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RbEr<sub>2</sub>AsS<sub>7</sub>: A Rubidium-Containing Erbium Sulfide Thioarsenate(III) with (S<sub>2</sub>)<sup>2−</sup> Ligands According to RbEr<sub>2</sub>S(S<sub>2</sub>)[AsS<...
Published 2023-12-01“…The [ErS<sub>9</sub>] polyhedra are corner- and face-connected, while the [ErS<sub>7</sub>] units share common edges, both building chains along [010]. …”
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H-type Ce2[Si2O7]
Published 2023-07-01“…The four crystallographically distinct CeIII cations form distorted square antiprisms, capped square antiprisms, and bicapped square antiprisms as coordination polyhedra consisting of oxygen atoms. Four crystallographically different silicon atoms recruit the centers of two different isolated [Si2O7]6– units.…”
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The Short Series of the Oxygen-Poor Lanthanide Oxide Selenides M10OSe14 with M = La–Nd
Published 2012-08-01“…All three crystallographically independent M3+ cations exhibit eight contacts to chalcogenide anions (O2– and/or Se2–) resulting in the formation of bicapped trigonal prismatic coordination polyhedra. The optical band gaps of the oxide selenides M10OSe14 amount to values between 1.89 and 2.04 eV indicating wide band-gap semiconductors.…”
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Synthesis under high pressure: crystal structure and properties of cubic Dy36O11F50[AsO3]12 ∙ H2O
Published 2024-03-01“…Its crystal structure exhibits isolated ψ1-tetrahedral [AsO3]3– anions, but both the coordination numbers and the linking schemes of the Dy3+-centered polyhedra differ significantly from the mostly layered structures described so far in literature. …”
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Synthesis and Crystal Structure of the Short <i>Ln</i>Sb<sub>2</sub>O<sub>4</sub>Br Series (<i>Ln</i> = Eu–Tb) and Luminescence Properties of Eu<sup>3+</sup>-Doped Samples
Published 2020-11-01“…These [<i>Ln</i>O<sub>8</sub>]<sup>13−</sup> polyhedra form layers parallel to (100) by sharing common edges. …”
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A Challenge toward Novel Quaternary Sulfides SrLnCuS<sub>3</sub> (Ln = La, Nd, Tm): Unraveling Synthetic Pathways, Structures and Properties
Published 2022-10-01“…A 3D crystal structure of SrTmCuS<sub>3</sub> is constructed from the SrS<sub>6</sub> trigonal prisms, TmS<sub>6</sub> octahedra and CuS<sub>4</sub> tetrahedra. The latter two polyhedra are packed together into 2D layers, which are separated by 1D chains (SrS<sub>6</sub>)<sub>n</sub> and 1D free channels. …”
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Synthesis, Crystal Structure and Properties of the New Laminar Quaternary Tellurides Sr<i>Ln</i>CuTe<sub>3</sub> (<i>Ln</i> = Sm, Gd–Tm and Lu)
Published 2023-02-01“…The distortion of the polyhedra [CuTe<sub>4</sub>]<sup>7–</sup> was compared for the whole series Sr<i>Ln</i>CuTe<sub>3</sub> by means of τ<sub>4</sub>-descriptor for the four coordinating Te<sup>2–</sup> anions, which revealed a decrease in the degree of distortion with a decreasing radius at <i>Ln</i><sup>3+</sup>. …”
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