nanoparticles can be obtained. Detailed procedures are reported for the PSPAA encapsulation of nanoparticles, homo- and co-polymerization of the core-shell nanoparticles, separation and purification of the resulting nanoparticle chains. …”
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Ion-implantation-induced disorder in FePt-C thin films by Kumar, Durgesh, Gupta, Surbhi, Tham, Kim Kong, Nongjai, Razia, Saito, Shin, Asokan, Kandasami, Piramanayagam, S. N.

“…The mask pattern was fabricated using self-assembly of di-block copolymers. For implantation, high- (40 keV for 14N+ and 100 keV for 40Ar+ ) and low- (7.5 keV for 14N+ and 4.5 keV for 40Ar+ ) energy 14N+ and 40Ar+ ions were used to modify the structural and magnetic properties of these films. …”
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Synthesis of core-crosslinked star polymers via organocatalyzed living radical polymerization by Zheng, Yichao, Sarkar, Jit, Niino, Hiroshi, Chatani, Shunsuke, Hsu, Shu Yao, Goto, Atsushi

“…A PBA homopolymer, an amphiphilic PMMA–PPEGA block copolymer, and a hard-soft PMMA–PBA block copolymer were synthesized as macroinitiators, where PBA is poly(butyl acrylate), PMMA is poly(methyl methacrylate), and PPEGA is poly(poly(ethylene glycol) methyl ether acrylate). …”
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